Synthesis and characterization of novel energetic thermoplastic elastomers based on glycidyl azide polymer (GAP) with bonding functions
The energetic thermoplastic elastomers (ETPE) of glycidyl azide polymer with bonding functions were synthesized by using mixture of chain extenders including 1,4-butanediol and N -(2-cyanoethyl) diethanolamine. From FTIR results, the ability of ETPEs to form hydrogen bond weakened with the percentag...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2015-08, Vol.72 (8), p.1835-1847 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | Zhang, Zaijuan Wang, Gang Wang, Zhen Zhang, Yilu Ge, Zhen Luo, Yunjun |
| description | The energetic thermoplastic elastomers (ETPE) of glycidyl azide polymer with bonding functions were synthesized by using mixture of chain extenders including 1,4-butanediol and
N
-(2-cyanoethyl) diethanolamine. From FTIR results, the ability of ETPEs to form hydrogen bond weakened with the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, which further lead to the decrease of maximum stress of ETPEs and increase of elongation at break. On the other hand, the interfacial interactions between solid ingredients and ETPEs were enhanced owing to the more –CN content. With the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, two factors affect the adhesion between binder and fillers at the same time. The RDX/ETPE propellants were synthesized and the mechanical properties of them showed that the ETPE-50 with bonding functions can effectively prevent the dewetting, and then improve the mechanical properties of propellants. That is, when the percentage of
N
-(2-cyanoethyl) diethanolamine was 50 %, the synthesized ETPEs had not only binding function but also bonding interaction. |
| doi_str_mv | 10.1007/s00289-015-1375-7 |
| format | Article |
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N
-(2-cyanoethyl) diethanolamine. From FTIR results, the ability of ETPEs to form hydrogen bond weakened with the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, which further lead to the decrease of maximum stress of ETPEs and increase of elongation at break. On the other hand, the interfacial interactions between solid ingredients and ETPEs were enhanced owing to the more –CN content. With the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, two factors affect the adhesion between binder and fillers at the same time. The RDX/ETPE propellants were synthesized and the mechanical properties of them showed that the ETPE-50 with bonding functions can effectively prevent the dewetting, and then improve the mechanical properties of propellants. That is, when the percentage of
N
-(2-cyanoethyl) diethanolamine was 50 %, the synthesized ETPEs had not only binding function but also bonding interaction.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-015-1375-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Adhesives ; Bonding ; Butanediol ; Characterization and Evaluation of Materials ; Chemical plants ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Contact angle ; Curing ; Diethanolamine ; Elongation ; Glycidyl azide polymer ; Hydrogen ; Hydrogen bonds ; Mechanical properties ; Molecular weight ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer Sciences ; Polymers ; Propellants ; Soft and Granular Matter ; Synthesis ; Thermoplastic elastomers</subject><ispartof>Polymer bulletin (Berlin, Germany), 2015-08, Vol.72 (8), p.1835-1847</ispartof><rights>Springer-Verlag Berlin Heidelberg 2015</rights><rights>Springer-Verlag Berlin Heidelberg 2015.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c423t-153e90ec2c66c7c49937d4a657568f4ca6e0ba8554a7b78cb8b6fda6b405485a3</citedby><cites>FETCH-LOGICAL-c423t-153e90ec2c66c7c49937d4a657568f4ca6e0ba8554a7b78cb8b6fda6b405485a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-015-1375-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917935548?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21387,27923,27924,33743,41487,42556,43804,51318,64384,64388,72240</link.rule.ids></links><search><creatorcontrib>Zhang, Zaijuan</creatorcontrib><creatorcontrib>Wang, Gang</creatorcontrib><creatorcontrib>Wang, Zhen</creatorcontrib><creatorcontrib>Zhang, Yilu</creatorcontrib><creatorcontrib>Ge, Zhen</creatorcontrib><creatorcontrib>Luo, Yunjun</creatorcontrib><title>Synthesis and characterization of novel energetic thermoplastic elastomers based on glycidyl azide polymer (GAP) with bonding functions</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>The energetic thermoplastic elastomers (ETPE) of glycidyl azide polymer with bonding functions were synthesized by using mixture of chain extenders including 1,4-butanediol and
N
-(2-cyanoethyl) diethanolamine. From FTIR results, the ability of ETPEs to form hydrogen bond weakened with the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, which further lead to the decrease of maximum stress of ETPEs and increase of elongation at break. On the other hand, the interfacial interactions between solid ingredients and ETPEs were enhanced owing to the more –CN content. With the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, two factors affect the adhesion between binder and fillers at the same time. The RDX/ETPE propellants were synthesized and the mechanical properties of them showed that the ETPE-50 with bonding functions can effectively prevent the dewetting, and then improve the mechanical properties of propellants. That is, when the percentage of
