Synthesis of ambient temperature self-crosslinking VTES-based core–shell polyacrylate emulsion via modified micro-emulsion polymerization process

Modified micro-emulsion polymerization was successfully used to synthesize a kind of ambient temperature self-crosslinking core–shell emulsion, consisting of polyacrylate core and vinyltriethoxysilane (VTES) modified polyacrylate shell, by varying the ratio of soft monomer (BA) and hard monomer (MMA...

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Veröffentlicht in:	Polymer bulletin (Berlin, Germany) Germany), 2013-05, Vol.70 (5), p.1631-1645
Hauptverfasser:	Zhang, Yun-fei, Miao, Lei, Yang, Chao-long, Lu, Man-geng
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylic resins Ambient temperature Applied sciences Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Contact angle Copolymerization Core-shell structure Crosslinking Differential scanning calorimetry Emulsion polymerization Exact sciences and technology Fourier transforms Glass transition temperature Latex Mechanical properties Microemulsions Monomers Nitrogen Organic Chemistry Organic polymers Original Paper Particle size Photomicrographs Physical Chemistry Physicochemistry of polymers Polymer Sciences Preparation, kinetics, thermodynamics, mechanism and catalysts Sodium Soft and Granular Matter Spectrum analysis Surface properties Thermal stability Thermodynamic properties Thermogravimetric analysis Transmission electron microscopy VOCs Volatile organic compounds Water resistance
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