Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation
A novel polyoxometalate-based compound, [H(atrz)] 4 [(atrz) 2 (Mo 8 O 26 )]·2H 2 O ( 1 ) (atrz = 3-amino-1,2,4-triazole), has been synthesized by traditional hydrothermal method, and characterized by means of elemental analysis, FT-IR spectroscopy, Powder X-ray diffraction and single-crystal X-ray....
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| Veröffentlicht in: | Journal of cluster science 2014-09, Vol.25 (5), p.1263-1272 |
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| creator | Gao, Hongcheng Yu, Jiehui Du, Juan Niu, Huiling Wang, Jing Song, Xiaojing Zhang, Wenxiang Jia, Mingjun |
| description | A novel polyoxometalate-based compound, [H(atrz)]
4
[(atrz)
2
(Mo
8
O
26
)]·2H
2
O (
1
) (atrz = 3-amino-1,2,4-triazole), has been synthesized by traditional hydrothermal method, and characterized by means of elemental analysis, FT-IR spectroscopy, Powder X-ray diffraction and single-crystal X-ray. The compound
1
contains a 2D supramolecualr layer which is constructed from [(atrz)
2
(γ-Mo
8
O
26
)]
4−
units via intermolecular hydrogen-bonding interactions. Furthermore, the adjacent 2D layers are packed together through the aromatic π⋯π stacking interactions and exhibits a 3D supramolecular structure. The catalytic properties of
1
were investigated in olefin epoxidation with
tert
-butylhydroperoxide (
t
-BuOOH) as the oxidant. It was found that compound
1
could serve as active and stable heterogeneous catalyst for the epoxidation of cyclooctene and 1-octence. Besides, introducing copper ions into compound
1
could further improve the catalytic activity for olefin epoxidation. |
| doi_str_mv | 10.1007/s10876-014-0704-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2918277497</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2918277497</sourcerecordid><originalsourceid>FETCH-LOGICAL-c386t-bad9318468e53e01641878fbd7b351b7f9667fbaf2c65437b5f3173dac44e3b03</originalsourceid><addsrcrecordid>eNp1kM1OwzAQhC0EEqXwANwscQ7YsWM73EooP1KlHlrOlu04KFWaBNtBhDfgrXEJEidOs9r9ZlYaAC4xusYI8RuPkeAsQZgmiCOasCMwwxlPEyFYehxnRFHCUy5OwZn3O4RQLgiZga_N0Du17xprhkY5uPDe7nUzwjvlbQm7Fq5NONxHXapgoWpLuHW1-owOeG9d_a5C_W5vYeFGH1QDN8ENJgxuQgsVd2OoDVz0fVObCMfIOqY2toqy7LuPuvzZnoOTSjXeXvzqHLw8LLfFU7JaPz4Xi1ViiGAh0arMCRaUCZsRizCjWHBR6ZJrkmHNq5wxXmlVpYZllHCdVQRzUipDqSUakTm4mnJ7170N1ge56wbXxpcyzbFIOac5jxSeKOM6752tZO_qvXKjxEgeGpdT4zI2Lg-NSxY96eTxkW1frftL_t_0DbSHhfM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2918277497</pqid></control><display><type>article</type><title>Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation</title><source>ProQuest Central Essentials</source><source>ProQuest Central (Alumni Edition)</source><source>ProQuest Central Student</source><source>SpringerNature Journals</source><source>ProQuest Central Korea</source><source>ProQuest Central UK/Ireland</source><source>ProQuest Central</source><creator>Gao, Hongcheng ; Yu, Jiehui ; Du, Juan ; Niu, Huiling ; Wang, Jing ; Song, Xiaojing ; Zhang, Wenxiang ; Jia, Mingjun</creator><creatorcontrib>Gao, Hongcheng ; Yu, Jiehui ; Du, Juan ; Niu, Huiling ; Wang, Jing ; Song, Xiaojing ; Zhang, Wenxiang ; Jia, Mingjun</creatorcontrib><description>A novel polyoxometalate-based compound, [H(atrz)]
4
[(atrz)
2
(Mo
8
O
26
)]·2H
2
O (
1
) (atrz = 3-amino-1,2,4-triazole), has been synthesized by traditional hydrothermal method, and characterized by means of elemental analysis, FT-IR spectroscopy, Powder X-ray diffraction and single-crystal X-ray. The compound
1
contains a 2D supramolecualr layer which is constructed from [(atrz)
2
(γ-Mo
8
O
26
)]
4−
units via intermolecular hydrogen-bonding interactions. Furthermore, the adjacent 2D layers are packed together through the aromatic π⋯π stacking interactions and exhibits a 3D supramolecular structure. The catalytic properties of
1
were investigated in olefin epoxidation with
tert
-butylhydroperoxide (
t
-BuOOH) as the oxidant. It was found that compound
1
could serve as active and stable heterogeneous catalyst for the epoxidation of cyclooctene and 1-octence. Besides, introducing copper ions into compound
1
