Synthesis and characterization of phosphorus containing aromatic poly(amide-imide)s copolymers for high temperature applications
A series of novel thermally stable poly(amide-imide)s (PAIs) based on non-coplaner diimide-diacid (DIDA) monomer is synthesized. These polymers are characterized by elemental analysis, FT-IR, 1 H-NMR, 13 C-NMR and 31 P-NMR spectroscopic techniques and their physical and thermal properties are also s...
Gespeichert in:
| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2013-12, Vol.70 (12), p.3241-3260 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3260 |
|---|---|
| container_issue | 12 |
| container_start_page | 3241 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 70 |
| creator | Agrawal, Seema Narula, Anudeep Kumar |
| description | A series of novel thermally stable poly(amide-imide)s (PAIs) based on non-coplaner diimide-diacid (DIDA) monomer is synthesized. These polymers are characterized by elemental analysis, FT-IR,
1
H-NMR,
13
C-NMR and
31
P-NMR spectroscopic techniques and their physical and thermal properties are also studied. Four different dianhydrides pyromellitic anhydride (PMDA)/3,3′,4,4′-benzophenone tetracarboxylic dianhydride (BTDA)/1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA)/4,4′-oxydiphthalic anhydride (ODPA) and amino acid
l
-tryptophan are used to synthesize DIDA. The polymerization of DIDA with phosphorus containing triamines having phenyl moieties gives poly(amide-imide)s. The synthesized polymers are obtained in high yield and possessed inherent viscosity in the range 0.66–0.98 dL/g. These polymers display higher solubility in polar aprotic solvents, such as DMSO, NMP and DMF. In addition, the absorption edge values (
λ
o
) obtained from their UV curves are determined, and all the resulting poly(amide-imide)s films exhibited high optical transparency. The glass transition temperature (
T
g
) of these polymers is recorded in the range 211–265 °C, initial decomposition temperature in excess of 435 °C and char yield at 800 °C in nitrogen ranged from 52 to 70 %. Wide angle X-ray diffraction showed that all the polymers are almost amorphous. |
| doi_str_mv | 10.1007/s00289-013-1021-1 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2918036643</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2918036643</sourcerecordid><originalsourceid>FETCH-LOGICAL-c383t-8d33bbe460c09dffba0a64a785387460ec9822a105aeda873ce749b5ffa245743</originalsourceid><addsrcrecordid>eNp1kE9r3DAQxUVJoZukH6A3QSk0ByWjP2vLxxKSthDIIe1ZzMrSWmEtuZL3sDnlo0fOhvbUw2jQ6PfeiEfIJw6XHKC9KgBCdwy4ZBwEZ_wdWXElGyaU6k7ICngLDLTsPpDTUh6h3puGr8jzwyHOgyuhUIw9tQNmtLPL4QnnkCJNnk5DKrXyvlCb4owhhrilmNNYEUuntDt8xTH0joXlvFiwZTi6XKhPmQ5hO9DZjZPLOO-zozhNu2BfF5Rz8t7jrriPb_2M_L69-XX9g93df_95_e2OWanlzHQv5WbjVAMWut77DQI2Clu9lrqtU2c7LQRyWKPrUbfSulZ1m7X3KNS6VfKMfD76Tjn92bsym8e0z7GuNKLjGmTTKFkpfqRsTqVk582Uw4j5YDiYJWhzDNrUoM0StOFV8-XNGYvFnc8YbSh_haLVSvFXb3HkSn2KW5f__eD_5i_TDpC7</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2918036643</pqid></control><display><type>article</type><title>Synthesis and characterization of phosphorus containing aromatic poly(amide-imide)s copolymers for high temperature applications</title><source>ProQuest Central UK/Ireland</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Agrawal, Seema ; Narula, Anudeep Kumar</creator><creatorcontrib>Agrawal, Seema ; Narula, Anudeep Kumar</creatorcontrib><description>A series of novel thermally stable poly(amide-imide)s (PAIs) based on non-coplaner diimide-diacid (DIDA) monomer is synthesized. These polymers are characterized by elemental analysis, FT-IR,
1
H-NMR,
13
C-NMR and
31
P-NMR spectroscopic techniques and their physical and thermal properties are also studied. Four different dianhydrides pyromellitic anhydride (PMDA)/3,3′,4,4′-benzophenone tetracarboxylic dianhydride (BTDA)/1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA)/4,4′-oxydiphthalic anhydride (ODPA) and amino acid
l
-tryptophan are used to synthesize DIDA. The polymerization of DIDA with phosphorus containing triamines having phenyl moieties gives poly(amide-imide)s. The synthesized polymers are obtained in high yield and possessed inherent viscosity in the range 0.66–0.98 dL/g. These polymers display higher solubility in polar aprotic solvents, such as DMSO, NMP and DMF. In addition, the absorption edge values (
λ
o
) obtained from their UV curves are determined, and all the resulting poly(amide-imide)s films exhibited high optical transparency. The glass transition temperature (
T
g
