Synergistic effect of carbon fabric and multiwalled carbon nanotubes on the fracture, wear and dynamic load response of epoxy-based multiscale composites
In this work, the effect of inclusion of 0.5 to 2 wt% multiwalled carbon nanotubes (MWCNT) in epoxy on the performance of the epoxy-carbon fabric (CF) composites is analyzed. High-resolution transmission electron microscopy (HRTEM) correlated the dispersion of the nanofillers and morphology of the n...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2022-07, Vol.79 (7), p.5063-5084 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | Sarath Kumar, P. Jayanarayanan, Karingamanna Deeraj, B. D. S. Joseph, K. Balachandran, Meera |
| description | In this work, the effect of inclusion of 0.5 to 2 wt% multiwalled carbon nanotubes (MWCNT) in epoxy on the performance of the epoxy-carbon fabric (CF) composites is analyzed. High-resolution transmission electron microscopy (HRTEM) correlated the dispersion of the nanofillers and morphology of the nanocomposites. The tensile and fracture properties of the composites improved significantly with MWCNT content. Beyond 1 wt%, the properties declined in both nano- and multiscale composites due to the agglomeration of MWCNTs. The wear rate showed a decreasing trend with increase in MWCNT content. The incorporation of MWCNTs resulted in a positive shift in the glass transition temperature (
T
g
) of the nanocomposites. The complex network formed between MWCNT and CF severely impeded the segmental mobility of the polymer chains which improved the storage modulus of the composites. From the tensile fracture surface analysis, the failure pattern of multiscale composites is found to be relatively ductile in comparison with epoxy-CF composites. |
| doi_str_mv | 10.1007/s00289-021-03742-6 |
| format | Article |
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T
g
) of the nanocomposites. The complex network formed between MWCNT and CF severely impeded the segmental mobility of the polymer chains which improved the storage modulus of the composites. From the tensile fracture surface analysis, the failure pattern of multiscale composites is found to be relatively ductile in comparison with epoxy-CF composites.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-021-03742-6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Carbon fiber reinforcement ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Crack initiation ; Crack propagation ; Dynamic loads ; Epoxy resins ; Fracture surfaces ; Glass transition temperature ; High resolution electron microscopy ; Mechanical properties ; Morphology ; Multi wall carbon nanotubes ; Nanocomposites ; Nanoparticles ; Organic Chemistry ; Original Paper ; Pattern analysis ; Physical Chemistry ; Polymer Sciences ; Polymers ; Shear strength ; Soft and Granular Matter ; Storage modulus ; Surface analysis (chemical) ; Synergistic effect ; Temperature ; Transmission electron microscopy ; Wear rate</subject><ispartof>Polymer bulletin (Berlin, Germany), 2022-07, Vol.79 (7), p.5063-5084</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-6b06adad71192a9ec49c0111fec8bf64be3da9509d205731d885a8803ba415cc3</citedby><cites>FETCH-LOGICAL-c319t-6b06adad71192a9ec49c0111fec8bf64be3da9509d205731d885a8803ba415cc3</cites><orcidid>0000-0002-0330-6553</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-021-03742-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917937311?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,777,781,21369,27905,27906,33725,41469,42538,43786,51300,64364,64368,72218</link.rule.ids></links><search><creatorcontrib>Sarath Kumar, P.</creatorcontrib><creatorcontrib>Jayanarayanan, Karingamanna</creatorcontrib><creatorcontrib>Deeraj, B. D. S.</creatorcontrib><creatorcontrib>Joseph, K.</creatorcontrib><creatorcontrib>Balachandran, Meera</creatorcontrib><title>Synergistic effect of carbon fabric and multiwalled carbon nanotubes on the fracture, wear and dynamic load response of epoxy-based multiscale composites</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>In this work, the effect of inclusion of 0.5 to 2 wt% multiwalled carbon nanotubes (MWCNT) in epoxy on the performance of the epoxy-carbon fabric (CF) composites is analyzed. High-resolution transmission electron microscopy (HRTEM) correlated the dispersion of the nanofillers and morphology of the nanocomposites. The tensile and fracture properties of the composites improved significantly with MWCNT content. Beyond 1 wt%, the properties declined in both nano- and multiscale composites due to the agglomeration of MWCNTs. The wear rate showed a decreasing trend with increase in MWCNT content. The incorporation of MWCNTs resulted in a positive shift in the glass transition temperature (
T
g
