Poly(ionic liquid)s-based polyurethane blends: effect of polyols structure and ILs counter cations in CO2 sorption performance of PILs physical blends
Carbon dioxide (CO 2 ) capture from natural gas, and further utilization is an essential issue for greenhouse gas reduction. Poly(ionic liquid)s (PILs) assemble ILs unique properties, with those of polymers being versatile materials for CO 2 capture from flue gas (CO 2 /N 2 ) and natural gas (CO 2 /...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2022-08, Vol.79 (8), p.6123-6139 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | da Luz, Murilo Dias, Guilherme Zimmer, Henrique Bernard, Franciele L. do Nascimento, Jailton F. Einloft, Sandra |
| description | Carbon dioxide (CO
2
) capture from natural gas, and further utilization is an essential issue for greenhouse gas reduction. Poly(ionic liquid)s (PILs) assemble ILs unique properties, with those of polymers being versatile materials for CO
2
capture from flue gas (CO
2
/N
2
) and natural gas (CO
2
/CH
4
). PILs based on polyurethanes obtained with different polyols and ILs cations were blended in different proportions aiming to improve PILs CO
2
sorption capacity. Two different polyols structures (PC and PG) and ILs counter cations (imidazolium and phosphonium) were tested to evaluate how they influence PILs blends CO
2
sorption performance. PILs and PILs blends were characterized by SEC, FTIR, DSC, TGA, DMTA, AFM, and CO
2
sorption that were carried out using the pressure-decay technique. PILs blends presented good thermal stability and mechanical properties. PILs blend polyurethane backbones compositions can be tuned aiming to increase CO
2
sorption capacity. As far as we know, all obtained PILs blends presented higher CO
2
sorption capacity results compared with other Poly(ionic liquid)s reported in the literature. The best CO
2
sorption result was obtained for PIL blend with imidazolium (PLIPC95-PG5-BMIM = 116.9 mgCO
2
/g at 303.15 K and 10 bar). |
| doi_str_mv | 10.1007/s00289-021-03799-3 |
| format | Article |
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2
) capture from natural gas, and further utilization is an essential issue for greenhouse gas reduction. Poly(ionic liquid)s (PILs) assemble ILs unique properties, with those of polymers being versatile materials for CO
2
capture from flue gas (CO
2
/N
2
) and natural gas (CO
2
/CH
4
). PILs based on polyurethanes obtained with different polyols and ILs cations were blended in different proportions aiming to improve PILs CO
2
sorption capacity. Two different polyols structures (PC and PG) and ILs counter cations (imidazolium and phosphonium) were tested to evaluate how they influence PILs blends CO
2
sorption performance. PILs and PILs blends were characterized by SEC, FTIR, DSC, TGA, DMTA, AFM, and CO
2
sorption that were carried out using the pressure-decay technique. PILs blends presented good thermal stability and mechanical properties. PILs blend polyurethane backbones compositions can be tuned aiming to increase CO
2
sorption capacity. As far as we know, all obtained PILs blends presented higher CO
2
sorption capacity results compared with other Poly(ionic liquid)s reported in the literature. The best CO
2
sorption result was obtained for PIL blend with imidazolium (PLIPC95-PG5-BMIM = 116.9 mgCO
2
/g at 303.15 K and 10 bar).</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-021-03799-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Carbon dioxide ; Carbon sequestration ; Cations ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Energy consumption ; Flue gas ; Fourier transforms ; Gas absorption ; Gases ; Greenhouse gases ; Ionic liquids ; Mechanical properties ; Membranes ; Natural gas ; NMR ; Nuclear magnetic resonance ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer blends ; Polymer Sciences ; Polyols ; Polyurethane ; Polyurethane resins ; Soft and Granular Matter ; Sorption ; Thermal stability ; Viscosity</subject><ispartof>Polymer bulletin (Berlin, Germany), 2022-08, Vol.79 (8), p.6123-6139</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c293t-d5336a9845b0e81c7643fc4cb636e96e3cff297201a2992eeb5c6ca81486b793</citedby><cites>FETCH-LOGICAL-c293t-d5336a9845b0e81c7643fc4cb636e96e3cff297201a2992eeb5c6ca81486b793</cites><orcidid>0000-0003-1364-0325</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-021-03799-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917875221?