Poly(3,4-ethylenedioxythiophene) electrode grown in the presence of ionic liquid and its symmetrical electrochemical supercapacitor application
Poly(3,4-ethylenedioxythiophene) polymer film (PEDOT-IL) was electrosynthesized in the ionic liquid (IL) 1-ethyl-3-methylimidazolium hydrogen sulphate (EMIMHSO 4 ) medium, which also contains 0.1 M LiClO 4 in ACN. For comparison reasons in terms of structure and electrode capacitance performance, PE...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2018-04, Vol.75 (4), p.1547-1562 |
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| creator | Carbas, Buket Bezgin Tekin, Burak |
| description | Poly(3,4-ethylenedioxythiophene) polymer film (PEDOT-IL) was electrosynthesized in the ionic liquid (IL) 1-ethyl-3-methylimidazolium hydrogen sulphate (EMIMHSO
4
) medium, which also contains 0.1 M LiClO
4
in ACN. For comparison reasons in terms of structure and electrode capacitance performance, PEDOT film was also synthesized electrochemically without IL. The SEM results show that PEDOT-IL film has more porous surface and fine textures with nanometer-diameter than PEDOT polymer. Different electrochemical methods including galvanostatic charge–discharge (CD) experiments, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were carried out to investigate the applicability of the system as a redox supercapacitor for both polymers. PEDOT-IL electrode shows higher optimum specific capacitance than PEDOT film. Additionally, the symmetrical supercapacitor was assembled from two PEDOT-IL electrodes in LiClO
4
/ACN medium and exhibited a maximum specific capacitance of 107 F g
−1
, an energy density of 11.5 Wh kg
−1
at a power density 13 kW kg
−1
, and an excellent cycle life of 96% specific capacitance retention after 1000 cycles. |
| doi_str_mv | 10.1007/s00289-017-2111-2 |
| format | Article |
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4
) medium, which also contains 0.1 M LiClO
4
in ACN. For comparison reasons in terms of structure and electrode capacitance performance, PEDOT film was also synthesized electrochemically without IL. The SEM results show that PEDOT-IL film has more porous surface and fine textures with nanometer-diameter than PEDOT polymer. Different electrochemical methods including galvanostatic charge–discharge (CD) experiments, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were carried out to investigate the applicability of the system as a redox supercapacitor for both polymers. PEDOT-IL electrode shows higher optimum specific capacitance than PEDOT film. Additionally, the symmetrical supercapacitor was assembled from two PEDOT-IL electrodes in LiClO
4
/ACN medium and exhibited a maximum specific capacitance of 107 F g
−1
, an energy density of 11.5 Wh kg
−1
at a power density 13 kW kg
−1
, and an excellent cycle life of 96% specific capacitance retention after 1000 cycles.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-017-2111-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Capacitance ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Electrochemical impedance spectroscopy ; Electrodes ; Electrolytes ; Energy consumption ; Energy storage ; Ionic liquids ; Metal oxides ; Morphology ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer films ; Polymer Sciences ; Polymerization ; Polymers ; Scanning electron microscopy ; Soft and Granular Matter ; Solvents ; Supercapacitors ; Viscosity</subject><ispartof>Polymer bulletin (Berlin, Germany), 2018-04, Vol.75 (4), p.1547-1562</ispartof><rights>Springer-Verlag GmbH Germany 2017</rights><rights>Springer-Verlag GmbH Germany 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c423t-a18d9cb034a32cd61b850bcff7503ece23c6b86416f7fbb907b8c95ccfe42dfa3</citedby><cites>FETCH-LOGICAL-c423t-a18d9cb034a32cd61b850bcff7503ece23c6b86416f7fbb907b8c95ccfe42dfa3</cites><orcidid>0000-0002-4178-5911</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-017-2111-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918034519?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,41464,42533,43781,51294</link.rule.ids></links><search><creatorcontrib>Carbas, Buket Bezgin</creatorcontrib><creatorcontrib>Tekin, Burak</creatorcontrib><title>Poly(3,4-ethylenedioxythiophene) electrode grown in the presence of ionic liquid and its symmetrical electrochemical supercapacitor application</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>Poly(3,4-ethylenedioxythiophene) polymer film (PEDOT-IL) was electrosynthesized in the ionic liquid (IL) 1-ethyl-3-methylimidazolium hydrogen sulphate (EMIMHSO
4
) medium, which also contains 0.1 M LiClO
4
in ACN. For comparison reasons in terms of structure and electrode capacitance performance, PEDOT film was also synthesized electrochemically without IL. The SEM results show that PEDOT-IL film has more porous surface and fine textures with nanometer-diameter than PEDOT polymer. Different electrochemical methods including galvanostatic charge–discharge (CD) experiments, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were carried out to investigate the applicability of the system as a redox supercapacitor for both polymers. PEDOT-IL electrode shows higher optimum specific capacitance than PEDOT film. Additionally, the symmetrical supercapacitor was assembled from two PEDOT-IL electrodes in LiClO