) of the nanocomposites. The complex network formed between MWCNT and CF severely impeded the segmental mobility of the polymer chains which improved the storage modulus of the composites. From the tensile fracture surface analysis, the failure pattern of multiscale composites is found to be relatively ductile in comparison with epoxy-CF composites.</description><subject>Carbon fiber reinforcement</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Crack initiation</subject><subject>Crack propagation</subject><subject>Dynamic loads</subject><subject>Epoxy resins</subject><subject>Fracture surfaces</subject><subject>Glass transition temperature</subject><subject>High resolution electron microscopy</subject><subject>Mechanical properties</subject><subject>Morphology</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Pattern analysis</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Shear strength</subject><subject>Soft and Granular Matter</subject><subject>Storage modulus</subject><subject>Surface analysis (chemical)</subject><subject>Synergistic effect</subject><subject>Temperature</subject><subject>Transmission electron microscopy</subject><subject>Wear rate</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kc1u1TAQhS0EEpe2L9CVJbYYZuLcJF6iij-pEgtgbU3sSUmVawfbUbmP0rfF7S1ix2o0M-c7o9ER4hLhLQL07zJAMxgFDSrQfduo7pnYYas71bSteS52gD0oGLR5KV7lfAu17zrciftvx8DpZs5ldpKniV2RcZKO0hiDnGhMdU7By8O2lPmOloX9322gEMs2cpa1KT9ZTolc2RK_kXdM6RHzx0CHarFE8jJxXmPI_HCB1_j7qEbK_OSdHS0sXTysMc-F87l4MdGS-eKpnokfHz98v_qsrr9--nL1_lo5jaaoboSOPPke0TRk2LXGASLWT4Zx6tqRtSezB-Mb2Pca_TDsaRhAj9Ti3jl9Jl6ffNcUf22ci72NWwr1pG0M9kZXCKuqOalcijknnuya5gOlo0WwDxHYUwS2RmAfI7BdhfQJylUcbjj9s_4P9QdLJYzO</recordid><startdate>20220701</startdate><enddate>20220701</enddate><creator>Sarath Kumar, P.</creator><creator>Jayanarayanan, Karingamanna</creator><creator>Deeraj, B. D. S.</creator><creator>Joseph, K.</creator><creator>Balachandran, Meera</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-0330-6553</orcidid></search><sort><creationdate>20220701</creationdate><title>Synergistic effect of carbon fabric and multiwalled carbon nanotubes on the fracture, wear and dynamic load response of epoxy-based multiscale composites</title><author>Sarath Kumar, P. ; Jayanarayanan, Karingamanna ; Deeraj, B. D. S. ; Joseph, K. ; Balachandran, Meera</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-6b06adad71192a9ec49c0111fec8bf64be3da9509d205731d885a8803ba415cc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Carbon fiber reinforcement</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Crack initiation</topic><topic>Crack propagation</topic><topic>Dynamic loads</topic><topic>Epoxy resins</topic><topic>Fracture surfaces</topic><topic>Glass transition temperature</topic><topic>High resolution electron microscopy</topic><topic>Mechanical properties</topic><topic>Morphology</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Pattern analysis</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Shear strength</topic><topic>Soft and Granular Matter</topic><topic>Storage modulus</topic><topic>Surface analysis (chemical)</topic><topic>Synergistic effect</topic><topic>Temperature</topic><topic>Transmission electron microscopy</topic><topic>Wear rate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sarath Kumar, P.</creatorcontrib><creatorcontrib>Jayanarayanan, Karingamanna</creatorcontrib><creatorcontrib>Deeraj, B. 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D. S.</au><au>Joseph, K.</au><au>Balachandran, Meera</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synergistic effect of carbon fabric and multiwalled carbon nanotubes on the fracture, wear and dynamic load response of epoxy-based multiscale composites</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2022-07-01</date><risdate>2022</risdate><volume>79</volume><issue>7</issue><spage>5063</spage><epage>5084</epage><pages>5063-5084</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>In this work, the effect of inclusion of 0.5 to 2 wt% multiwalled carbon nanotubes (MWCNT) in epoxy on the performance of the epoxy-carbon fabric (CF) composites is analyzed. High-resolution transmission electron microscopy (HRTEM) correlated the dispersion of the nanofillers and morphology of the nanocomposites. The tensile and fracture properties of the composites improved significantly with MWCNT content. Beyond 1 wt%, the properties declined in both nano- and multiscale composites due to the agglomeration of MWCNTs. The wear rate showed a decreasing trend with increase in MWCNT content. The incorporation of MWCNTs resulted in a positive shift in the glass transition temperature (
T
g
) of the nanocomposites. The complex network formed between MWCNT and CF severely impeded the segmental mobility of the polymer chains which improved the storage modulus of the composites. From the tensile fracture surface analysis, the failure pattern of multiscale composites is found to be relatively ductile in comparison with epoxy-CF composites.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-021-03742-6</doi><tpages>22</tpages><orcidid>https://orcid.org/0000-0002-0330-6553</orcidid></addata></record> |
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| subjects | Carbon fiber reinforcement Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Crack initiation Crack propagation Dynamic loads Epoxy resins Fracture surfaces Glass transition temperature High resolution electron microscopy Mechanical properties Morphology Multi wall carbon nanotubes Nanocomposites Nanoparticles Organic Chemistry Original Paper Pattern analysis Physical Chemistry Polymer Sciences Polymers Shear strength Soft and Granular Matter Storage modulus Surface analysis (chemical) Synergistic effect Temperature Transmission electron microscopy Wear rate |
| title | Synergistic effect of carbon fabric and multiwalled carbon nanotubes on the fracture, wear and dynamic load response of epoxy-based multiscale composites |
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