Physical–chemical and biological properties of novel resin-based composites for dental applications

Insufficient mechanical properties of hydroxyapatite-based composites prompted the search for new and effective solutions for dental applications. To improve the mechanical properties without losing the remineralization potential, the use of hybrid fillers was proposed. The first of them was based o...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2023-10, Vol.80 (10), p.11249-11272
Hauptverfasser: Buchwald, Zuzanna, Sandomierski, Mariusz, Smułek, Wojciech, Ratajczak, Maria, Patalas, Adam, Kaczorek, Ewa, Voelkel, Adam
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container_issue 10
container_start_page 11249
container_title Polymer bulletin (Berlin, Germany)
container_volume 80
creator Buchwald, Zuzanna
Sandomierski, Mariusz
Smułek, Wojciech
Ratajczak, Maria
Patalas, Adam
Kaczorek, Ewa
Voelkel, Adam
description Insufficient mechanical properties of hydroxyapatite-based composites prompted the search for new and effective solutions for dental applications. To improve the mechanical properties without losing the remineralization potential, the use of hybrid fillers was proposed. The first of them was based on the formation of hydroxyapatite (HA) layer on the surface of SYLOID®244 silica. The second of the investigated fillers was created by simultaneous synthesis of nanoparticles from precursors of HA and silica. The obtained fillers were extensively characterized by spectral methods including X-ray Diffractometry (XRD), Fourier-Transform Infrared Spectroscopy (FT-IR), and X-ray fluorescence (XRF), as well as by Scanning Electron Microscopy (SEM)/Energy Dispersive Spectroscopy (EDS). Tests using probiotic microorganisms were an important part of the analysis, indicating that there was no potential interaction of the materials with microflora. The tests of degree of conversion, depth of cure, opacity, sorption, solubility, flexural and compressive strength, and the remineralizing potential also showed that the composites with nano-sized silica/HA showed better mechanical properties than the composites with HA alone or commercial silica and at the same time the remineralization remained at the desired level. Thus, the proposed composite has a high application potential in the creation of implants and dental materials. Graphical abstract
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To improve the mechanical properties without losing the remineralization potential, the use of hybrid fillers was proposed. The first of them was based on the formation of hydroxyapatite (HA) layer on the surface of SYLOID®244 silica. The second of the investigated fillers was created by simultaneous synthesis of nanoparticles from precursors of HA and silica. The obtained fillers were extensively characterized by spectral methods including X-ray Diffractometry (XRD), Fourier-Transform Infrared Spectroscopy (FT-IR), and X-ray fluorescence (XRF), as well as by Scanning Electron Microscopy (SEM)/Energy Dispersive Spectroscopy (EDS). Tests using probiotic microorganisms were an important part of the analysis, indicating that there was no potential interaction of the materials with microflora. The tests of degree of conversion, depth of cure, opacity, sorption, solubility, flexural and compressive strength, and the remineralizing potential also showed that the composites with nano-sized silica/HA showed better mechanical properties than the composites with HA alone or commercial silica and at the same time the remineralization remained at the desired level. Thus, the proposed composite has a high application potential in the creation of implants and dental materials. 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subjects Biological properties
Calcium phosphates
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Composite materials
Compressive strength
Dental materials
Fillers
Fourier transforms
Hydroxyapatite
Hypotheses
Infrared spectroscopy
Mechanical properties
Organic Chemistry
Original Paper
Physical Chemistry
Polymer Sciences
Potassium
Scanning electron microscopy
Silicon dioxide
Soft and Granular Matter
Spectral methods
Spectrum analysis
X-ray fluorescence
X-rays
title Physical–chemical and biological properties of novel resin-based composites for dental applications
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