Photocatalytic activity of polyaniline and neutral polyaniline for degradation of methylene blue and malachite green dyes under UV Light
A polyaniline (PANI) and neutral Polyaniline (NPANI) have been synthesized in acetonitrile–water mixture via the chemical oxidative polymerization of aniline. Scanning electron microscopy, FTIR spectra, UV–vis spectroscopy measurements were used to characterize the resulting PANI and NPANI. The phot...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2021-05, Vol.78 (5), p.2849-2865 |
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| creator | Haspulat Taymaz, Bircan Taş, Recep Kamış, Handan Can, Muzaffer |
| description | A polyaniline (PANI) and neutral Polyaniline (NPANI) have been synthesized in acetonitrile–water mixture via the chemical oxidative polymerization of aniline. Scanning electron microscopy, FTIR spectra, UV–vis spectroscopy measurements were used to characterize the resulting PANI and NPANI. The photocatalytic activities of PANI and NPANI were investigated by the degradation of methylene blue (MB) and malachite green (MG) dyes in aqueous medium under UV light irradiation. MB and MG dyes completely degraded under UV light irradiation in the presence of NPANI after 60 and 75 min, respectively. The effect of dye type, irradiation time, dye concentration and photocatalyst amount on photocatalytic performance of PANI and NPANI have been examined under UV light irradiation. Three kinetic models have proposed for photocatalytic degradation of dyes by using PANI and NPANI under UV light illumination. This work explores the easy way to synthesize efficient PANI and NPANI polymers to degrade organic compound under both UV and visible light irradiations. |
| doi_str_mv | 10.1007/s00289-021-03674-1 |
| format | Article |
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Scanning electron microscopy, FTIR spectra, UV–vis spectroscopy measurements were used to characterize the resulting PANI and NPANI. The photocatalytic activities of PANI and NPANI were investigated by the degradation of methylene blue (MB) and malachite green (MG) dyes in aqueous medium under UV light irradiation. MB and MG dyes completely degraded under UV light irradiation in the presence of NPANI after 60 and 75 min, respectively. The effect of dye type, irradiation time, dye concentration and photocatalyst amount on photocatalytic performance of PANI and NPANI have been examined under UV light irradiation. Three kinetic models have proposed for photocatalytic degradation of dyes by using PANI and NPANI under UV light illumination. This work explores the easy way to synthesize efficient PANI and NPANI polymers to degrade organic compound under both UV and visible light irradiations.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-021-03674-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acetonitrile ; Aniline ; Aqueous solutions ; Catalytic activity ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Dyes ; Fourier transforms ; Light ; Light irradiation ; Malachite green ; Methylene blue ; Morphology ; Organic Chemistry ; Organic compounds ; Original Paper ; Oxidation ; Photocatalysis ; Photodegradation ; Physical Chemistry ; Pollutants ; Polyanilines ; Polymer Sciences ; Polymerization ; Polymers ; Scanning electron microscopy ; Soft and Granular Matter ; Ultraviolet radiation</subject><ispartof>Polymer bulletin (Berlin, Germany), 2021-05, Vol.78 (5), p.2849-2865</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-20e095021ba271cbbac2f9290ab4eda6d6f2d29ea3db5360db84ab0881c26ede3</citedby><cites>FETCH-LOGICAL-c356t-20e095021ba271cbbac2f9290ab4eda6d6f2d29ea3db5360db84ab0881c26ede3</cites><orcidid>0000-0002-5170-322X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-021-03674-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917875397?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,778,782,21371,27907,27908,33727,41471,42540,43788,51302,64366,64370,72220</link.rule.ids></links><search><creatorcontrib>Haspulat Taymaz, Bircan</creatorcontrib><creatorcontrib>Taş, Recep</creatorcontrib><creatorcontrib>Kamış, Handan</creatorcontrib><creatorcontrib>Can, Muzaffer</creatorcontrib><title>Photocatalytic activity of polyaniline and neutral polyaniline for degradation of methylene blue and malachite green dyes under UV Light</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>A polyaniline (PANI) and neutral Polyaniline (NPANI) have been synthesized in acetonitrile–water mixture via the chemical oxidative polymerization of aniline. Scanning electron microscopy, FTIR spectra, UV–vis spectroscopy measurements were used to characterize the resulting PANI and NPANI. The photocatalytic activities of PANI and NPANI were investigated by the degradation of methylene blue (MB) and malachite green (MG) dyes in aqueous medium under UV light irradiation. MB and MG dyes completely degraded under UV light irradiation in the presence of NPANI after 60 and 75 min, respectively. The effect of dye type, irradiation time, dye concentration and photocatalyst amount on photocatalytic performance of PANI and NPANI have been examined under UV light irradiation. Three kinetic models have proposed for photocatalytic degradation of dyes by using PANI and NPANI under UV light illumination. This work explores the easy way to synthesize efficient PANI and NPANI polymers to degrade organic compound under both UV and visible light irradiations.