Synthetic method of polyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid via reversible addition-fragmentation chain transfer (RAFT) polymerization with functionalized polyethylene
SummaryPolyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid was synthesized via RAFT polymerization of MMA with PE chain transfer agent (PE-CTA) for the first time. The structure of PE-CTA produced by sequential functionalization of terminally hydroxylated PE was confirmed by 1H NMR and FT...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2006-10, Vol.57 (6), p.805-812 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | KAWAHARA, Nobuo KOJOH, Shin-Ichi MATSUO, Shingo KANEKO, Hideyuki MATSUGI, Tomoaki SAITO, Junji KASHIWA, Norio |
| description | SummaryPolyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid was synthesized via RAFT polymerization of MMA with PE chain transfer agent (PE-CTA) for the first time. The structure of PE-CTA produced by sequential functionalization of terminally hydroxylated PE was confirmed by 1H NMR and FT-IR analyses. The results of GPC after MMA polymerization revealed that the molecular weight (Mw) of the resulting polymers increased compared with the one of the PE-CTA. 1H NMR analysis of resulting polymers confirmed that the amounts of PMMA segments were in a range of 7.8 and 23 wt %. TEM images indicated the nanometer level microphase-separation morphology between the PE segment and PMMA segment. |
| doi_str_mv | 10.1007/s00289-006-0642-z |
| format | Article |
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The structure of PE-CTA produced by sequential functionalization of terminally hydroxylated PE was confirmed by 1H NMR and FT-IR analyses. The results of GPC after MMA polymerization revealed that the molecular weight (Mw) of the resulting polymers increased compared with the one of the PE-CTA. 1H NMR analysis of resulting polymers confirmed that the amounts of PMMA segments were in a range of 7.8 and 23 wt %. TEM images indicated the nanometer level microphase-separation morphology between the PE segment and PMMA segment.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-006-0642-z</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Addition polymerization ; Applied sciences ; Chain transfer ; Exact sciences and technology ; NMR ; Nuclear magnetic resonance ; Organic polymers ; Physicochemistry of polymers ; Polyethylenes ; Polymerization ; Polymers ; Polymethyl methacrylate ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Segments</subject><ispartof>Polymer bulletin (Berlin, Germany), 2006-10, Vol.57 (6), p.805-812</ispartof><rights>2007 INIST-CNRS</rights><rights>Springer-Verlag 2006. This work is published under http://creativecommons.org/licenses/by-nc/2/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-a86f03e7aeb02c00ab1709e356b9198e5bd7285c06bffc972a0195c0d2b664113</citedby><cites>FETCH-LOGICAL-c346t-a86f03e7aeb02c00ab1709e356b9198e5bd7285c06bffc972a0195c0d2b664113</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2918112369?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,43805,64385,64389,72469</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18247927$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>KAWAHARA, Nobuo</creatorcontrib><creatorcontrib>KOJOH, Shin-Ichi</creatorcontrib><creatorcontrib>MATSUO, Shingo</creatorcontrib><creatorcontrib>KANEKO, Hideyuki</creatorcontrib><creatorcontrib>MATSUGI, Tomoaki</creatorcontrib><creatorcontrib>SAITO, Junji</creatorcontrib><creatorcontrib>KASHIWA, Norio</creatorcontrib><title>Synthetic method of polyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid via reversible addition-fragmentation chain transfer (RAFT) polymerization with functionalized polyethylene</title><title>Polymer bulletin (Berlin, Germany)</title><description>SummaryPolyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid was synthesized via RAFT polymerization of MMA with PE chain transfer agent (PE-CTA) for the first time. The structure of PE-CTA produced by sequential functionalization of terminally hydroxylated PE was confirmed by 1H NMR and FT-IR analyses. The results of GPC after MMA polymerization revealed that the molecular weight (Mw) of the resulting polymers increased compared with the one of the PE-CTA. 1H NMR analysis of resulting polymers confirmed that the amounts of PMMA segments were in a range of 7.8 and 23 wt %. TEM images indicated the nanometer level microphase-separation morphology between the PE segment and PMMA segment.