Liquid–Air Interface Self-Assembly of Nanoparticles Synthesized from Reaction Between Fe(dbm)3 and Pt(acac)2
The liquid–air interface is demonstrated as a method to assemble nanoparticles synthesized from the reaction between iron (III) dibenzoylmethane (Fe(dbm) 3 ) and platinum acetylacetonate (Pt(acac) 2 ) into a long range monolayer. These surface-modified particles have average Fe to Pt atomic ratio of...
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| Veröffentlicht in: | Journal of cluster science 2016, Vol.27 (1), p.1-8 |
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| creator | Sarmphim, Pharunee Chokprasombat, Komkrich Sirisathitkul, Chitnarong Sirisathitkul, Yaowarat Ratchaphonsaenwong, Kunthaya Pinitsoontorn, Supree Harding, Phimphaka |
| description | The liquid–air interface is demonstrated as a method to assemble nanoparticles synthesized from the reaction between iron (III) dibenzoylmethane (Fe(dbm)
3
) and platinum acetylacetonate (Pt(acac)
2
) into a long range monolayer. These surface-modified particles have average Fe to Pt atomic ratio of 0.77:1. The increase in surfactants further reduces the Fe:Pt ratio and increases the particle diameter to over 4 nm. The self-assembled pattern of FePt-based nanoparticles can be enhanced by dropping nanoparticle suspensions on the surface of diethelyne glycol (DEG). The concentrations of these nanoparticle suspensions in hexane from 0.2 to 0.4 mg/ml can be used without the agglomeration into multilayered islands. The voids in the self-assembled monolayer on the DEG-air interface are reduced to the minimum in the case of the lowest concentration. |
| doi_str_mv | 10.1007/s10876-015-0922-6 |
| format | Article |
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3
) and platinum acetylacetonate (Pt(acac)
2
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3
) and platinum acetylacetonate (Pt(acac)
2
) into a long range monolayer. These surface-modified particles have average Fe to Pt atomic ratio of 0.77:1. The increase in surfactants further reduces the Fe:Pt ratio and increases the particle diameter to over 4 nm. The self-assembled pattern of FePt-based nanoparticles can be enhanced by dropping nanoparticle suspensions on the surface of diethelyne glycol (DEG). The concentrations of these nanoparticle suspensions in hexane from 0.2 to 0.4 mg/ml can be used without the agglomeration into multilayered islands. The voids in the self-assembled monolayer on the DEG-air interface are reduced to the minimum in the case of the lowest concentration.</description><subject>Acids</subject><subject>Brief Communication</subject><subject>Catalysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diffraction</subject><subject>Hexanes</subject><subject>Inorganic Chemistry</subject><subject>Iron</subject><subject>Monolayers</subject><subject>Nanochemistry</subject><subject>Nanoparticles</subject><subject>Particle size</subject><subject>Physical Chemistry</subject><subject>Platinum</subject><subject>Self-assembled monolayers</subject><subject>Self-assembly</subject><subject>Surfactants</subject><issn>1040-7278</issn><issn>1572-8862</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kE1OwzAQRiMEEqVwAHaW2LQLg-0k_lmWikKlChDt3nKcCaRKnNZOhcqKO3BDTkKqILFiMzOL930jvSi6pOSaEiJuAiVScExoioliDPOjaEBTwbCUnB13N0kIFkzI0-gshDUhRMk4HkRuUW53Zf79-TUpPZq7FnxhLKAlVAWehAB1Vu1RU6BH45qN8W1pKwhouXftG4TyA3JU-KZGL2BsWzYO3UL7DuDQDEZ5Vo9jZFyOntuRscaO2Xl0UpgqwMXvHkar2d1q-oAXT_fz6WSBbUwoxyrmIrUphziVJE0YS1MmREK7WQgpDJM5WOCMW54ZyK2VvAAbK6UyahMaD6Orvnbjm-0OQqvXzc677qNmikqmCFWso2hPWd-E4KHQG1_Wxu81JfpgVfdWdWdVH6xq3mVYnwkd617B_zX_H_oBoiB5qA</recordid><startdate>2016</startdate><enddate>2016</enddate><creator>Sarmphim, Pharunee</creator><creator>Chokprasombat, Komkrich</creator><creator>Sirisathitkul, Chitnarong</creator><creator>Sirisathitkul, Yaowarat</creator><creator>Ratchaphonsaenwong, Kunthaya</creator><creator>Pinitsoontorn, Supree</creator><creator>Harding, Phimphaka</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>2016</creationdate><title>Liquid–Air