Polyelectrolyte-Cu(II) interactions studied by cyclic voltammetry
SUMMARYThe polymer-metal ion interactions were studied by cyclic voltammetry. These were carried out with poly(acrylic acid)-Cu(II) and poly(vinylsulfonic acid)-Cu(II) systems at different pH. At low pH, the polymer was adsorbed on the electrode surface increasing the irreversibility of the Cu2+/Cu(...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2000-11, Vol.45 (3), p.259-265 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | RIVAS, Bernabé L SCHIAPPACASSE, Nicolas BASAEZ, Luis A |
| description | SUMMARYThe polymer-metal ion interactions were studied by cyclic voltammetry. These were carried out with poly(acrylic acid)-Cu(II) and poly(vinylsulfonic acid)-Cu(II) systems at different pH. At low pH, the polymer was adsorbed on the electrode surface increasing the irreversibility of the Cu2+/Cu(s) redox system. At pH 2.7, it was possible to demonstrate that the interaction between Cu(II) and poly(vinylsulfonic acid) is basically electrostatic and with poly(acrylic acid) a complex formation also exists. |
| doi_str_mv | 10.1007/s002890070029 |
| format | Article |
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These were carried out with poly(acrylic acid)-Cu(II) and poly(vinylsulfonic acid)-Cu(II) systems at different pH. At low pH, the polymer was adsorbed on the electrode surface increasing the irreversibility of the Cu2+/Cu(s) redox system. At pH 2.7, it was possible to demonstrate that the interaction between Cu(II) and poly(vinylsulfonic acid) is basically electrostatic and with poly(acrylic acid) a complex formation also exists.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s002890070029</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Applied sciences ; Complex formation ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polyacrylic acid ; Polyelectrolytes ; Polymers ; Properties and characterization ; Solution and gel properties ; Voltammetry</subject><ispartof>Polymer bulletin (Berlin, Germany), 2000-11, Vol.45 (3), p.259-265</ispartof><rights>2001 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2000.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c291t-9319c17002c48dfc496389b7f0ae235732ff477fec69330c4a8f7b2316f78e393</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2917979516?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,43805,64385,64389,72469</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=825596$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>RIVAS, Bernabé L</creatorcontrib><creatorcontrib>SCHIAPPACASSE, Nicolas</creatorcontrib><creatorcontrib>BASAEZ, Luis A</creatorcontrib><title>Polyelectrolyte-Cu(II) interactions studied by cyclic voltammetry</title><title>Polymer bulletin (Berlin, Germany)</title><description>SUMMARYThe polymer-metal ion interactions were studied by cyclic voltammetry. These were carried out with poly(acrylic acid)-Cu(II) and poly(vinylsulfonic acid)-Cu(II) systems at different pH. At low pH, the polymer was adsorbed on the electrode surface increasing the irreversibility of the Cu2+/Cu(s) redox system. At pH 2.7, it was possible to demonstrate that the interaction between Cu(II) and poly(vinylsulfonic acid) is basically electrostatic and with poly(acrylic acid) a complex formation also exists.</description><subject>Applied sciences</subject><subject>Complex formation</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyacrylic acid</subject><subject>Polyelectrolytes</subject><subject>Polymers</subject><subject>Properties and characterization</subject><subject>Solution and gel properties</subject><subject>Voltammetry</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpVUEtLAzEYDKJgrR69L3jRQzSvzeNYio-Fgh70vKTfJrBlHzXJCvvvTamInmY-mG9mGISuKbmnhKiHSAjTJrOM5gQtqOASMyHMKVoQqggmmptzdBHjjuRbSrpAq7exm13nIIVMksPr6baq7op2SC5YSO04xCKmqWldU2znAmboWii-xi7ZvncpzJfozNsuuqsfXKKPp8f39QvevD5X69UGAzM0YcOpAXqoBkI3HoSRXJut8sQ6xkvFmfdCKe9AGs4JCKu92jJOpVfaccOX6Obouw_j5-RiqnfjFIYcWecAZZQpqcwqfFRBGGMMztf70PY2zDUl9WGl-t9Kf1xtBNv5YAdo4--TZmWZi34DSqdlFQ</recordid><startdate>20001109</startdate><enddate>20001109</enddate><creator>RIVAS, Bernabé L</creator><creator>SCHIAPPACASSE, Nicolas</creator><creator>BASAEZ, Luis A</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20001109</creationdate><title>Polyelectrolyte-Cu(II) interactions studied by cyclic voltammetry</title><author>RIVAS, Bernabé L ; SCHIAPPACASSE, Nicolas ; BASAEZ, Luis A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c291t-9319c17002c48dfc496389b7f0ae235732ff477fec69330c4a8f7b2316f78e393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Applied sciences</topic><topic>Complex formation</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polyacrylic acid</topic><topic>Polyelectrolytes</topic><topic>Polymers</topic><topic>Properties and characterization</topic><topic>Solution and gel properties</topic><topic>Voltammetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>RIVAS, Bernabé L</creatorcontrib><creatorcontrib>SCHIAPPACASSE, Nicolas</creatorcontrib><creatorcontrib>BASAEZ, Luis A</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>RIVAS, Bernabé L</au><au>SCHIAPPACASSE, Nicolas</au><au>BASAEZ, Luis A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polyelectrolyte-Cu(II) interactions studied by cyclic voltammetry</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>2000-11-09</date><risdate>2000</risdate><volume>45</volume><issue>3</issue><spage>259</spage><epage>265</epage><pages>259-265</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>SUMMARYThe polymer-metal ion interactions were studied by cyclic voltammetry. These were carried out with poly(acrylic acid)-Cu(II) and poly(vinylsulfonic acid)-Cu(II) systems at different pH. At low pH, the polymer was adsorbed on the electrode surface increasing the irreversibility of the Cu2+/Cu(s) redox system. At pH 2.7, it was possible to demonstrate that the interaction between Cu(II) and poly(vinylsulfonic acid) is basically electrostatic and with poly(acrylic acid) a complex formation also exists.</abstract><cop>Heidelberg</cop><cop>Berlin</cop><cop>New York, NY</cop><pub>Springer</pub><doi>10.1007/s002890070029</doi><tpages>7</tpages></addata></record> |
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| ispartof | Polymer bulletin (Berlin, Germany), 2000-11, Vol.45 (3), p.259-265 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| source | ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Applied sciences Complex formation Exact sciences and technology Organic polymers Physicochemistry of polymers Polyacrylic acid Polyelectrolytes Polymers Properties and characterization Solution and gel properties Voltammetry |
| title | Polyelectrolyte-Cu(II) interactions studied by cyclic voltammetry |
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