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>315,782,786,21395,27931,27932,33751,41495,42564,43812,51326,64392,64396,72476</link.rule.ids></links><search><creatorcontrib>da Luz, Murilo</creatorcontrib><creatorcontrib>Dias, Guilherme</creatorcontrib><creatorcontrib>Zimmer, Henrique</creatorcontrib><creatorcontrib>Bernard, Franciele L.</creatorcontrib><creatorcontrib>do Nascimento, Jailton F.</creatorcontrib><creatorcontrib>Einloft, Sandra</creatorcontrib><title>Poly(ionic liquid)s-based polyurethane blends: effect of polyols structure and ILs counter cations in CO2 sorption performance of PILs physical blends</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>Carbon dioxide (CO
2
) capture from natural gas, and further utilization is an essential issue for greenhouse gas reduction. Poly(ionic liquid)s (PILs) assemble ILs unique properties, with those of polymers being versatile materials for CO
2
capture from flue gas (CO
2
/N
2
) and natural gas (CO
2
/CH
4
). PILs based on polyurethanes obtained with different polyols and ILs cations were blended in different proportions aiming to improve PILs CO
2
sorption capacity. Two different polyols structures (PC and PG) and ILs counter cations (imidazolium and phosphonium) were tested to evaluate how they influence PILs blends CO
2
sorption performance. PILs and PILs blends were characterized by SEC, FTIR, DSC, TGA, DMTA, AFM, and CO
2
sorption that were carried out using the pressure-decay technique. PILs blends presented good thermal stability and mechanical properties. PILs blend polyurethane backbones compositions can be tuned aiming to increase CO
2
sorption capacity. As far as we know, all obtained PILs blends presented higher CO
2
sorption capacity results compared with other Poly(ionic liquid)s reported in the literature. The best CO
2
sorption result was obtained for PIL blend with imidazolium (PLIPC95-PG5-BMIM = 116.9 mgCO
2
/g at 303.15 K and 10 bar).</description><subject>Carbon dioxide</subject><subject>Carbon sequestration</subject><subject>Cations</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Energy consumption</subject><subject>Flue gas</subject><subject>Fourier transforms</subject><subject>Gas absorption</subject><subject>Gases</subject><subject>Greenhouse gases</subject><subject>Ionic liquids</subject><subject>Mechanical properties</subject><subject>Membranes</subject><subject>Natural gas</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymer blends</subject><subject>Polymer Sciences</subject><subject>Polyols</subject><subject>Polyurethane</subject><subject>Polyurethane resins</subject><subject>Soft and Granular Matter</subject><subject>Sorption</subject><subject>Thermal stability</subject><subject>Viscosity</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kM1u2zAQhImiBeq6eYGcCPTSHpjyR6bE3gKjTQIYiA--ExS1bBTIpMyVDn6RPG_pH6C3nBa7O_MNMITcCn4nOK9_IueyMYxLwbiqjWHqA1mISmkmq8p8JAsuas54o8xn8gXxlZdda7Egb9s0HL_3KfaeDv1h7rsfyFqH0NGxfOYM04uLQNsBYoe_KIQAfqIpnN9pQIpTnv1UhNTFjj5tkPo0xwky9W4qYKR9pOtnSTHl8XSgI-SQ8t5FDyfQ9uQZX47Yezdcg76ST8ENCDfXuSS7P79360e2eX54Wt9vmJdGTaxbKaWdaapVy6ERvtaVCr7yrVYajAblQ5Cmllw4aYwEaFdee9eIqtFtbdSSfLtgx5wOM-BkX9OcY0m00oi6qVdSiqKSF5XPCTFDsGPu9y4freD2VL-91G9L_fZcv1XFpC4mLOL4F_J_9Duuf70AilI</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>da Luz, Murilo</creator><creator>Dias, Guilherme</creator><creator>Zimmer, Henrique</creator><creator>Bernard, Franciele L.</creator><creator>do Nascimento, Jailton F.