N
-(2-cyanoethyl) diethanolamine was 50 %, the synthesized ETPEs had not only binding function but also bonding interaction.</description><subject>Adhesives</subject><subject>Bonding</subject><subject>Butanediol</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical plants</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Contact angle</subject><subject>Curing</subject><subject>Diethanolamine</subject><subject>Elongation</subject><subject>Glycidyl azide polymer</subject><subject>Hydrogen</subject><subject>Hydrogen bonds</subject><subject>Mechanical properties</subject><subject>Molecular weight</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Propellants</subject><subject>Soft and Granular Matter</subject><subject>Synthesis</subject><subject>Thermoplastic elastomers</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kM1KxDAUhYMoOP48gLuAG11UkzY_7VIGHYUBBXUd0vS2E-kkY9JR6gv42qaM4MrV4cL33QMHoTNKrigh8joSkpdVRijPaCF5JvfQjLJCZDlj1T6aESpJRsqiOkRHMb6RdAtBZ-j7eXTDCqKNWLsGm5UO2gwQ7JcerHfYt9j5D-gxOAgdDNbghIe13_Q6ThdM6dcQIq51hAYnqetHY5uxx_rLNoA3vh8TgC8WN0-X-NMOK1x711jX4XbrzNQTT9BBq_sIp795jF7vbl_m99nycfEwv1lmhuXFkFFeQEXA5EYIIw2rqkI2TAsuuShbZrQAUuuSc6ZlLUtTl7VoGy1qRjgruS6O0fnu7yb49y3EQb35bXCpUuUVlVWR1DJRdEeZ4GMM0KpNsGsdRkWJmvZWu71V2ltNeyuZnHznxMS6DsLf5_-lHyXwhb0</recordid><startdate>20150801</startdate><enddate>20150801</enddate><creator>Zhang, Zaijuan</creator><creator>Wang, Gang</creator><creator>Wang, Zhen</creator><creator>Zhang, Yilu</creator><creator>Ge, Zhen</creator><creator>Luo, Yunjun</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20150801</creationdate><title>Synthesis and characterization of novel energetic thermoplastic elastomers based on glycidyl azide polymer (GAP) with bonding functions</title><author>Zhang, Zaijuan ; Wang, Gang ; Wang, Zhen ; Zhang, Yilu ; Ge, Zhen ; Luo, Yunjun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c423t-153e90ec2c66c7c49937d4a657568f4ca6e0ba8554a7b78cb8b6fda6b405485a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Adhesives</topic><topic>Bonding</topic><topic>Butanediol</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical plants</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Contact angle</topic><topic>Curing</topic><topic>Diethanolamine</topic><topic>Elongation</topic><topic>Glycidyl azide polymer</topic><topic>Hydrogen</topic><topic>Hydrogen bonds</topic><topic>Mechanical properties</topic><topic>Molecular weight</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Propellants</topic><topic>Soft and Granular Matter</topic><topic>Synthesis</topic><topic>Thermoplastic elastomers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Zaijuan</creatorcontrib><creatorcontrib>Wang, Gang</creatorcontrib><creatorcontrib>Wang, Zhen</creatorcontrib><creatorcontrib>Zhang, Yilu</creatorcontrib><creatorcontrib>Ge, Zhen</creatorcontrib><creatorcontrib>Luo, Yunjun</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Zaijuan</au><au>Wang, Gang</au><au>Wang, Zhen</au><au>Zhang, Yilu</au><au>Ge, Zhen</au><au>Luo, Yunjun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of novel energetic thermoplastic elastomers based on glycidyl azide polymer (GAP) with bonding functions</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2015-08-01</date><risdate>2015</risdate><volume>72</volume><issue>8</issue><spage>1835</spage><epage>1847</epage><pages>1835-1847</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>The energetic thermoplastic elastomers (ETPE) of glycidyl azide polymer with bonding functions were synthesized by using mixture of chain extenders including 1,4-butanediol and
N
-(2-cyanoethyl) diethanolamine. From FTIR results, the ability of ETPEs to form hydrogen bond weakened with the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, which further lead to the decrease of maximum stress of ETPEs and increase of elongation at break. On the other hand, the interfacial interactions between solid ingredients and ETPEs were enhanced owing to the more –CN content. With the percentage of
N
-(2-cyanoethyl) diethanolamine increasing, two factors affect the adhesion between binder and fillers at the same time. The RDX/ETPE propellants were synthesized and the mechanical properties of them showed that the ETPE-50 with bonding functions can effectively prevent the dewetting, and then improve the mechanical properties of propellants. That is, when the percentage of
N
-(2-cyanoethyl) diethanolamine was 50 %, the synthesized ETPEs had not only binding function but also bonding interaction.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-015-1375-7</doi><tpages>13</tpages></addata></record> |
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| ispartof | Polymer bulletin (Berlin, Germany), 2015-08, Vol.72 (8), p.1835-1847 |
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| subjects | Adhesives Bonding Butanediol Characterization and Evaluation of Materials Chemical plants Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Contact angle Curing Diethanolamine Elongation Glycidyl azide polymer Hydrogen Hydrogen bonds Mechanical properties Molecular weight Organic Chemistry Original Paper Physical Chemistry Polymer Sciences Polymers Propellants Soft and Granular Matter Synthesis Thermoplastic elastomers |
| title | Synthesis and characterization of novel energetic thermoplastic elastomers based on glycidyl azide polymer (GAP) with bonding functions |
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