Enhancing the electrochromic performances of polyaniline film through incorporating polyaniline nanofibers synthesized by interfacial polymerization approach
In this paper, we demonstrate a simple approach to improve the electrochromic performances of polyaniline (PANI) by incorporating PANI nanofibers (PANI-NFs) synthesized by interfacial polymerization into water-soluble PANI:poly(styrene sulfonate) (PANI:PSS). The one-dimensional PANI-NFs endow spin-c...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2018-08, Vol.75 (8), p.3427-3443 |
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| creator | Xiong, Shanxin Wang, Yuyun Lu, Yizhang Li, Haifu Liu, Jian Li, Shuai Qiu, Zhu Gong, Ming Wu, Bohua Chu, Jia Wang, Xiaoqin Zhang, Runlan |
| description | In this paper, we demonstrate a simple approach to improve the electrochromic performances of polyaniline (PANI) by incorporating PANI nanofibers (PANI-NFs) synthesized by interfacial polymerization into water-soluble PANI:poly(styrene sulfonate) (PANI:PSS). The one-dimensional PANI-NFs endow spin-coated PANI film high electrochemical activities and electrochromic properties. The structures and morphologies of PANI-NFs were characterized by FTIR spectroscopy and SEM observation. The electrochemical behaviors of PANI/PANI-NFs composites were analyzed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The electrochromic properties of composites were tested using electrochemical working station combining a UV-Vis spectrometer. The results show that the PANI-NFs with even diameter of ~ 30 nm can be synthesized easily using interfacial polymerization method. With the increasing of feeding amount of PANI-NFs, the oxidation peaks of CV curves shift to low potential direction, indicating enhanced electrochemical activities. The electrochromic test confirms that the PANI/PANI-NFs composites films have higher electrochromic contrast of 0.67 as comparison to 0.49 of PANI:PSS film. The PANI/PANI-NFs also exhibit excellent electrochromic stability. After 2000 cycles switching, only less than 4% contrast decay is observed. The enhanced electrochromic properties can be attributed to the small charge-transfer resistance and facile ion diffusion process brought by PANI-NFs. The EIS tests exhibit that with incorporating of highly conductive PANI-NFs, the PANI/PANI-NFs composites possess relatively lower charge-transfer resistance of 76 Ω as comparison to 94 Ω of neat PANI:PSS.
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| doi_str_mv | 10.1007/s00289-017-2216-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2917880095</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2917880095</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-13e3179c7685da8953edc9451c4cfe0bee11cfbc8bb2335c9d0f3255670c06553</originalsourceid><addsrcrecordid>eNp1kc1OxCAUhYnRxHH0AdyRuK5CKW1ZGuNfYuJG14TeuUwxLVToLMZ38V1lHBPduCKE7zsn4RByztklZ6y5SoyVrSoYb4qy5HXRHJAFr0RdlFWlDskiP7CCtUIdk5OU3li-1zVfkM9b3xsPzq_p3CPFAWGOAfoYRgd0wmhDHDOAiQZLpzBsjXeD80itG8bsxLBZ99R5CHEK0cy7pL-YNz5Y12FMNG197kjuA1e022ZnzvEGnBm-jRGj-8gBwVMzTTEY6E_JkTVDwrOfc0le725fbh6Kp-f7x5vrpwKEFHPBBQreKGjqVq5Mq6TAFahKcqjAIusQOQfbQdt1pRAS1IpZUUpZNwxYLaVYkot9bq5932Ca9VvYRJ8rdal407aMqR3F9xTEkFJEq6foRhO3mjO9W0HvV9D5c_VuBd1kp9w7KbN-jfE3-X_pC1w4kAo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2917880095</pqid></control><display><type>article</type><title>Enhancing the electrochromic performances of polyaniline film through incorporating polyaniline nanofibers synthesized by interfacial polymerization approach</title><source>SpringerLink Journals</source><source>ProQuest Central UK/Ireland</source><source>ProQuest Central</source><creator>Xiong, Shanxin ; Wang, Yuyun ; Lu, Yizhang ; Li, Haifu ; Liu, Jian ; Li, Shuai ; Qiu, Zhu ; Gong, Ming ; Wu, Bohua ; Chu, Jia ; Wang, Xiaoqin ; Zhang, Runlan</creator><creatorcontrib>Xiong, Shanxin ; Wang, Yuyun ; Lu, Yizhang ; Li, Haifu ; Liu, Jian ; Li, Shuai ; Qiu, Zhu ; Gong, Ming ; Wu, Bohua ; Chu, Jia ; Wang, Xiaoqin ; Zhang, Runlan</creatorcontrib><description>In this paper, we demonstrate a simple approach to improve the electrochromic