Diacetylenic Derivatives of Fe2(CO)6(μ-EE′): Spectroscopic Investigations of Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} (E = E′, E ≠ E′; E, E′ = S, Se, Te)

The diacetylenic adducts, Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} (E = E′, E ≠ E′; E, E′ = S, Se, Te) (1–8) have been obtained from the room temperature stirring of Fe2(CO)6(μ-EE′) with HC ≡ CC ≡ CMe in methanol solvent containing sodium acetate. Compounds 1–8 have been characterized by IR and multinuclear...

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Veröffentlicht in:	Journal of cluster science 1998-06, Vol.9 (2), p.131-143
Hauptverfasser:	Mathur, Pradeep, Dash, Aswini K
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts NMR Nuclear magnetic resonance Room temperature Selenium Sodium acetate Tellurium
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description	The diacetylenic adducts, Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} (E = E′, E ≠ E′; E, E′ = S, Se, Te) (1–8) have been obtained from the room temperature stirring of Fe2(CO)6(μ-EE′) with HC ≡ CC ≡ CMe in methanol solvent containing sodium acetate. Compounds 1–8 have been characterized by IR and multinuclear NMR (1H, 13C, 77Se, and l25Te) spectroscopy. Trends in the chemical shifts of 77Se and 125Te NMR spectra of Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} with a variation of EE′ are discussed.
doi_str_mv	10.1023/A:1021937931974
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Compounds 1–8 have been characterized by IR and multinuclear NMR (1H, 13C, 77Se, and l25Te) spectroscopy. 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Compounds 1–8 have been characterized by IR and multinuclear NMR (1H, 13C, 77Se, and l25Te) spectroscopy. Trends in the chemical shifts of 77Se and 125Te NMR spectra of Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} with a variation of EE′ are discussed.</description><subject>Adducts</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Room temperature</subject><subject>Selenium</subject><subject>Sodium acetate</subject><subject>Tellurium</subject><issn>1040-7278</issn><issn>1572-8862</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNpVj81OwkAUhSdGExFdu53ETZu0Oj-dPwwLMhQhwbCAPSnDYEpIW9tCYoyJW94CX8G1z-BD8CQO6MbVPbnnfufmAHCN0S1GhN51Wm5gRYWiWInoBDQwEySUkpNTp1GEQkGEPAcXVbVECClJaQPsumlibP2ysllqYNeW6Sap042tYL6APUs8PfK59_0VxvH-_dNvwXFhTV3mlckLBwwyd1qnT47Js3_M64HRXt-Hbag9vd9-QP1o_UPKG_Ritz3IAMZwv90d9T2Mg6Nw3jiAYxvAifUvwdkiWVX26m82waQXT3Q_HI4eBrozDAvF63Bu-YwZRrhBRrmuMySFUcSShCMuo4gz5zPOF4mKpFFzrBhJ5iwy2DFsRmkT3PzGFmX-vHadpst8XWbu45QoLInglHH6A76ca6Q</recordid><startdate>19980601</startdate><enddate>19980601</enddate><creator>Mathur, Pradeep</creator><creator>Dash, Aswini K</creator><general>Springer Nature B.V</general><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>19980601</creationdate><title>Diacetylenic Derivatives of Fe2(CO)6(μ-EE′): Spectroscopic Investigations of Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} (E = E′, E ≠ E′; E, E′ = S, Se, Te)</title><author>Mathur, Pradeep ; Dash, Aswini K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p96t-de6b5c526c0c9104b087c92e2a606844656b5566fa948c9d1952ad54c15265b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Adducts</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Room temperature</topic><topic>Selenium</topic><topic>Sodium acetate</topic><topic>Tellurium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mathur, Pradeep</creatorcontrib><creatorcontrib>Dash, Aswini K</creatorcontrib><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>Science Database</collection><collection>ProQuest advanced technologies & aerospace journals</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of cluster science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mathur, Pradeep</au><au>Dash, Aswini K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diacetylenic Derivatives of Fe2(CO)6(μ-EE′): Spectroscopic Investigations of Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} (E = E′, E ≠ E′; E, E′ = S, Se, Te)</atitle><jtitle>Journal of cluster science</jtitle><date>1998-06-01</date><risdate>1998</risdate><volume>9</volume><issue>2</issue><spage>131</spage><epage>143</epage><pages>131-143</pages><issn>1040-7278</issn><eissn>1572-8862</eissn><abstract>The diacetylenic adducts, Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} (E = E′, E ≠ E′; E, E′ = S, Se, Te) (1–8) have been obtained from the room temperature stirring of Fe2(CO)6(μ-EE′) with HC ≡ CC ≡ CMe in methanol solvent containing sodium acetate. Compounds 1–8 have been characterized by IR and multinuclear NMR (1H, 13C, 77Se, and l25Te) spectroscopy. Trends in the chemical shifts of 77Se and 125Te NMR spectra of Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} with a variation of EE′ are discussed.</abstract><cop>New York</cop><pub>Springer Nature B.V</pub><doi>10.1023/A:1021937931974</doi><tpages>13</tpages></addata></record>
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subjects	Adducts NMR Nuclear magnetic resonance Room temperature Selenium Sodium acetate Tellurium
title	Diacetylenic Derivatives of Fe2(CO)6(μ-EE′): Spectroscopic Investigations of Fe2(CO)6{μ-EC(H) = C(C≡ CMe)E′} (E = E′, E ≠ E′; E, E′ = S, Se, Te)
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