</creator><creator>Einloft, Sandra</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0003-1364-0325</orcidid></search><sort><creationdate>20220801</creationdate><title>Poly(ionic liquid)s-based polyurethane blends: effect of polyols structure and ILs counter cations in CO2 sorption performance of PILs physical blends</title><author>da Luz, Murilo ; Dias, Guilherme ; Zimmer, Henrique ; Bernard, Franciele L. ; do Nascimento, Jailton F. ; Einloft, Sandra</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c293t-d5336a9845b0e81c7643fc4cb636e96e3cff297201a2992eeb5c6ca81486b793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Carbon dioxide</topic><topic>Carbon sequestration</topic><topic>Cations</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Energy consumption</topic><topic>Flue gas</topic><topic>Fourier transforms</topic><topic>Gas absorption</topic><topic>Gases</topic><topic>Greenhouse gases</topic><topic>Ionic liquids</topic><topic>Mechanical properties</topic><topic>Membranes</topic><topic>Natural gas</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymer blends</topic><topic>Polymer Sciences</topic><topic>Polyols</topic><topic>Polyurethane</topic><topic>Polyurethane resins</topic><topic>Soft and Granular Matter</topic><topic>Sorption</topic><topic>Thermal stability</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>da Luz, Murilo</creatorcontrib><creatorcontrib>Dias, Guilherme</creatorcontrib><creatorcontrib>Zimmer, Henrique</creatorcontrib><creatorcontrib>Bernard, Franciele L.</creatorcontrib><creatorcontrib>do Nascimento, Jailton F.</creatorcontrib><creatorcontrib>Einloft, Sandra</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Luz, Murilo</au><au>Dias, Guilherme</au><au>Zimmer, Henrique</au><au>Bernard, Franciele L.</au><au>do Nascimento, Jailton F.</au><au>Einloft, Sandra</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Poly(ionic liquid)s-based polyurethane blends: effect of polyols structure and ILs counter cations in CO2 sorption performance of PILs physical blends</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>79</volume><issue>8</issue><spage>6123</spage><epage>6139</epage><pages>6123-6139</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>Carbon dioxide (CO
2
) capture from natural gas, and further utilization is an essential issue for greenhouse gas reduction. Poly(ionic liquid)s (PILs) assemble ILs unique properties, with those of polymers being versatile materials for CO
2
capture from flue gas (CO
2
/N
2
) and natural gas (CO
2
/CH
4
). PILs based on polyurethanes obtained with different polyols and ILs cations were blended in different proportions aiming to improve PILs CO
2
sorption capacity. Two different polyols structures (PC and PG) and ILs counter cations (imidazolium and phosphonium) were tested to evaluate how they influence PILs blends CO
2
sorption performance. PILs and PILs blends were characterized by SEC, FTIR, DSC, TGA, DMTA, AFM, and CO
2
sorption that were carried out using the pressure-decay technique. PILs blends presented good thermal stability and mechanical properties. PILs blend polyurethane backbones compositions can be tuned aiming to increase CO
2
sorption capacity. As far as we know, all obtained PILs blends presented higher CO
2
sorption capacity results compared with other Poly(ionic liquid)s reported in the literature. The best CO
2
sorption result was obtained for PIL blend with imidazolium (PLIPC95-PG5-BMIM = 116.9 mgCO
2
/g at 303.15 K and 10 bar).</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-021-03799-3</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0003-1364-0325</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2022-08, Vol.79 (8), p.6123-6139 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_2917875221 |
| source | SpringerNature Journals; ProQuest Central UK/Ireland; ProQuest Central |
| subjects | Carbon dioxide Carbon sequestration Cations Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Energy consumption Flue gas Fourier transforms Gas absorption Gases Greenhouse gases Ionic liquids Mechanical properties Membranes Natural gas NMR Nuclear magnetic resonance Organic Chemistry Original Paper Physical Chemistry Polymer blends Polymer Sciences Polyols Polyurethane Polyurethane resins Soft and Granular Matter Sorption Thermal stability Viscosity |
| title | Poly(ionic liquid)s-based polyurethane blends: effect of polyols structure and ILs counter cations in CO2 sorption performance of PILs physical blends |
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