</description><subject>Acetonitrile</subject><subject>Aniline</subject><subject>Aqueous solutions</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Dyes</subject><subject>Fourier transforms</subject><subject>Light</subject><subject>Light irradiation</subject><subject>Malachite green</subject><subject>Methylene blue</subject><subject>Morphology</subject><subject>Organic Chemistry</subject><subject>Organic compounds</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Photodegradation</subject><subject>Physical Chemistry</subject><subject>Pollutants</subject><subject>Polyanilines</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Scanning electron microscopy</subject><subject>Soft and Granular Matter</subject><subject>Ultraviolet radiation</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1v1DAQhi1EpS4tf6AnS5wDYzvrxEdU8SWtBAfK1ZrYk11XWXuxHaT8A342KUFCXDiNZuZ95uNl7E7AawHQvSkAsjcNSNGA0l3biGdsJ1qlG9m25jnbgeiggV6Za_ailEdYc63Fjv38cko1Oaw4LTU4jq6GH6EuPI38kqYFY5hCJI7R80hzzTj9Ux9T5p6OGT3WkOITdqZ6WiZam8M0b-QZJ3SnUIkfM1HkfqHC5-gp84dv_BCOp3rLrkacCr38E2_Yw_t3X-8_NofPHz7dvz00Tu11bSQQmP3654CyE24Y0MnRSAM4tORRez1KLw2h8sNeafBD3-IAfS-c1ORJ3bBX29xLTt9nKtU-pjnHdaWVRnR9t1emW1VyU7mcSsk02ksOZ8yLFWCfHLeb43a9xP523IoVUhtUVnE8Uv47-j_UL3KyhzA</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Haspulat Taymaz, Bircan</creator><creator>Taş, Recep</creator><creator>Kamış, Handan</creator><creator>Can, Muzaffer</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-5170-322X</orcidid></search><sort><creationdate>20210501</creationdate><title>Photocatalytic activity of polyaniline and neutral polyaniline for degradation of methylene blue and malachite green dyes under UV Light</title><author>Haspulat Taymaz, Bircan ; Taş, Recep ; Kamış, Handan ; Can, Muzaffer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-20e095021ba271cbbac2f9290ab4eda6d6f2d29ea3db5360db84ab0881c26ede3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acetonitrile</topic><topic>Aniline</topic><topic>Aqueous solutions</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Dyes</topic><topic>Fourier transforms</topic><topic>Light</topic><topic>Light irradiation</topic><topic>Malachite green</topic><topic>Methylene blue</topic><topic>Morphology</topic><topic>Organic Chemistry</topic><topic>Organic compounds</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Photodegradation</topic><topic>Physical Chemistry</topic><topic>Pollutants</topic><topic>Polyanilines</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Scanning electron microscopy</topic><topic>Soft and Granular Matter</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Haspulat Taymaz, Bircan</creatorcontrib><creatorcontrib>Taş, Recep</creatorcontrib><creatorcontrib>Kamış, Handan</creatorcontrib><creatorcontrib>Can, Muzaffer</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Haspulat Taymaz, Bircan</au><au>Taş, Recep</au><au>Kamış, Handan</au><au>Can, Muzaffer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photocatalytic activity of polyaniline and neutral polyaniline for degradation of methylene blue and malachite green dyes under UV Light</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>78</volume><issue>5</issue><spage>2849</spage><epage>2865</epage><pages>2849-2865</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>A polyaniline (PANI) and neutral Polyaniline (NPANI) have been synthesized in acetonitrile–water mixture via the chemical oxidative polymerization of aniline. Scanning electron microscopy, FTIR spectra, UV–vis spectroscopy measurements were used to characterize the resulting PANI and NPANI. The photocatalytic activities of PANI and NPANI were investigated by the degradation of methylene blue (MB) and malachite green (MG) dyes in aqueous medium under UV light irradiation. MB and MG dyes completely degraded under UV light irradiation in the presence of NPANI after 60 and 75 min, respectively. The effect of dye type, irradiation time, dye concentration and photocatalyst amount on photocatalytic performance of PANI and NPANI have been examined under UV light irradiation. Three kinetic models have proposed for photocatalytic degradation of dyes by using PANI and NPANI under UV light illumination. This work explores the easy way to synthesize efficient PANI and NPANI polymers to degrade organic compound under both UV and visible light irradiations.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-021-03674-1</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0002-5170-322X</orcidid></addata></record> |
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| subjects | Acetonitrile Aniline Aqueous solutions Catalytic activity Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Dyes Fourier transforms Light Light irradiation Malachite green Methylene blue Morphology Organic Chemistry Organic compounds Original Paper Oxidation Photocatalysis Photodegradation Physical Chemistry Pollutants Polyanilines Polymer Sciences Polymerization Polymers Scanning electron microscopy Soft and Granular Matter Ultraviolet radiation |
| title | Photocatalytic activity of polyaniline and neutral polyaniline for degradation of methylene blue and malachite green dyes under UV Light |
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