Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs
N,N′−Diphenylamidines and the silver(I) complexes of their deprotonated anions have been synthesized. Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring...
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| Veröffentlicht in: | Journal of cluster science 2000-03, Vol.11 (1), p.261-283 |
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| creator | Archibald, Stephen J Alcock, Nathaniel W Busch, Daryle H Whitcomb, David R |
| description | N,N′−Diphenylamidines and the silver(I) complexes of their deprotonated anions have been synthesized. Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring resulted in a cationic silver trimer in which hydrogen bonding links silver(I)-bound water molecules to the methoxy substituents. The thermal stabilities of the tetrameric species vary with alkyl chain length. The new complexes are: tetrakis(N,N′-diphenylpropamidinato) tetra silver(I), 1, tetrakis(N,N′-diphenylbutamidinato) tetrasilver(I) 2, tetrakis(N,N′-diphenylpentamidinato) tetra silver(I) 3, (N,N′-diphenyloctamidinato)silver(I) 4, (tetrakis(N,N′-di(4-n-butyl)phenylpropamidinato)tetrasilver(I), 5, bis(N,N′-di(2-methoxy)phenylacetamidinato)diaquatrisilver(I) nitrate 6 and tetrakis(N,N′-di(4-methoxy)phenylacetamidinato) tetrasilver(I), 7. Compounds 1, 5, 6 and 7 were structurally characterized by X-ray methods. |
| doi_str_mv | 10.1023/A:1009085319864 |
| format | Article |
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Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring resulted in a cationic silver trimer in which hydrogen bonding links silver(I)-bound water molecules to the methoxy substituents. The thermal stabilities of the tetrameric species vary with alkyl chain length. The new complexes are: tetrakis(N,N′-diphenylpropamidinato) tetra silver(I), 1, tetrakis(N,N′-diphenylbutamidinato) tetrasilver(I) 2, tetrakis(N,N′-diphenylpentamidinato) tetra silver(I) 3, (N,N′-diphenyloctamidinato)silver(I) 4, (tetrakis(N,N′-di(4-n-butyl)phenylpropamidinato)tetrasilver(I), 5, bis(N,N′-di(2-methoxy)phenylacetamidinato)diaquatrisilver(I) nitrate 6 and tetrakis(N,N′-di(4-methoxy)phenylacetamidinato) tetrasilver(I), 7. 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Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring resulted in a cationic silver trimer in which hydrogen bonding links silver(I)-bound water molecules to the methoxy substituents. The thermal stabilities of the tetrameric species vary with alkyl chain length. The new complexes are: tetrakis(N,N′-diphenylpropamidinato) tetra silver(I), 1, tetrakis(N,N′-diphenylbutamidinato) tetrasilver(I) 2, tetrakis(N,N′-diphenylpentamidinato) tetra silver(I) 3, (N,N′-diphenyloctamidinato)silver(I) 4, (tetrakis(N,N′-di(4-n-butyl)phenylpropamidinato)tetrasilver(I), 5, bis(N,N′-di(2-methoxy)phenylacetamidinato)diaquatrisilver(I) nitrate 6 and tetrakis(N,N′-di(4-methoxy)phenylacetamidinato) tetrasilver(I), 7. Compounds 1, 5, 6 and 7 were structurally characterized by X-ray methods.</description><subject>Functional groups</subject><subject>Hydrogen bonding</subject><subject>Trimers</subject><issn>1040-7278</issn><issn>1572-8862</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNotkE1OwzAUhC0EEqWwZmuJDUgE_JPEdndVoFCplEXLunITR3Fxk2A7QLviFByEI3ESDGX15kmjGc0HwClGVxgRej0cYIQE4gnFgqfxHujhhJGI85TsB41iFDHC-CE4cm6FgpVT2gOfs03tK-W0g7IuYFZJK3OvrN5Kr5saNiWcafOq7Pn4AmbNujXqXTn4pn0Fs2honjcGjro6_zVLo7eqgNPL6ffHV3Sj20rVGyPXutC19MoN4Fx5K9chPf9rm1u9e2bedrnvrDTwofG6dMfgoJTGqZP_2wdPo9t5dh9NHu_G2XAStZhjH2EslVzGYslSxgtBMM8F4wSJQASXLKVxgVhR0iROAwYhOcEpyhMkBYuJCgD64GyX29rmpVPOL1ZNZ8MStyACc8ISjmL6Ax3Majk</recordid><startdate>20000301</startdate><enddate>20000301</enddate><creator>Archibald, Stephen J</creator><creator>Alcock, Nathaniel W</creator><creator>Busch, Daryle H</creator><creator>Whitcomb, David R</creator><general>Springer Nature B.V</general><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20000301</creationdate><title>Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs</title><author>Archibald, Stephen J ; Alcock, Nathaniel W ; Busch, Daryle H ; Whitcomb, David R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p181t-11aeab49b7678d9218c9782091021f7634d07df35468629a82160c50a9742e833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Functional groups</topic><topic>Hydrogen bonding</topic><topic>Trimers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Archibald, Stephen J</creatorcontrib><creatorcontrib>Alcock, Nathaniel W</creatorcontrib><creatorcontrib>Busch, Daryle H</creatorcontrib><creatorcontrib>Whitcomb, David R</creatorcontrib><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of cluster science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Archibald, Stephen J</au><au>Alcock, Nathaniel W</au><au>Busch, Daryle H</au><au>Whitcomb, David R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs</atitle><jtitle>Journal of cluster science</jtitle><date>2000-03-01</date><risdate>2000</risdate><volume>11</volume><issue>1</issue><spage>261</spage><epage>283</epage><pages>261-283</pages><issn>1040-7278</issn><eissn>1572-8862</eissn><abstract>N,N′−Diphenylamidines and the silver(I) complexes of their deprotonated anions have been synthesized. Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring resulted in a cationic silver trimer in which hydrogen bonding links silver(I)-bound water molecules to the methoxy substituents. The thermal stabilities of the tetrameric species vary with alkyl chain length. The new complexes are: tetrakis(N,N′-diphenylpropamidinato) tetra silver(I), 1, tetrakis(N,N′-diphenylbutamidinato) tetrasilver(I) 2, tetrakis(N,N′-diphenylpentamidinato) tetra silver(I) 3, (N,N′-diphenyloctamidinato)silver(I) 4, (tetrakis(N,N′-di(4-n-butyl)phenylpropamidinato)tetrasilver(I), 5, bis(N,N′-di(2-methoxy)phenylacetamidinato)diaquatrisilver(I) nitrate 6 and tetrakis(N,N′-di(4-methoxy)phenylacetamidinato) tetrasilver(I), 7. Compounds 1, 5, 6 and 7 were structurally characterized by X-ray methods.</abstract><cop>New York</cop><pub>Springer Nature B.V</pub><doi>10.1023/A:1009085319864</doi><tpages>23</tpages></addata></record> |
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| subjects | Functional groups Hydrogen bonding Trimers |
| title | Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs |
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