) of these polymers is recorded in the range 211–265 °C, initial decomposition temperature in excess of 435 °C and char yield at 800 °C in nitrogen ranged from 52 to 70 %. Wide angle X-ray diffraction showed that all the polymers are almost amorphous.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-013-1021-1</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Amino acids ; Anhydrides ; Applied sciences ; Characterization and Evaluation of Materials ; Chemical analysis ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Composite materials ; Copolymers ; Dianhydrides ; Diimide ; Exact sciences and technology ; Flame retardants ; Glass transition temperature ; High temperature ; Inorganic and organomineral polymers ; Naphthalene ; NMR ; Nuclear magnetic resonance ; Organic Chemistry ; Original Paper ; Phosphorus ; Physical Chemistry ; Physicochemistry of polymers ; Polymer Sciences ; Polymers ; Preparation ; Soft and Granular Matter ; Solvents ; Synthesis ; Thermal stability ; Thermodynamic properties ; Tryptophan</subject><ispartof>Polymer bulletin (Berlin, Germany), 2013-12, Vol.70 (12), p.3241-3260</ispartof><rights>Springer-Verlag Berlin Heidelberg 2013</rights><rights>2015 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2013.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-8d33bbe460c09dffba0a64a785387460ec9822a105aeda873ce749b5ffa245743</citedby><cites>FETCH-LOGICAL-c383t-8d33bbe460c09dffba0a64a785387460ec9822a105aeda873ce749b5ffa245743</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-013-1021-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918036643?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,41488,42557,43805,51319,64385,64389,72469</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27844143$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Agrawal, Seema</creatorcontrib><creatorcontrib>Narula, Anudeep Kumar</creatorcontrib><title>Synthesis and characterization of phosphorus containing aromatic poly(amide-imide)s copolymers for high temperature applications</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>A series of novel thermally stable poly(amide-imide)s (PAIs) based on non-coplaner diimide-diacid (DIDA) monomer is synthesized. These polymers are characterized by elemental analysis, FT-IR,
1
H-NMR,
13
C-NMR and
31
P-NMR spectroscopic techniques and their physical and thermal properties are also studied. Four different dianhydrides pyromellitic anhydride (PMDA)/3,3′,4,4′-benzophenone tetracarboxylic dianhydride (BTDA)/1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA)/4,4′-oxydiphthalic anhydride (ODPA) and amino acid
l
-tryptophan are used to synthesize DIDA. The polymerization of DIDA with phosphorus containing triamines having phenyl moieties gives poly(amide-imide)s. The synthesized polymers are obtained in high yield and possessed inherent viscosity in the range 0.66–0.98 dL/g. These polymers display higher solubility in polar aprotic solvents, such as DMSO, NMP and DMF. In addition, the absorption edge values (
λ
o
) obtained from their UV curves are determined, and all the resulting poly(amide-imide)s films exhibited high optical transparency. The glass transition temperature (
T
g
) of these polymers is recorded in the range 211–265 °C, initial decomposition temperature in excess of 435 °C and char yield at 800 °C in nitrogen ranged from 52 to 70 %. Wide angle X-ray diffraction showed that all the polymers are almost amorphous.</description><subject>Amino acids</subject><subject>Anhydrides</subject><subject>Applied sciences</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Composite materials</subject><subject>Copolymers</subject><subject>Dianhydrides</subject><subject>Diimide</subject><subject>Exact sciences and technology</subject><subject>Flame retardants</subject><subject>Glass transition temperature</subject><subject>High temperature</subject><subject>Inorganic and organomineral polymers</subject><subject>Naphthalene</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Phosphorus</subject><subject>Physical Chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Preparation</subject><subject>Soft and Granular Matter</subject><subject>Solvents</subject><subject>Synthesis</subject><subject>Thermal stability</subject><subject>Thermodynamic properties</subject><subject>Tryptophan</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kE9r3DAQxUVJoZukH6A3QSk0ByWjP2vLxxKSthDIIe1ZzMrSWmEtuZL3sDnlo0fOhvbUw2jQ6PfeiEfIJw6XHKC9KgBCdwy4ZBwEZ_wdWXElGyaU6k7ICngLDLTsPpDTUh6h3puGr8jzwyHOgyuhUIw9tQNmtLPL4QnnkCJNnk5DKrXyvlCb4owhhrilmNNYEUuntDt8xTH0joXlvFiwZTi6XKhPmQ5hO9DZjZPLOO-zozhNu2BfF5Rz8t7jrriPb_2M_L69-XX9g93df_95_e2OWanlzHQv5WbjVAMWut77DQI2Clu9lrqtU2c7LQRyWKPrUbfSulZ1m7X3KNS6VfKMfD76Tjn92bsym8e0z7GuNKLjGmTTKFkpfqRsTqVk582Uw4j5YDiYJWhzDNrUoM0StOFV8-XNGYvFnc8YbSh_haLVSvFXb3HkSn2KW5f__eD_5i_TDpC7</recordid><startdate>20131201</startdate><enddate>20131201</enddate><creator>Agrawal, Seema</creator><creator>Narula, Anudeep Kumar</creator><general>Springer Berlin Heidelberg</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20131201</creationdate><title>Synthesis