performances of polyaniline (PANI) by incorporating PANI nanofibers (PANI-NFs) synthesized by interfacial polymerization into water-soluble PANI:poly(styrene sulfonate) (PANI:PSS). The one-dimensional PANI-NFs endow spin-coated PANI film high electrochemical activities and electrochromic properties. The structures and morphologies of PANI-NFs were characterized by FTIR spectroscopy and SEM observation. The electrochemical behaviors of PANI/PANI-NFs composites were analyzed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The electrochromic properties of composites were tested using electrochemical working station combining a UV-Vis spectrometer. The results show that the PANI-NFs with even diameter of ~ 30 nm can be synthesized easily using interfacial polymerization method. With the increasing of feeding amount of PANI-NFs, the oxidation peaks of CV curves shift to low potential direction, indicating enhanced electrochemical activities. The electrochromic test confirms that the PANI/PANI-NFs composites films have higher electrochromic contrast of 0.67 as comparison to 0.49 of PANI:PSS film. The PANI/PANI-NFs also exhibit excellent electrochromic stability. After 2000 cycles switching, only less than 4% contrast decay is observed. The enhanced electrochromic properties can be attributed to the small charge-transfer resistance and facile ion diffusion process brought by PANI-NFs. The EIS tests exhibit that with incorporating of highly conductive PANI-NFs, the PANI/PANI-NFs composites possess relatively lower charge-transfer resistance of 76 Ω as comparison to 94 Ω of neat PANI:PSS.
Graphical abstract</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-017-2216-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aqueous solutions ; Characterization and Evaluation of Materials ; Charge transfer ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Composite materials ; Diameters ; Electric properties ; Electrochemical impedance spectroscopy ; Electrochromism ; Electrodes ; Electrolytes ; Fourier transforms ; Ion diffusion ; Nanocomposites ; Nanofibers ; Nanowires ; Organic Chemistry ; Original Paper ; Oxidation ; Physical Chemistry ; Polyanilines ; Polymer Sciences ; Polymerization ; Polymers ; Polystyrene resins ; Soft and Granular Matter ; Spin coating ; Synthesis</subject><ispartof>Polymer bulletin (Berlin, Germany), 2018-08, Vol.75 (8), p.3427-3443</ispartof><rights>Springer-Verlag GmbH Germany 2017</rights><rights>Springer-Verlag GmbH Germany 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-13e3179c7685da8953edc9451c4cfe0bee11cfbc8bb2335c9d0f3255670c06553</citedby><cites>FETCH-LOGICAL-c353t-13e3179c7685da8953edc9451c4cfe0bee11cfbc8bb2335c9d0f3255670c06553</cites><orcidid>0000-0002-6293-3872</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-017-2216-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917880095?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,777,781,21369,27905,27906,33725,41469,42538,43786,51300,64364,64368,72218</link.rule.ids></links><search><creatorcontrib>Xiong, Shanxin</creatorcontrib><creatorcontrib>Wang, Yuyun</creatorcontrib><creatorcontrib>Lu, Yizhang</creatorcontrib><creatorcontrib>Li, Haifu</creatorcontrib><creatorcontrib>Liu, Jian</creatorcontrib><creatorcontrib>Li, Shuai</creatorcontrib><creatorcontrib>Qiu, Zhu</creatorcontrib><creatorcontrib>Gong, Ming</creatorcontrib><creatorcontrib>Wu, Bohua</creatorcontrib><creatorcontrib>Chu, Jia</creatorcontrib><creatorcontrib>Wang, Xiaoqin</creatorcontrib><creatorcontrib>Zhang, Runlan</creatorcontrib><title>Enhancing the electrochromic performances of polyaniline film through incorporating polyaniline nanofibers synthesized by interfacial polymerization approach</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>In this paper, we demonstrate a simple approach to improve the electrochromic performances of polyaniline (PANI) by incorporating PANI nanofibers (PANI-NFs) synthesized by interfacial polymerization into water-soluble PANI:poly(styrene sulfonate) (PANI:PSS). The one-dimensional PANI-NFs endow spin-coated PANI film high electrochemical activities