Microwave Promoted Oxidative Addition Reactions of Os3(CO)12: Efficient Syntheses of Triosmium Clusters of the Type Os3(μ-X)2(CO)10 and Os3(μ-H)(μ-OR)(CO)10

Microwave heating allows for the high-yield, one-step synthesis of the known triosmium complexes Os 3 (μ-Br) 2 (CO) 10 ( 1 ), Os 3 (μ-I) 2 (CO) 10 ( 2 ), and Os 3 (μ-H)(μ-OR)(CO) 10 with R  = methyl ( 3 ), ethyl ( 4 ), isopropyl ( 5 ), n -butyl ( 6 ), and phenyl ( 7 ). In addition, the new clusters...

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