could further improve the catalytic activity for olefin epoxidation.</description><identifier>ISSN: 1040-7278</identifier><identifier>EISSN: 1572-8862</identifier><identifier>DOI: 10.1007/s10876-014-0704-6</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Catalysis ; Catalytic activity ; Chemical analysis ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Epoxidation ; Fourier transforms ; Hydrogen bonding ; Hydrogen bonds ; Hydrothermal crystal growth ; Infrared spectroscopy ; Inorganic Chemistry ; Ligands ; Nanochemistry ; Original Paper ; Oxidizing agents ; Physical Chemistry ; Polyoxometallates ; Radiation ; Reagents ; Single crystals ; Triazoles ; X ray powder diffraction</subject><ispartof>Journal of cluster science, 2014-09, Vol.25 (5), p.1263-1272</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>Springer Science+Business Media New York 2014.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-bad9318468e53e01641878fbd7b351b7f9667fbaf2c65437b5f3173dac44e3b03</citedby><cites>FETCH-LOGICAL-c386t-bad9318468e53e01641878fbd7b351b7f9667fbaf2c65437b5f3173dac44e3b03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10876-014-0704-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918277497?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,21389,21390,21391,23256,27924,27925,33530,33703,33744,34005,34314,41488,42557,43659,43787,43805,43953,44067,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Gao, Hongcheng</creatorcontrib><creatorcontrib>Yu, Jiehui</creatorcontrib><creatorcontrib>Du, Juan</creatorcontrib><creatorcontrib>Niu, Huiling</creatorcontrib><creatorcontrib>Wang, Jing</creatorcontrib><creatorcontrib>Song, Xiaojing</creatorcontrib><creatorcontrib>Zhang, Wenxiang</creatorcontrib><creatorcontrib>Jia, Mingjun</creatorcontrib><title>Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation</title><title>Journal of cluster science</title><addtitle>J Clust Sci</addtitle><description>A novel polyoxometalate-based compound, [H(atrz)]
4
[(atrz)
2
(Mo
8
O
26
)]·2H
2
O (
1
) (atrz = 3-amino-1,2,4-triazole), has been synthesized by traditional hydrothermal method, and characterized by means of elemental analysis, FT-IR spectroscopy, Powder X-ray diffraction and single-crystal X-ray. The compound
1
contains a 2D supramolecualr layer which is constructed from [(atrz)
2
(γ-Mo
8
O
26
)]
4−
units via intermolecular hydrogen-bonding interactions. Furthermore, the adjacent 2D layers are packed together through the aromatic π⋯π stacking interactions and exhibits a 3D supramolecular structure. The catalytic properties of
1
were investigated in olefin epoxidation with
tert
-butylhydroperoxide (
t
-BuOOH) as the oxidant. It was found that compound
1
could serve as active and stable heterogeneous catalyst for the epoxidation of cyclooctene and 1-octence. Besides, introducing copper ions into compound
1
could further improve the catalytic activity for olefin epoxidation.</description><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Chemical analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Epoxidation</subject><subject>Fourier transforms</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Hydrothermal crystal growth</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Nanochemistry</subject><subject>Original Paper</subject><subject>Oxidizing agents</subject><subject>Physical Chemistry</subject><subject>Polyoxometallates</subject><subject>Radiation</subject><subject>Reagents</subject><subject>Single crystals</subject><subject>Triazoles</subject><subject>X ray powder diffraction</subject><issn>1040-7278</issn><issn>1572-8862</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kM1OwzAQhC0EEqXwANwscQ7YsWM73EooP1KlHlrOlu04KFWaBNtBhDfgrXEJEidOs9r9ZlYaAC4xusYI8RuPkeAsQZgmiCOasCMwwxlPEyFYehxnRFHCUy5OwZn3O4RQLgiZga_N0Du17xprhkY5uPDe7nUzwjvlbQm7Fq5NONxHXapgoWpLuHW1-owOeG9d_a5C_W5vYeFGH1QDN8ENJgxuQgsVd2OoDVz0fVObCMfIOqY2toqy7LuPuvzZnoOTSjXeXvzqHLw8LLfFU7JaPz4Xi1ViiGAh0arMCRaUCZsRizCjWHBR6ZJrkmHNq5wxXmlVpYZllHCdVQRzUipDqSUakTm4mnJ7170N1ge56wbXxpcyzbFIOac5jxSeKOM6752tZO_qvXKjxEgeGpdT4zI2Lg-NSxY96eTxkW1frftL_t_0DbSHhfM</recordid><startdate>20140901</startdate><enddate>20140901</enddate><creator>Gao, Hongcheng</creator><creator>Yu, Jiehui</creator><creator>Du, Juan</creator><creator>Niu, Huiling</creator><creator>Wang, Jing</creator><creator>Song, Xiaojing</creator><creator>Zhang, Wenxiang</creator><creator>Jia, Mingjun</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20140901</creationdate><title>Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation</title><author>Gao, Hongcheng ; Yu, Jiehui ; Du, Juan ; Niu, Huiling ; Wang, Jing ; Song, Xiaojing ; Zhang, Wenxiang ; Jia, Mingjun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-bad9318468e53e01641878fbd7b351b7f9667fbaf2c65437b5f3173dac44e3b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Chemical analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Epoxidation</topic><topic>Fourier transforms</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Hydrothermal crystal growth</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Nanochemistry</topic><topic>Original Paper</topic><topic>Oxidizing agents</topic><topic>Physical Chemistry</topic><topic>Polyoxometallates</topic><topic>Radiation</topic><topic>Reagents</topic><topic>Single crystals</topic><topic>Triazoles</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Hongcheng</creatorcontrib><creatorcontrib>Yu, Jiehui</creatorcontrib><creatorcontrib>Du, Juan</creatorcontrib><creatorcontrib>Niu, Huiling</creatorcontrib><creatorcontrib>Wang, Jing</creatorcontrib><creatorcontrib>Song, Xiaojing</creatorcontrib><creatorcontrib>Zhang, Wenxiang</creatorcontrib><creatorcontrib>Jia, Mingjun</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of cluster science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Hongcheng</au><au>Yu, Jiehui</au><au>Du, Juan</au><au>Niu, Huiling</au><au>Wang, Jing</au><au>Song, Xiaojing</au><au>Zhang, Wenxiang</au><au>Jia, Mingjun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation</atitle><jtitle>Journal of cluster science</jtitle><stitle>J Clust Sci</stitle><date>2014-09-01</date><risdate>2014</risdate><volume>25</volume><issue>5</issue><spage>1263</spage><epage>1272</epage><pages>1263-1272</pages><issn>1040-7278</issn><eissn>1572-8862</eissn><abstract>A novel polyoxometalate-based compound, [H(atrz)]
4
[(atrz)
2
(Mo
8
O
26
)]·2H
2
O (
1
) (atrz = 3-amino-1,2,4-triazole), has been synthesized by traditional hydrothermal method, and characterized by means of elemental analysis, FT-IR spectroscopy, Powder X-ray diffraction and single-crystal X-ray. The compound
1
contains a 2D supramolecualr layer which is constructed from [(atrz)
2
(γ-Mo
8
O
26
)]
4−
units via intermolecular hydrogen-bonding interactions. Furthermore, the adjacent 2D layers are packed together through the aromatic π⋯π stacking interactions and exhibits a 3D supramolecular structure. The catalytic properties of
1
were investigated in olefin epoxidation with
tert
-butylhydroperoxide (
t
-BuOOH) as the oxidant. It was found that compound
1
could serve as active and stable heterogeneous catalyst for the epoxidation of cyclooctene and 1-octence. Besides, introducing copper ions into compound
1
could further improve the catalytic activity for olefin epoxidation.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10876-014-0704-6</doi><tpages>10</tpages></addata></record> |
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| identifier | ISSN: 1040-7278 |
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| language | eng |
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| source | ProQuest Central Essentials; ProQuest Central (Alumni Edition); ProQuest Central Student; SpringerNature Journals; ProQuest Central Korea; ProQuest Central UK/Ireland; ProQuest Central |
| subjects | Catalysis Catalytic activity Chemical analysis Chemistry Chemistry and Materials Science Crystal structure Epoxidation Fourier transforms Hydrogen bonding Hydrogen bonds Hydrothermal crystal growth Infrared spectroscopy Inorganic Chemistry Ligands Nanochemistry Original Paper Oxidizing agents Physical Chemistry Polyoxometallates Radiation Reagents Single crystals Triazoles X ray powder diffraction |
| title | Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation |
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