and electrochromic properties. The structures and morphologies of PANI-NFs were characterized by FTIR spectroscopy and SEM observation. The electrochemical behaviors of PANI/PANI-NFs composites were analyzed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The electrochromic properties of composites were tested using electrochemical working station combining a UV-Vis spectrometer. The results show that the PANI-NFs with even diameter of ~ 30 nm can be synthesized easily using interfacial polymerization method. With the increasing of feeding amount of PANI-NFs, the oxidation peaks of CV curves shift to low potential direction, indicating enhanced electrochemical activities. The electrochromic test confirms that the PANI/PANI-NFs composites films have higher electrochromic contrast of 0.67 as comparison to 0.49 of PANI:PSS film. The PANI/PANI-NFs also exhibit excellent electrochromic stability. After 2000 cycles switching, only less than 4% contrast decay is observed. The enhanced electrochromic properties can be attributed to the small charge-transfer resistance and facile ion diffusion process brought by PANI-NFs. The EIS tests exhibit that with incorporating of highly conductive PANI-NFs, the PANI/PANI-NFs composites possess relatively lower charge-transfer resistance of 76 Ω as comparison to 94 Ω of neat PANI:PSS.
Graphical abstract</description><subject>Aqueous solutions</subject><subject>Characterization and Evaluation of Materials</subject><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Composite materials</subject><subject>Diameters</subject><subject>Electric properties</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochromism</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Fourier transforms</subject><subject>Ion diffusion</subject><subject>Nanocomposites</subject><subject>Nanofibers</subject><subject>Nanowires</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Polyanilines</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polystyrene resins</subject><subject>Soft and Granular Matter</subject><subject>Spin coating</subject><subject>Synthesis</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kc1OxCAUhYnRxHH0AdyRuK5CKW1ZGuNfYuJG14TeuUwxLVToLMZ38V1lHBPduCKE7zsn4RByztklZ6y5SoyVrSoYb4qy5HXRHJAFr0RdlFWlDskiP7CCtUIdk5OU3li-1zVfkM9b3xsPzq_p3CPFAWGOAfoYRgd0wmhDHDOAiQZLpzBsjXeD80itG8bsxLBZ99R5CHEK0cy7pL-YNz5Y12FMNG197kjuA1e022ZnzvEGnBm-jRGj-8gBwVMzTTEY6E_JkTVDwrOfc0le725fbh6Kp-f7x5vrpwKEFHPBBQreKGjqVq5Mq6TAFahKcqjAIusQOQfbQdt1pRAS1IpZUUpZNwxYLaVYkot9bq5932Ca9VvYRJ8rdal407aMqR3F9xTEkFJEq6foRhO3mjO9W0HvV9D5c_VuBd1kp9w7KbN-jfE3-X_pC1w4kAo</recordid><startdate>20180801</startdate><enddate>20180801</enddate><creator>Xiong, Shanxin</creator><creator>Wang, Yuyun</creator><creator>Lu, Yizhang</creator><creator>Li, Haifu</creator><creator>Liu, Jian</creator><creator>Li, Shuai</creator><creator>Qiu, Zhu</creator><creator>Gong, Ming</creator><creator>Wu, Bohua</creator><creator>Chu, Jia</creator><creator>Wang, Xiaoqin</creator><creator>Zhang, Runlan</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-6293-3872</orcidid></search><sort><creationdate>20180801</creationdate><title>Enhancing the electrochromic performances of polyaniline film through incorporating polyaniline nanofibers synthesized by interfacial polymerization approach</title><author>Xiong, Shanxin ; Wang, Yuyun ; Lu, Yizhang ; Li, Haifu ; Liu, Jian ; Li, Shuai ; Qiu, Zhu ; Gong, Ming ; Wu, Bohua ; Chu, Jia ; Wang, Xiaoqin ; Zhang, Runlan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-13e3179c7685da8953edc9451c4cfe0bee11cfbc8bb2335c9d0f3255670c06553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aqueous solutions</topic><topic>Characterization and Evaluation of Materials</topic><topic>Charge transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Composite materials</topic><topic>Diameters</topic><topic>Electric properties</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochromism</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Fourier transforms</topic><topic>Ion