Molecular Dynamics of Alkenylphenol Derivatives in Solution as Studied by NMR Spectroscopy
The formation of hydrogen bonds and molecular dynamics of alkenylphenol derivatives has been investigated in solution using nuclear magnetic resonance. The results confirm formation of an N···H, O···H-type intramolecular hydrogen bond. The spin–lattice relaxation times ( T 1 ) and activation energy...
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Veröffentlicht in: | Applied magnetic resonance 2010-06, Vol.38 (3), p.257-269 |
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creator | Mamedov, Ibrahim Garib Eichhoff, U. Maharramov, A. M. Bayramov, M. R. Mamedova, Y. V. |
description | The formation of hydrogen bonds and molecular dynamics of alkenylphenol derivatives has been investigated in solution using nuclear magnetic resonance. The results confirm formation of an N···H, O···H-type intramolecular hydrogen bond. The spin–lattice relaxation times (
T
1
) and activation energy of molecular dynamics have been investigated confirming the importance of relaxation times as a very sensitive tool for studying molecular mobility. |
doi_str_mv | 10.1007/s00723-010-0117-0 |
format | Article |
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T
1
) and activation energy of molecular dynamics have been investigated confirming the importance of relaxation times as a very sensitive tool for studying molecular mobility.</description><identifier>ISSN: 0937-9347</identifier><identifier>EISSN: 1613-7507</identifier><identifier>DOI: 10.1007/s00723-010-0117-0</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Atoms and Molecules in Strong Fields ; Chemical bonds ; Hydrocarbons ; Hydrogen bonds ; Laser Matter Interaction ; Molecular dynamics ; NMR ; NMR spectroscopy ; Nuclear magnetic resonance ; Organic Chemistry ; Phenols ; Physical Chemistry ; Physical properties ; Physics ; Physics and Astronomy ; Solid State Physics ; Spectroscopy/Spectrometry ; Spectrum analysis ; Spin-lattice relaxation</subject><ispartof>Applied magnetic resonance, 2010-06, Vol.38 (3), p.257-269</ispartof><rights>Springer 2010</rights><rights>Springer 2010.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-c79ab7f7f61efd8d6265610d616d1f77ceb6d29aa52dc532b018194085749a083</citedby><cites>FETCH-LOGICAL-c316t-c79ab7f7f61efd8d6265610d616d1f77ceb6d29aa52dc532b018194085749a083</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00723-010-0117-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918048798?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,41464,42533,43781,51294</link.rule.ids></links><search><creatorcontrib>Mamedov, Ibrahim Garib</creatorcontrib><creatorcontrib>Eichhoff, U.</creatorcontrib><creatorcontrib>Maharramov, A. M.</creatorcontrib><creatorcontrib>Bayramov, M. R.</creatorcontrib><creatorcontrib>Mamedova, Y. V.</creatorcontrib><title>Molecular Dynamics of Alkenylphenol Derivatives in Solution as Studied by NMR Spectroscopy</title><title>Applied magnetic resonance</title><addtitle>Appl Magn Reson</addtitle><description>The formation of hydrogen bonds and molecular dynamics of alkenylphenol derivatives has been investigated in solution using nuclear magnetic resonance. The results confirm formation of an N···H, O···H-type intramolecular hydrogen bond. The spin–lattice relaxation times (
T
1
) and activation energy of molecular dynamics have been investigated confirming the importance of relaxation times as a very sensitive tool for studying molecular mobility.</description><subject>Atoms and Molecules in Strong Fields</subject><subject>Chemical bonds</subject><subject>Hydrocarbons</subject><subject>Hydrogen bonds</subject><subject>Laser Matter Interaction</subject><subject>Molecular dynamics</subject><subject>NMR</subject><subject>NMR spectroscopy</subject><subject>Nuclear magnetic resonance</subject><subject>Organic Chemistry</subject><subject>Phenols</subject><subject>Physical Chemistry</subject><subject>Physical properties</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Solid State Physics</subject><subject>Spectroscopy/Spectrometry</subject><subject>Spectrum analysis</subject><subject>Spin-lattice relaxation</subject><issn>0937-9347</issn><issn>1613-7507</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEtPwzAQhC0EEqXwA7hZ4hzYzcOOj1XLS2pBonDhYjm2AylpHOykUv49qYrEicPuXmZmRx8hlwjXCMBvwrjiJAKEcZBHcEQmyDCJeAb8mExAJDwSScpPyVkIGwDMcuQT8r5ytdV9rTxdDI3aVjpQV9JZ_WWboW4_beNqurC-2qmu2tlAq4auXd13lWuoCnTd9aayhhYDfVq90HVrdedd0K4dzslJqepgL37vlLzd3b7OH6Ll8_3jfLaMdIKsizQXquAlLxna0uSGxSxjCIYhM1hyrm3BTCyUymKjsyQuAHMUKeQZT4WCPJmSq0Nu6913b0MnN673zfhSxgJzSHMu9io8qPRYL3hbytZXW-UHiSD3COUBoRwRyj1CCaMnPnjCqG0-rP9L_t_0A_rAc4I</recordid><startdate>20100601</startdate><enddate>20100601</enddate><creator>Mamedov, Ibrahim Garib</creator><creator>Eichhoff, U.</creator><creator>Maharramov, A. 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V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-c79ab7f7f61efd8d6265610d616d1f77ceb6d29aa52dc532b018194085749a083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Atoms and Molecules in Strong Fields</topic><topic>Chemical bonds</topic><topic>Hydrocarbons</topic><topic>Hydrogen bonds</topic><topic>Laser Matter Interaction</topic><topic>Molecular dynamics</topic><topic>NMR</topic><topic>NMR spectroscopy</topic><topic>Nuclear magnetic resonance</topic><topic>Organic Chemistry</topic><topic>Phenols</topic><topic>Physical Chemistry</topic><topic>Physical properties</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Solid State Physics</topic><topic>Spectroscopy/Spectrometry</topic><topic>Spectrum analysis</topic><topic>Spin-lattice relaxation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mamedov, Ibrahim Garib</creatorcontrib><creatorcontrib>Eichhoff, U.</creatorcontrib><creatorcontrib>Maharramov, A. 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T
1
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subjects | Atoms and Molecules in Strong Fields Chemical bonds Hydrocarbons Hydrogen bonds Laser Matter Interaction Molecular dynamics NMR NMR spectroscopy Nuclear magnetic resonance Organic Chemistry Phenols Physical Chemistry Physical properties Physics Physics and Astronomy Solid State Physics Spectroscopy/Spectrometry Spectrum analysis Spin-lattice relaxation |
title | Molecular Dynamics of Alkenylphenol Derivatives in Solution as Studied by NMR Spectroscopy |
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