Controlled release study of phenol formaldehyde based microcapsules containing various loading percentage of core cypermethrin at different agitation rates
s Cypermethrin is a synthetic pyrethroid that acts as a neurotoxin and is used on large scale in both agricultural and domestic purposes. It is easily degraded on soil and plants but can be effective for weeks when applied to indoor inert surfaces. Sometimes it develops tingling, burning, dizziness,...
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Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2019-05, Vol.76 (5), p.2519-2536 |
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creator | Karandikar, Pravin S. Rajput, Jamatsing D. Bagul, Suresh D. Gite, Vikas V. Bendre, Ratnamala S. |
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Cypermethrin is a synthetic pyrethroid that acts as a neurotoxin and is used on large scale in both agricultural and domestic purposes. It is easily degraded on soil and plants but can be effective for weeks when applied to indoor inert surfaces. Sometimes it develops tingling, burning, dizziness, and itching to the operator which is why there is a need to develop a safe and effective formulation, which can release cypermethrin under controlled conditions. In this communication, we report a successful encapsulation of cypermethrin within shell of phenol formaldehyde (PF). A series of PF microcapsules have been prepared at various loading percentage and varying agitation rates by in situ polymerization. The formulation consists of mainly two parts, namely emulsification of the oil and wall formation. The morphology of formulated microcapsules was confirmed initially by observing under optical microscope and further with FESEM, which indicated spherical shape, smooth surface, and rigid nature to the microcapsules. The microcapsules were characterized by FTIR, TGA, and particle size analyzer. Release rate of cypermethrin from polymeric microcapsules was calculated by UV spectrophotometer and also by a simple gravimetric method. The stable, safe, and controlled release formulation of easily degradable, highly burning and etching cypermethrin is the success of our present work.
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doi_str_mv | 10.1007/s00289-018-2508-6 |
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Cypermethrin is a synthetic pyrethroid that acts as a neurotoxin and is used on large scale in both agricultural and domestic purposes. It is easily degraded on soil and plants but can be effective for weeks when applied to indoor inert surfaces. Sometimes it develops tingling, burning, dizziness, and itching to the operator which is why there is a need to develop a safe and effective formulation, which can release cypermethrin under controlled conditions. In this communication, we report a successful encapsulation of cypermethrin within shell of phenol formaldehyde (PF). A series of PF microcapsules have been prepared at various loading percentage and varying agitation rates by in situ polymerization. The formulation consists of mainly two parts, namely emulsification of the oil and wall formation. The morphology of formulated microcapsules was confirmed initially by observing under optical microscope and further with FESEM, which indicated spherical shape, smooth surface, and rigid nature to the microcapsules. The microcapsules were characterized by FTIR, TGA, and particle size analyzer. Release rate of cypermethrin from polymeric microcapsules was calculated by UV spectrophotometer and also by a simple gravimetric method. The stable, safe, and controlled release formulation of easily degradable, highly burning and etching cypermethrin is the success of our present work.
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Cypermethrin is a synthetic pyrethroid that acts as a neurotoxin and is used on large scale in both agricultural and domestic purposes. It is easily degraded on soil and plants but can be effective for weeks when applied to indoor inert surfaces. Sometimes it develops tingling, burning, dizziness, and itching to the operator which is why there is a need to develop a safe and effective formulation, which can release cypermethrin under controlled conditions. In this communication, we report a successful encapsulation of cypermethrin within shell of phenol formaldehyde (PF). A series of PF microcapsules have been prepared at various loading percentage and varying agitation rates by in situ polymerization. The formulation consists of mainly two parts, namely emulsification of the oil and wall formation. The morphology of formulated microcapsules was confirmed initially by observing under optical microscope and further with FESEM, which indicated spherical shape, smooth surface, and rigid nature to the microcapsules. The microcapsules were characterized by FTIR, TGA, and particle size analyzer. Release rate of cypermethrin from polymeric microcapsules was calculated by UV spectrophotometer and also by a simple gravimetric method. The stable, safe, and controlled release formulation of easily degradable, highly burning and etching cypermethrin is the success of our present work.