diffusion</topic><topic>Nanocomposites</topic><topic>Nanofibers</topic><topic>Nanowires</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Polyanilines</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polystyrene resins</topic><topic>Soft and Granular Matter</topic><topic>Spin coating</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiong, Shanxin</creatorcontrib><creatorcontrib>Wang, Yuyun</creatorcontrib><creatorcontrib>Lu, Yizhang</creatorcontrib><creatorcontrib>Li, Haifu</creatorcontrib><creatorcontrib>Liu, Jian</creatorcontrib><creatorcontrib>Li, Shuai</creatorcontrib><creatorcontrib>Qiu, Zhu</creatorcontrib><creatorcontrib>Gong, Ming</creatorcontrib><creatorcontrib>Wu, Bohua</creatorcontrib><creatorcontrib>Chu, Jia</creatorcontrib><creatorcontrib>Wang, Xiaoqin</creatorcontrib><creatorcontrib>Zhang, Runlan</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiong, Shanxin</au><au>Wang, Yuyun</au><au>Lu, Yizhang</au><au>Li, Haifu</au><au>Liu, Jian</au><au>Li, Shuai</au><au>Qiu, Zhu</au><au>Gong, Ming</au><au>Wu, Bohua</au><au>Chu, Jia</au><au>Wang, Xiaoqin</au><au>Zhang, Runlan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancing the electrochromic performances of polyaniline film through incorporating polyaniline nanofibers synthesized by interfacial polymerization approach</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2018-08-01</date><risdate>2018</risdate><volume>75</volume><issue>8</issue><spage>3427</spage><epage>3443</epage><pages>3427-3443</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>In this paper, we demonstrate a simple approach to improve the electrochromic performances of polyaniline (PANI) by incorporating PANI nanofibers (PANI-NFs) synthesized by interfacial polymerization into water-soluble PANI:poly(styrene sulfonate) (PANI:PSS). The one-dimensional PANI-NFs endow spin-coated PANI film high electrochemical activities and electrochromic properties. The structures and morphologies of PANI-NFs were characterized by FTIR spectroscopy and SEM observation. The electrochemical behaviors of PANI/PANI-NFs composites were analyzed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The electrochromic properties of composites were tested using electrochemical working station combining a UV-Vis spectrometer. The results show that the PANI-NFs with even diameter of ~ 30 nm can be synthesized easily using interfacial polymerization method. With the increasing of feeding amount of PANI-NFs, the oxidation peaks of CV curves shift to low potential direction, indicating enhanced electrochemical activities. The electrochromic test confirms that the PANI/PANI-NFs composites films have higher electrochromic contrast of 0.67 as comparison to 0.49 of PANI:PSS film. The PANI/PANI-NFs also exhibit excellent electrochromic stability. After 2000 cycles switching, only less than 4% contrast decay is observed. The enhanced electrochromic properties can be attributed to the small charge-transfer resistance and facile ion diffusion process brought by PANI-NFs. The EIS tests exhibit that with incorporating of highly conductive PANI-NFs, the PANI/PANI-NFs composites possess relatively lower charge-transfer resistance of 76 Ω as comparison to 94 Ω of neat PANI:PSS.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-017-2216-7</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0002-6293-3872</orcidid></addata></record> |
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| subjects | Aqueous solutions Characterization and Evaluation of Materials Charge transfer Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Composite materials Diameters Electric properties Electrochemical impedance spectroscopy Electrochromism Electrodes Electrolytes Fourier transforms Ion diffusion Nanocomposites Nanofibers Nanowires Organic Chemistry Original Paper Oxidation Physical Chemistry Polyanilines Polymer Sciences Polymerization Polymers Polystyrene resins Soft and Granular Matter Spin coating Synthesis |
| title | Enhancing the electrochromic performances of polyaniline film through incorporating polyaniline nanofibers synthesized by interfacial polymerization approach |
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