Interface Self-Assembly of Nanoparticles Synthesized from Reaction Between Fe(dbm)3 and Pt(acac)2</title><author>Sarmphim, Pharunee ; Chokprasombat, Komkrich ; Sirisathitkul, Chitnarong ; Sirisathitkul, Yaowarat ; Ratchaphonsaenwong, Kunthaya ; Pinitsoontorn, Supree ; Harding, Phimphaka</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3016-93675c56e358054225527741527f787a28dece626c6baedcc86fec3999b1c413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acids</topic><topic>Brief Communication</topic><topic>Catalysis</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diffraction</topic><topic>Hexanes</topic><topic>Inorganic Chemistry</topic><topic>Iron</topic><topic>Monolayers</topic><topic>Nanochemistry</topic><topic>Nanoparticles</topic><topic>Particle size</topic><topic>Physical Chemistry</topic><topic>Platinum</topic><topic>Self-assembled monolayers</topic><topic>Self-assembly</topic><topic>Surfactants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sarmphim, Pharunee</creatorcontrib><creatorcontrib>Chokprasombat, Komkrich</creatorcontrib><creatorcontrib>Sirisathitkul, Chitnarong</creatorcontrib><creatorcontrib>Sirisathitkul, Yaowarat</creatorcontrib><creatorcontrib>Ratchaphonsaenwong, Kunthaya</creatorcontrib><creatorcontrib>Pinitsoontorn, Supree</creatorcontrib><creatorcontrib>Harding, Phimphaka</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of cluster science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sarmphim, Pharunee</au><au>Chokprasombat, Komkrich</au><au>Sirisathitkul, Chitnarong</au><au>Sirisathitkul, Yaowarat</au><au>Ratchaphonsaenwong, Kunthaya</au><au>Pinitsoontorn, Supree</au><au>Harding, Phimphaka</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Liquid–Air Interface Self-Assembly of Nanoparticles Synthesized from Reaction Between Fe(dbm)3 and Pt(acac)2</atitle><jtitle>Journal of cluster science</jtitle><stitle>J Clust Sci</stitle><date>2016</date><risdate>2016</risdate><volume>27</volume><issue>1</issue><spage>1</spage><epage>8</epage><pages>1-8</pages><issn>1040-7278</issn><eissn>1572-8862</eissn><abstract>The liquid–air interface is demonstrated as a method to assemble nanoparticles synthesized from the reaction between iron (III) dibenzoylmethane (Fe(dbm)
3
) and platinum acetylacetonate (Pt(acac)
2
) into a long range monolayer. These surface-modified particles have average Fe to Pt atomic ratio of 0.77:1. The increase in surfactants further reduces the Fe:Pt ratio and increases the particle diameter to over 4 nm. The self-assembled pattern of FePt-based nanoparticles can be enhanced by dropping nanoparticle suspensions on the surface of diethelyne glycol (DEG). The concentrations of these nanoparticle suspensions in hexane from 0.2 to 0.4 mg/ml can be used without the agglomeration into multilayered islands. The voids in the self-assembled monolayer on the DEG-air interface are reduced to the minimum in the case of the lowest concentration.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10876-015-0922-6</doi><tpages>8</tpages></addata></record> |
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| subjects | Acids Brief Communication Catalysis Chemical synthesis Chemistry Chemistry and Materials Science Diffraction Hexanes Inorganic Chemistry Iron Monolayers Nanochemistry Nanoparticles Particle size Physical Chemistry Platinum Self-assembled monolayers Self-assembly Surfactants |
| title | Liquid–Air Interface Self-Assembly of Nanoparticles Synthesized from Reaction Between Fe(dbm)3 and Pt(acac)2 |
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