Graphical abstract</description><subject>Agitation</subject><subject>Aqueous solutions</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Controlled release</subject><subject>Emulsion polymerization</subject><subject>Itching</subject><subject>Microencapsulation</subject><subject>Morphology</subject><subject>Optical microscopes</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Particle size</subject><subject>Phenol formaldehyde</subject><subject>Phenols</subject><subject>Physical Chemistry</subject><subject>Polylactic acid</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Soft and Granular Matter</subject><subject>Toxins</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kc1q3DAUhUVoIdNpH6A7QddOr_wjy8swtEkh0E2yFvq5mtFgW44kF-ZZ-rLV4EBWXYkjfedcrg4hXxncMYD-ewKoxVABE1Xdgaj4DdmxtuFV3bbDB7ID1kMFohluyaeUzlA052xH_h7CnGMYR7Q04ogqIU15tRcaHF1OOIeRuhAnNVo8XSxSXQhLJ29iMGpJ64iJmpKh_OznI_2jog9romNQ9qoXjAbL6xGvgSZEpOZSLifMp-hnqjK13jmMBaLq6LPKPsw0qozpM_no1Jjwy9u5Jy8_fzwfHqun3w-_DvdPlWm6JldcA3fGaNRuUAw071ExN-im1wDCGCtaEJyJ8hu85qB7qzvBu27olG07rps9-bblLjG8rpiyPIc1zmWkrAfWD6LlnSgU26iyeUoRnVyin1S8SAby2oHcOpClA3ntQPLiqTdPKux8xPie_H_TP9F_ji4</recordid><startdate>20190501</startdate><enddate>20190501</enddate><creator>Karandikar, Pravin S.</creator><creator>Rajput, Jamatsing D.</creator><creator>Bagul, Suresh D.</creator><creator>Gite, Vikas V.</creator><creator>Bendre, Ratnamala S.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20190501</creationdate><title>Controlled release study of phenol formaldehyde based microcapsules containing various loading percentage of core cypermethrin at different agitation rates</title><author>Karandikar, Pravin S. ; Rajput, Jamatsing D. ; Bagul, Suresh D. ; Gite, Vikas V. ; Bendre, Ratnamala S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-6b06fccbebf9a10b67ea1f9b37b008ccd84086184366260b7db5865595ad456b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Agitation</topic><topic>Aqueous solutions</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Controlled release</topic><topic>Emulsion polymerization</topic><topic>Itching</topic><topic>Microencapsulation</topic><topic>Morphology</topic><topic>Optical microscopes</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Particle size</topic><topic>Phenol formaldehyde</topic><topic>Phenols</topic><topic>Physical Chemistry</topic><topic>Polylactic acid</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Soft and Granular Matter</topic><topic>Toxins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karandikar, Pravin S.</creatorcontrib><creatorcontrib>Rajput, Jamatsing D.</creatorcontrib><creatorcontrib>Bagul, Suresh D.</creatorcontrib><creatorcontrib>Gite, Vikas V.</creatorcontrib><creatorcontrib>Bendre, Ratnamala S.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karandikar, Pravin S.</au><au>Rajput, Jamatsing D.</au><au>Bagul, Suresh D.</au><au>Gite, Vikas V.</au><au>Bendre, Ratnamala S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Controlled release study of phenol formaldehyde based microcapsules containing various loading percentage of core cypermethrin at different agitation rates</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2019-05-01</date><risdate>2019</risdate><volume>76</volume><issue>5</issue><spage>2519</spage><epage>2536</epage><pages>2519-2536</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>s
Cypermethrin is a synthetic pyrethroid that acts as a neurotoxin and is used on large scale in both agricultural and domestic purposes. It is easily degraded on soil and plants but can be effective for weeks when applied to indoor inert surfaces. Sometimes it develops tingling, burning, dizziness, and itching to the operator which is why there is a need to develop a safe and effective formulation, which can release cypermethrin under controlled conditions. In this communication, we report a successful encapsulation of cypermethrin within shell of phenol formaldehyde (PF). A series of PF microcapsules have been prepared at various loading percentage and varying agitation rates by in situ polymerization. The formulation consists of mainly two parts, namely emulsification of the oil and wall formation. The morphology of formulated microcapsules was confirmed initially by observing under optical microscope and further with FESEM, which indicated spherical shape, smooth surface, and rigid nature to the microcapsules. The microcapsules were characterized by FTIR, TGA, and particle size analyzer. Release rate of cypermethrin from polymeric microcapsules was calculated by UV spectrophotometer and also by a simple gravimetric method. The stable, safe, and controlled release formulation of easily degradable, highly burning and etching cypermethrin is the success of our present work.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-018-2508-6</doi><tpages>18</tpages></addata></record> |
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subjects | Agitation Aqueous solutions Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Controlled release Emulsion polymerization Itching Microencapsulation Morphology Optical microscopes Organic Chemistry Original Paper Particle size Phenol formaldehyde Phenols Physical Chemistry Polylactic acid Polymer Sciences Polymerization Soft and Granular Matter Toxins |
title | Controlled release study of phenol formaldehyde based microcapsules containing various loading percentage of core cypermethrin at different agitation rates |
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