Rapid and efficient uptake of aqueous lead pollutant using starch-based superabsorbent hydrogel
The need for a viable and sustainable environment has triggered the increased preference for eco-friendly agro-based biosorbents to synthetic ones. In this study, a superabsorbent hydrogel ( ‘c-hydrogel’ ) synthesized from a renewable agro-based precursor via polyacrylonitrile (PAN) graft copolymeri...
Gespeichert in:
| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2022-08, Vol.79 (8), p.6373-6388 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 6388 |
|---|---|
| container_issue | 8 |
| container_start_page | 6373 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 79 |
| creator | Aniagor, Chukwunonso O. Afifi, M. A. Hashem, A. |
| description | The need for a viable and sustainable environment has triggered the increased preference for eco-friendly agro-based biosorbents to synthetic ones. In this study, a superabsorbent hydrogel (
‘c-hydrogel’
) synthesized from a renewable agro-based precursor via polyacrylonitrile (PAN) graft copolymerization and subsequent hydrolysis was utilized for aqueous lead [Pb(II)] uptake. The chemical structure (using Fourier transform infrared spectroscopy, FTIR equipment), surface morphology (using scanning electron microscopy, SEM equipment) and the physicochemical properties of the synthesized
‘c-hydrogel’
were investigated. Similarly, the effect of some process variables on the biosorbents’ adsorption capacity, as well as the process equilibrium and kinetics modelling, was also undertaken in the study. The isotherm data were best fitted to the Langmuir and Temkin model, with a maximum adsorption capacity of 264.37 mg/g and fast kinetics of 40 min at pH 5.0. Conversely, the kinetic data were well fitted to the pseudo-first-order model. The ‘c-hydrogel’ showed a high water absorbency of 550 g water/g ‘c-hydrogel’ and demonstrated effectiveness, as a renewable and eco-friendly biosorbent for the aqueous lead ion [Pb (II)] removal. |
| doi_str_mv | 10.1007/s00289-021-03817-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2917875211</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2917875211</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-619f40ae2c8e0aea4207f9343619edb4cc72f1fffc29772124a4bf20cc67f2463</originalsourceid><addsrcrecordid>eNp9kE9LxDAQxYMouK5-AU8Bz9GZNDbNURb_wYIgeg5pmux2rU1N2sN-e7NW8ObpMfDem5kfIZcI1wggbxIArxQDjgyKCiUTR2SBoigZF0IdkwWgBAZVoU7JWUo7yHNZ4oLoVzO0DTV9Q533rW1dP9JpGM2Ho8FT8zW5MCXaOdPQIXTdNJqDIbX9hqbRRLtltUmuoWkaXDR1CrE-VGz3TQwb152TE2-65C5-dUneH-7fVk9s_fL4vLpbM1ugGlmJygswjtvKZTGCg_SqyA-gck0trJXco_feciUlRy6MqD0Ha0vpuSiLJbmae4cY8s1p1LswxT6v1FyhrOQtR8wuPrtsDClF5_UQ208T9xpBH0DqGaTOIPUPSC1yqJhDKZv7jYt_1f-kvgHuVHdY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2917875211</pqid></control><display><type>article</type><title>Rapid and efficient uptake of aqueous lead pollutant using starch-based superabsorbent hydrogel</title><source>ProQuest Central UK/Ireland</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Aniagor, Chukwunonso O. ; Afifi, M. A. ; Hashem, A.</creator><creatorcontrib>Aniagor, Chukwunonso O. ; Afifi, M. A. ; Hashem, A.</creatorcontrib><description>The need for a viable and sustainable environment has triggered the increased preference for eco-friendly agro-based biosorbents to synthetic ones. In this study, a superabsorbent hydrogel (
‘c-hydrogel’
) synthesized from a renewable agro-based precursor via polyacrylonitrile (PAN) graft copolymerization and subsequent hydrolysis was utilized for aqueous lead [Pb(II)] uptake. The chemical structure (using Fourier transform infrared spectroscopy, FTIR equipment), surface morphology (using scanning electron microscopy, SEM equipment) and the physicochemical properties of the synthesized
‘c-hydrogel’