</description><subject>Addition polymerization</subject><subject>Applied sciences</subject><subject>Chain transfer</subject><subject>Exact sciences and technology</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyethylenes</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polymethyl methacrylate</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Segments</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpVkV9rFDEUxYMouFY_gG8BEbYP0ZvMbGbyuJRWhZYWrc8hk7lxUubPmmRbZj-cn81Mt1R8uZcfnHO43EPIew6fOED1OQKIWjEAyUCWgh1ekBUvC8lEWaqXZAW8AgZ1oV6TNzHeQWYp-Yr8-TGPqcPkLR0wdVNLJ0d3Uz9nmHsckS2wHh5xmcaGuTcJT-n65pzdXF1tTx_1AwbazU3wLb33hga8xxB90yM1beuTn0bmgvk14JjMQtR2xo80BTNGl73r79uL2-cofziKHnzqqNuPdiHT-wO2_133lrxypo_47mmfkJ8X57dnX9nl9ZdvZ9tLZotSJmZq6aDAymADwgKYJr9DYbGRjeKqxk3TVqLeWJCNc1ZVwgBXGVvRSFlyXpyQD8fcXZh-7zEmfTftQ74oaqF4zbkopMoqflTZMMUY0Old8IMJs-agl5r0sSada9JLTfqQPR-fkk20ps8_Gq2P_4y1KCslquIvtKeX8Q</recordid><startdate>20061001</startdate><enddate>20061001</enddate><creator>KAWAHARA, Nobuo</creator><creator>KOJOH, Shin-Ichi</creator><creator>MATSUO, Shingo</creator><creator>KANEKO, Hideyuki</creator><creator>MATSUGI, Tomoaki</creator><creator>SAITO, Junji</creator><creator>KASHIWA, Norio</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20061001</creationdate><title>Synthetic method of polyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid via reversible addition-fragmentation chain transfer (RAFT) polymerization with functionalized polyethylene</title><author>KAWAHARA, Nobuo ; KOJOH, Shin-Ichi ; MATSUO, Shingo ; KANEKO, Hideyuki ; MATSUGI, Tomoaki ; SAITO, Junji ; KASHIWA, Norio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-a86f03e7aeb02c00ab1709e356b9198e5bd7285c06bffc972a0195c0d2b664113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Addition polymerization</topic><topic>Applied sciences</topic><topic>Chain transfer</topic><topic>Exact sciences and technology</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polyethylenes</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polymethyl methacrylate</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Segments</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KAWAHARA, Nobuo</creatorcontrib><creatorcontrib>KOJOH, Shin-Ichi</creatorcontrib><creatorcontrib>MATSUO, Shingo</creatorcontrib><creatorcontrib>KANEKO, Hideyuki</creatorcontrib><creatorcontrib>MATSUGI, Tomoaki</creatorcontrib><creatorcontrib>SAITO, Junji</creatorcontrib><creatorcontrib>KASHIWA, Norio</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KAWAHARA, Nobuo</au><au>KOJOH, Shin-Ichi</au><au>MATSUO, Shingo</au><au>KANEKO, Hideyuki</au><au>MATSUGI, Tomoaki</au><au>SAITO, Junji</au><au>KASHIWA, Norio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthetic method of polyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid via reversible addition-fragmentation chain transfer (RAFT) polymerization with functionalized polyethylene</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>2006-10-01</date><risdate>2006</risdate><volume>57</volume><issue>6</issue><spage>805</spage><epage>812</epage><pages>805-812</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>SummaryPolyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid was synthesized via RAFT polymerization of MMA with PE chain transfer agent (PE-CTA) for the first time. The structure of PE-CTA produced by sequential functionalization of terminally hydroxylated PE was confirmed by 1H NMR and FT-IR analyses. The results of GPC after MMA polymerization revealed that the molecular weight (Mw) of the resulting polymers increased compared with the one of the PE-CTA. 1H NMR analysis of resulting polymers confirmed that the amounts of PMMA segments were in a range of 7.8 and 23 wt %. TEM images indicated the nanometer level microphase-separation morphology between the PE segment and PMMA segment.</abstract><cop>Heidelberg</cop><cop>Berlin</cop><cop>New York, NY</cop><pub>Springer</pub><doi>10.1007/s00289-006-0642-z</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Addition polymerization Applied sciences Chain transfer Exact sciences and technology NMR Nuclear magnetic resonance Organic polymers Physicochemistry of polymers Polyethylenes Polymerization Polymers Polymethyl methacrylate Preparation, kinetics, thermodynamics, mechanism and catalysts Segments |
| title | Synthetic method of polyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid via reversible addition-fragmentation chain transfer (RAFT) polymerization with functionalized polyethylene |
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