The SNP measurement of the electron transfer reaction from quadricyclane to tetrafluoro-p-benzoquinone
The stimulated nuclear polarization (SNP) [1] is measured in the photoinduced electron transfer reaction from quadricyclane to tetrafluoro-p-benzoquinone. We conclude that the radicalion pair in this system involves quadricyclane cation radical and that the isomerization reaction from quadricyclane...
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| Veröffentlicht in: | Applied magnetic resonance 1997-05, Vol.12 (4), p.441-447 |
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| container_end_page | 447 |
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| container_title | Applied magnetic resonance |
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| creator | Yamakage, Y. Nagashima, T. Maeda, K. Murai, H. Azumi, T. |
| description | The stimulated nuclear polarization (SNP) [1] is measured in the photoinduced electron transfer reaction from quadricyclane to tetrafluoro-p-benzoquinone. We conclude that the radicalion pair in this system involves quadricyclane cation radical and that the isomerization reaction from quadricyclane cation radical to norbornadiene cation radical mainly occurs outside the cage of radical-ion pair. |
| doi_str_mv | 10.1007/BF03164125 |
| format | Article |
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| ispartof | Applied magnetic resonance, 1997-05, Vol.12 (4), p.441-447 |
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| language | eng |
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| subjects | Benzoquinone Cations Electron transfer Ion pairs Isomerization |
| title | The SNP measurement of the electron transfer reaction from quadricyclane to tetrafluoro-p-benzoquinone |
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