were investigated. Similarly, the effect of some process variables on the biosorbents’ adsorption capacity, as well as the process equilibrium and kinetics modelling, was also undertaken in the study. The isotherm data were best fitted to the Langmuir and Temkin model, with a maximum adsorption capacity of 264.37 mg/g and fast kinetics of 40 min at pH 5.0. Conversely, the kinetic data were well fitted to the pseudo-first-order model. The ‘c-hydrogel’ showed a high water absorbency of 550 g water/g ‘c-hydrogel’ and demonstrated effectiveness, as a renewable and eco-friendly biosorbent for the aqueous lead ion [Pb (II)] removal.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-021-03817-4</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Adsorbents ; Adsorption ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Copolymerization ; Equilibrium ; Fourier transforms ; Graft copolymers ; Hydrogels ; Kinetics ; Lead ; Lead content ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polyacrylonitrile ; Polymer Sciences ; Polymers ; Process variables ; Soft and Granular Matter ; Synthesis ; Water absorption</subject><ispartof>Polymer bulletin (Berlin, Germany), 2022-08, Vol.79 (8), p.6373-6388</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-619f40ae2c8e0aea4207f9343619edb4cc72f1fffc29772124a4bf20cc67f2463</citedby><cites>FETCH-LOGICAL-c319t-619f40ae2c8e0aea4207f9343619edb4cc72f1fffc29772124a4bf20cc67f2463</cites><orcidid>0000-0001-7981-4872 ; 0000-0001-6488-3998</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-021-03817-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917875211?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,41488,42557,43805,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Aniagor, Chukwunonso O.</creatorcontrib><creatorcontrib>Afifi, M. A.</creatorcontrib><creatorcontrib>Hashem, A.</creatorcontrib><title>Rapid and efficient uptake of aqueous lead pollutant using starch-based superabsorbent hydrogel</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>The need for a viable and sustainable environment has triggered the increased preference for eco-friendly agro-based biosorbents to synthetic ones. In this study, a superabsorbent hydrogel (
‘c-hydrogel’
) synthesized from a renewable agro-based precursor via polyacrylonitrile (PAN) graft copolymerization and subsequent hydrolysis was utilized for aqueous lead [Pb(II)] uptake. The chemical structure (using Fourier transform infrared spectroscopy, FTIR equipment), surface morphology (using scanning electron microscopy, SEM equipment) and the physicochemical properties of the synthesized
‘c-hydrogel’
were investigated. Similarly, the effect of some process variables on the biosorbents’ adsorption capacity, as well as the process equilibrium and kinetics modelling, was also undertaken in the study. The isotherm data were best fitted to the Langmuir and Temkin model, with a maximum adsorption capacity of 264.37 mg/g and fast kinetics of 40 min at pH 5.0. Conversely, the kinetic data were well fitted to the pseudo-first-order model. The ‘c-hydrogel’ showed a high water absorbency of 550 g water/g ‘c-hydrogel’ and demonstrated effectiveness, as a renewable and eco-friendly biosorbent for the aqueous lead ion [Pb (II)] removal.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Copolymerization</subject><subject>Equilibrium</subject><subject>Fourier transforms</subject><subject>Graft copolymers</subject><subject>Hydrogels</subject><subject>Kinetics</subject><subject>Lead</subject><subject>Lead content</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polyacrylonitrile</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Process variables</subject><subject>Soft and Granular Matter</subject><subject>Synthesis</subject><subject>Water absorption</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE9LxDAQxYMouK5-AU8Bz9GZNDbNURb_wYIgeg5pmux2rU1N2sN-e7NW8ObpMfDem5kfIZcI1wggbxIArxQDjgyKCiUTR2SBoigZF0IdkwWgBAZVoU7JWUo7yHNZ4oLoVzO0DTV9Q533rW1dP9JpGM2Ho8FT8zW5MCXaOdPQIXTdNJqDIbX9hqbRRLtltUmuoWkaXDR1CrE-VGz3TQwb152TE2-65C5-dUneH-7fVk9s_fL4vLpbM1ugGlmJygswjtvKZTGCg_SqyA-gck0trJXco_feciUlRy6MqD0Ha0vpuSiLJbmae4cY8s1p1LswxT6v1FyhrOQtR8wuPrtsDClF5_UQ208T9xpBH0DqGaTOIPUPSC1yqJhDKZv7jYt_1f-kvgHuVHdY</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Aniagor, Chukwunonso O.