Synthesis and Characterization of Anionic Exchange Resins with a Gradient in Polymer Composition for the PS-co-DVB/PDEAMA-co-DVB System
Summary Anionic exchange resins with a gradient in polymer composition were prepared in two stages. After P(S-co-DVB) suspension beads were obtained, N,N-diethylaminoethyl methacrylate monomer was let to diffuse into the beads at 25 °C, and immediately photopolymerized to fix the gradient polymer co...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2008, Vol.59 (6), p.777-785 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | Jasso-Gastinel, C. F. García-Enriquez, S. González-Ortiz, L. J. |
| description | Summary
Anionic exchange resins with a gradient in polymer composition were prepared in two stages. After P(S-co-DVB) suspension beads were obtained, N,N-diethylaminoethyl methacrylate monomer was let to diffuse into the beads at 25 °C, and immediately photopolymerized to fix the gradient polymer composition with high surface concentration of ion exchanger. Chemical composition through the radial position was estimated by means of a mathematical algorithm and using UV spectroscopy. Resin characterization included particle size distribution, “settled” density and total anion exchange capacity, following ASTM D-2187. Values were compared with a porous commercial resin (Amberlite IRA900RF Cl). Since non porous structure with high ion exchange capacity resins were obtained, useful resins for ion exchange with long term stability can be prepared with this methodology. |
| doi_str_mv | 10.1007/s00289-007-0825-2 |
| format | Article |
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Anionic exchange resins with a gradient in polymer composition were prepared in two stages. After P(S-co-DVB) suspension beads were obtained, N,N-diethylaminoethyl methacrylate monomer was let to diffuse into the beads at 25 °C, and immediately photopolymerized to fix the gradient polymer composition with high surface concentration of ion exchanger. Chemical composition through the radial position was estimated by means of a mathematical algorithm and using UV spectroscopy. Resin characterization included particle size distribution, “settled” density and total anion exchange capacity, following ASTM D-2187. Values were compared with a porous commercial resin (Amberlite IRA900RF Cl). Since non porous structure with high ion exchange capacity resins were obtained, useful resins for ion exchange with long term stability can be prepared with this methodology.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-007-0825-2</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Algorithms ; Amberlite (trademark) ; Anion exchanging ; Applied sciences ; Characterization and Evaluation of Materials ; Chemical composition ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Concentration gradient ; Exact sciences and technology ; Exchange resins and membranes ; Forms of application and semi-finished materials ; Ion exchange ; Ion exchangers ; Organic Chemistry ; Particle size distribution ; Physical Chemistry ; Polymer industry, paints, wood ; Polymer Sciences ; Polymers ; Polystyrene resins ; Soft and Granular Matter ; Technology of polymers</subject><ispartof>Polymer bulletin (Berlin, Germany), 2008, Vol.59 (6), p.777-785</ispartof><rights>Springer-Verlag 2007</rights><rights>2008 INIST-CNRS</rights><rights>Springer-Verlag 2007.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-611783d4cee5de6b25c25399e7ead5322751714fa51784515a362a4ce5bfebe13</citedby><cites>FETCH-LOGICAL-c346t-611783d4cee5de6b25c25399e7ead5322751714fa51784515a362a4ce5bfebe13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-007-0825-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917970736?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>315,781,785,4025,21390,27925,27926,27927,33746,41490,42559,43807,51321,64387,64391,72471</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19949931$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Jasso-Gastinel, C. F.</creatorcontrib><creatorcontrib>García-Enriquez, S.</creatorcontrib><creatorcontrib>González-Ortiz, L. J.</creatorcontrib><title>Synthesis and Characterization of Anionic Exchange Resins with a Gradient in Polymer Composition for the PS-co-DVB/PDEAMA-co-DVB System</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>Summary
Anionic exchange resins with a gradient in polymer composition were prepared in two stages. After P(S-co-DVB) suspension beads were obtained, N,N-diethylaminoethyl methacrylate monomer was let to diffuse into the beads at 25 °C, and immediately photopolymerized to fix the gradient polymer composition with high surface concentration of ion exchanger. Chemical composition through the radial position was estimated by means of a mathematical algorithm and using UV spectroscopy. Resin characterization included particle size distribution, “settled” density and total anion exchange capacity, following ASTM D-2187. Values were compared with a porous commercial resin (Amberlite IRA900RF Cl). Since non porous structure with high ion exchange capacity resins were obtained, useful resins for ion exchange with long term stability can be prepared with this methodology.