and characterization of phosphorus containing aromatic poly(amide-imide)s copolymers for high temperature applications</title><author>Agrawal, Seema ; Narula, Anudeep Kumar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-8d33bbe460c09dffba0a64a785387460ec9822a105aeda873ce749b5ffa245743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Amino acids</topic><topic>Anhydrides</topic><topic>Applied sciences</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Composite materials</topic><topic>Copolymers</topic><topic>Dianhydrides</topic><topic>Diimide</topic><topic>Exact sciences and technology</topic><topic>Flame retardants</topic><topic>Glass transition temperature</topic><topic>High temperature</topic><topic>Inorganic and organomineral polymers</topic><topic>Naphthalene</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Phosphorus</topic><topic>Physical Chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Preparation</topic><topic>Soft and Granular Matter</topic><topic>Solvents</topic><topic>Synthesis</topic><topic>Thermal stability</topic><topic>Thermodynamic properties</topic><topic>Tryptophan</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Agrawal, Seema</creatorcontrib><creatorcontrib>Narula, Anudeep Kumar</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Agrawal, Seema</au><au>Narula, Anudeep Kumar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of phosphorus containing aromatic poly(amide-imide)s copolymers for high temperature applications</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2013-12-01</date><risdate>2013</risdate><volume>70</volume><issue>12</issue><spage>3241</spage><epage>3260</epage><pages>3241-3260</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>A series of novel thermally stable poly(amide-imide)s (PAIs) based on non-coplaner diimide-diacid (DIDA) monomer is synthesized. These polymers are characterized by elemental analysis, FT-IR,
1
H-NMR,
13
C-NMR and
31
P-NMR spectroscopic techniques and their physical and thermal properties are also studied. Four different dianhydrides pyromellitic anhydride (PMDA)/3,3′,4,4′-benzophenone tetracarboxylic dianhydride (BTDA)/1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA)/4,4′-oxydiphthalic anhydride (ODPA) and amino acid
l
-tryptophan are used to synthesize DIDA. The polymerization of DIDA with phosphorus containing triamines having phenyl moieties gives poly(amide-imide)s. The synthesized polymers are obtained in high yield and possessed inherent viscosity in the range 0.66–0.98 dL/g. These polymers display higher solubility in polar aprotic solvents, such as DMSO, NMP and DMF. In addition, the absorption edge values (
λ
o
) obtained from their UV curves are determined, and all the resulting poly(amide-imide)s films exhibited high optical transparency. The glass transition temperature (
T
g
) of these polymers is recorded in the range 211–265 °C, initial decomposition temperature in excess of 435 °C and char yield at 800 °C in nitrogen ranged from 52 to 70 %. Wide angle X-ray diffraction showed that all the polymers are almost amorphous.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-013-1021-1</doi><tpages>20</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2013-12, Vol.70 (12), p.3241-3260 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_2918036643 |
| source | ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Amino acids Anhydrides Applied sciences Characterization and Evaluation of Materials Chemical analysis Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Composite materials Copolymers Dianhydrides Diimide Exact sciences and technology Flame retardants Glass transition temperature High temperature Inorganic and organomineral polymers Naphthalene NMR Nuclear magnetic resonance Organic Chemistry Original Paper Phosphorus Physical Chemistry Physicochemistry of polymers Polymer Sciences Polymers Preparation Soft and Granular Matter Solvents Synthesis Thermal stability Thermodynamic properties Tryptophan |
| title | Synthesis and characterization of phosphorus containing aromatic poly(amide-imide)s copolymers for high temperature applications |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T16%3A24%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20characterization%20of%20phosphorus%20containing%20aromatic%20poly(amide-imide)s%20copolymers%20for%20high%20temperature%20applications&rft.jtitle=Polymer%20bulletin%20(Berlin,%20Germany)&rft.au=Agrawal,%20Seema&rft.date=2013-12-01&rft.volume=70&rft.issue=12&rft.spage=3241&rft.epage=3260&rft.pages=3241-3260&rft.issn=0170-0839&rft.eissn=1436-2449&rft.coden=POBUDR&rft_id=info:doi/10.1007/s00289-013-1021-1&rft_dat=%3Cproquest_cross%3E2918036643%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2918036643&rft_id=info:pmid/&rfr_iscdi=true |