4
/ACN medium and exhibited a maximum specific capacitance of 107 F g
−1
, an energy density of 11.5 Wh kg
−1
at a power density 13 kW kg
−1
, and an excellent cycle life of 96% specific capacitance retention after 1000 cycles.</description><subject>Capacitance</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Energy consumption</subject><subject>Energy storage</subject><subject>Ionic liquids</subject><subject>Metal oxides</subject><subject>Morphology</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymer films</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Scanning electron microscopy</subject><subject>Soft and Granular Matter</subject><subject>Solvents</subject><subject>Supercapacitors</subject><subject>Viscosity</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kM1qGzEUhUVpoK7bB-hO0E0DVaKf8fwsQ0ibgCFZJGuhuXPlkRmPxpJMM0_RV45cp2SV1eXce8534RDyTfALwXl1GTmXdcO4qJgUQjD5gSxEoUomi6L5SBb5wBmvVfOJfI5xy7MuS7Egfx_8MP9QPwuGqZ8HHLFz_nlOvfNTn9U5xQEhBd8h3QT_Z6RupKlHOgWMOAJSb6nzowM6uP3BddSMHXUp0jjvdpiCAzP8Z0CPu386HiYMYCYDLvlAzTQNeZ8y5ws5s2aI-PV1LsnTr5vH61u2vv99d321ZlBIlZgRdddAy1VhlISuFG294i1YW624QkCpoGzrshClrWzbNrxqa2hWABYL2VmjluT7iTsFvz9gTHrrD2HML7VsRJ3BK9Fklzi5IPgYA1o9BbczYdaC62Pv-tS7znXqY-9a5ow8ZWL2jhsMb-T3Qy-W_Inf</recordid><startdate>20180401</startdate><enddate>20180401</enddate><creator>Carbas, Buket Bezgin</creator><creator>Tekin, Burak</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-4178-5911</orcidid></search><sort><creationdate>20180401</creationdate><title>Poly(3,4-ethylenedioxythiophene) electrode grown in the presence of ionic liquid and its symmetrical electrochemical supercapacitor application</title><author>Carbas, Buket Bezgin ; Tekin, Burak</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c423t-a18d9cb034a32cd61b850bcff7503ece23c6b86416f7fbb907b8c95ccfe42dfa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Capacitance</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Energy consumption</topic><topic>Energy storage</topic><topic>Ionic liquids</topic><topic>Metal oxides</topic><topic>Morphology</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymer films</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Scanning electron microscopy</topic><topic>Soft and Granular Matter</topic><topic>Solvents</topic><topic>Supercapacitors</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Carbas, Buket Bezgin</creatorcontrib><creatorcontrib>Tekin, Burak</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Carbas, Buket Bezgin</au><au>Tekin, Burak</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Poly(3,4-ethylenedioxythiophene) electrode grown in the presence of ionic liquid and its symmetrical electrochemical supercapacitor application</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2018-04-01</date><risdate>2018</risdate><volume>75</volume><issue>4</issue><spage>1547</spage><epage>1562</epage><pages>1547-1562</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>Poly(3,4-ethylenedioxythiophene) polymer film (PEDOT-IL) was electrosynthesized in the ionic liquid (IL) 1-ethyl-3-methylimidazolium hydrogen sulphate (EMIMHSO
4
) medium, which also contains 0.1 M LiClO
4
in ACN. For comparison reasons in terms of structure and electrode capacitance performance, PEDOT film was also synthesized electrochemically without IL. The SEM results show that PEDOT-IL film has more porous surface and fine textures with nanometer-diameter than PEDOT polymer. Different electrochemical methods including galvanostatic charge–discharge (CD) experiments, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were carried out to investigate the applicability of the system as a redox supercapacitor for both polymers. PEDOT-IL electrode shows higher optimum specific capacitance than PEDOT film. Additionally, the symmetrical supercapacitor was assembled from two PEDOT-IL electrodes in LiClO
4
/ACN medium and exhibited a maximum specific capacitance of 107 F g
−1
, an energy density of 11.5 Wh kg
−1
at a power density 13 kW kg
−1
, and an excellent cycle life of 96% specific capacitance retention after 1000 cycles.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-017-2111-2</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0002-4178-5911</orcidid></addata></record> |
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| subjects | Capacitance Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Electrochemical impedance spectroscopy Electrodes Electrolytes Energy consumption Energy storage Ionic liquids Metal oxides Morphology Organic Chemistry Original Paper Physical Chemistry Polymer films Polymer Sciences Polymerization Polymers Scanning electron microscopy Soft and Granular Matter Solvents Supercapacitors Viscosity |
| title | Poly(3,4-ethylenedioxythiophene) electrode grown in the presence of ionic liquid and its symmetrical electrochemical supercapacitor application |
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