Functionalization of low molecular weight atactic polypropylenePart II. Thermal and molecular weight studies

Functionalization of low molecular weight atactic polypropylenePart II. Thermal and molecular weight studies

SummaryNumber average molecular weight (Mn), intrinsic viscosity ([η]) and glass transition temperature (Tg) of low molecular weight atactic polypropylene (APP) grafted with 4-allyl-1,2-dimethoxybenzene (DMAB), 4-allyl-2-methoxyphenol (eugenol) and 4-propenylanisole (trans-anethole) in the presence...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2000-11, Vol.45 (3), p.245-252
Hauptverfasser: Akm-Öktem, Gülsu, Çetin, Sedat, Öktem, Zeki
Format: Artikel
Sprache:eng
Schlagworte:
Atacticity
Dicumyl peroxide
Glass transition temperature
Grafting
Low molecular weights
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creator Akm-Öktem, Gülsu
Çetin, Sedat
Öktem, Zeki
description SummaryNumber average molecular weight (Mn), intrinsic viscosity ([η]) and glass transition temperature (Tg) of low molecular weight atactic polypropylene (APP) grafted with 4-allyl-1,2-dimethoxybenzene (DMAB), 4-allyl-2-methoxyphenol (eugenol) and 4-propenylanisole (trans-anethole) in the presence of dicumyl peroxide (DCP) at 170°C were determined. The influences of reaction time, concentration and extent of grafting on Mn, [η] and Tg of APP were examined. The data were discussed with the mechanism of grafting reactions.
doi_str_mv 10.1007/s002890070027
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subjects Atacticity
Dicumyl peroxide
Glass transition temperature
Grafting
Low molecular weights
title Functionalization of low molecular weight atactic polypropylenePart II. Thermal and molecular weight studies
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