</description><subject>Algorithms</subject><subject>Amberlite (trademark)</subject><subject>Anion exchanging</subject><subject>Applied sciences</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Concentration gradient</subject><subject>Exact sciences and technology</subject><subject>Exchange resins and membranes</subject><subject>Forms of application and semi-finished materials</subject><subject>Ion exchange</subject><subject>Ion exchangers</subject><subject>Organic Chemistry</subject><subject>Particle size distribution</subject><subject>Physical Chemistry</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Polystyrene resins</subject><subject>Soft and Granular Matter</subject><subject>Technology of polymers</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kM9OAjEQxhujiYg-gLcmxmOlf7ZbekRANMFIRL1uSrcrJdBiu0TXF_C1LULCydN8k_nNN5MPgEuCbwjGohMxpl2JkkS4SzmiR6BFMpYjmmXyGLQwEThNmDwFZzEucOrznLTAz7Rx9dxEG6FyJezPVVC6NsF-q9p6B30Fey4Jq-HwS8-VezfwOeEuwk9bz6GCo6BKa1wNrYMTv2xWJsC-X619tH8OlQ8wXYCTKdIeDd5uO5PBsPfY23dw2sTarM7BSaWW0Vzsaxu83g1f-vdo_DR66PfGSLMsr1FOiOiyMtPG8NLkM8o15UxKI4wqOaNUcCJIVqlUuhknXLGcqoTzWWVmhrA2uNr5roP_2JhYFwu_CS6dLKgkQgosWJ4osqN08DEGUxXrYFcqNAXBxTbvYpd3sZXbvAuadq73zipqtayCctrGw6KUmZRs-wHdcTGNUpzh8MH_5r_vbo8S</recordid><startdate>2008</startdate><enddate>2008</enddate><creator>Jasso-Gastinel, C. F.</creator><creator>García-Enriquez, S.</creator><creator>González-Ortiz, L. J.</creator><general>Springer-Verlag</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>2008</creationdate><title>Synthesis and Characterization of Anionic Exchange Resins with a Gradient in Polymer Composition for the PS-co-DVB/PDEAMA-co-DVB System</title><author>Jasso-Gastinel, C. F. ; García-Enriquez, S. ; González-Ortiz, L. J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-611783d4cee5de6b25c25399e7ead5322751714fa51784515a362a4ce5bfebe13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Algorithms</topic><topic>Amberlite (trademark)</topic><topic>Anion exchanging</topic><topic>Applied sciences</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical composition</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Concentration gradient</topic><topic>Exact sciences and technology</topic><topic>Exchange resins and membranes</topic><topic>Forms of application and semi-finished materials</topic><topic>Ion exchange</topic><topic>Ion exchangers</topic><topic>Organic Chemistry</topic><topic>Particle size distribution</topic><topic>Physical Chemistry</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Polystyrene resins</topic><topic>Soft and Granular Matter</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jasso-Gastinel, C. F.</creatorcontrib><creatorcontrib>García-Enriquez, S.</creatorcontrib><creatorcontrib>González-Ortiz, L. J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>https://resources.nclive.org/materials</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jasso-Gastinel, C. F.</au><au>García-Enriquez, S.</au><au>González-Ortiz, L. J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of Anionic Exchange Resins with a Gradient in Polymer Composition for the PS-co-DVB/PDEAMA-co-DVB System</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2008</date><risdate>2008</risdate><volume>59</volume><issue>6</issue><spage>777</spage><epage>785</epage><pages>777-785</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>Summary
Anionic exchange resins with a gradient in polymer composition were prepared in two stages. After P(S-co-DVB) suspension beads were obtained, N,N-diethylaminoethyl methacrylate monomer was let to diffuse into the beads at 25 °C, and immediately photopolymerized to fix the gradient polymer composition with high surface concentration of ion exchanger. Chemical composition through the radial position was estimated by means of a mathematical algorithm and using UV spectroscopy. Resin characterization included particle size distribution, “settled” density and total anion exchange capacity, following ASTM D-2187. Values were compared with a porous commercial resin (Amberlite IRA900RF Cl). Since non porous structure with high ion exchange capacity resins were obtained, useful resins for ion exchange with long term stability can be prepared with this methodology.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00289-007-0825-2</doi><tpages>9</tpages></addata></record> |
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| subjects | Algorithms Amberlite (trademark) Anion exchanging Applied sciences Characterization and Evaluation of Materials Chemical composition Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Concentration gradient Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials Ion exchange Ion exchangers Organic Chemistry Particle size distribution Physical Chemistry Polymer industry, paints, wood Polymer Sciences Polymers Polystyrene resins Soft and Granular Matter Technology of polymers |
| title | Synthesis and Characterization of Anionic Exchange Resins with a Gradient in Polymer Composition for the PS-co-DVB/PDEAMA-co-DVB System |
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