</creator><creator>Afifi, M. A.</creator><creator>Hashem, A.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0001-7981-4872</orcidid><orcidid>https://orcid.org/0000-0001-6488-3998</orcidid></search><sort><creationdate>20220801</creationdate><title>Rapid and efficient uptake of aqueous lead pollutant using starch-based superabsorbent hydrogel</title><author>Aniagor, Chukwunonso O. ; Afifi, M. A. ; Hashem, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-619f40ae2c8e0aea4207f9343619edb4cc72f1fffc29772124a4bf20cc67f2463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Copolymerization</topic><topic>Equilibrium</topic><topic>Fourier transforms</topic><topic>Graft copolymers</topic><topic>Hydrogels</topic><topic>Kinetics</topic><topic>Lead</topic><topic>Lead content</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polyacrylonitrile</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Process variables</topic><topic>Soft and Granular Matter</topic><topic>Synthesis</topic><topic>Water absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aniagor, Chukwunonso O.</creatorcontrib><creatorcontrib>Afifi, M. A.</creatorcontrib><creatorcontrib>Hashem, A.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aniagor, Chukwunonso O.</au><au>Afifi, M. A.</au><au>Hashem, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rapid and efficient uptake of aqueous lead pollutant using starch-based superabsorbent hydrogel</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>79</volume><issue>8</issue><spage>6373</spage><epage>6388</epage><pages>6373-6388</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>The need for a viable and sustainable environment has triggered the increased preference for eco-friendly agro-based biosorbents to synthetic ones. In this study, a superabsorbent hydrogel (
‘c-hydrogel’
) synthesized from a renewable agro-based precursor via polyacrylonitrile (PAN) graft copolymerization and subsequent hydrolysis was utilized for aqueous lead [Pb(II)] uptake. The chemical structure (using Fourier transform infrared spectroscopy, FTIR equipment), surface morphology (using scanning electron microscopy, SEM equipment) and the physicochemical properties of the synthesized
‘c-hydrogel’
were investigated. Similarly, the effect of some process variables on the biosorbents’ adsorption capacity, as well as the process equilibrium and kinetics modelling, was also undertaken in the study. The isotherm data were best fitted to the Langmuir and Temkin model, with a maximum adsorption capacity of 264.37 mg/g and fast kinetics of 40 min at pH 5.0. Conversely, the kinetic data were well fitted to the pseudo-first-order model. The ‘c-hydrogel’ showed a high water absorbency of 550 g water/g ‘c-hydrogel’ and demonstrated effectiveness, as a renewable and eco-friendly biosorbent for the aqueous lead ion [Pb (II)] removal.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-021-03817-4</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0001-7981-4872</orcidid><orcidid>https://orcid.org/0000-0001-6488-3998</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2022-08, Vol.79 (8), p.6373-6388 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_2917875211 |
| source | ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Adsorbents Adsorption Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Copolymerization Equilibrium Fourier transforms Graft copolymers Hydrogels Kinetics Lead Lead content Organic Chemistry Original Paper Physical Chemistry Polyacrylonitrile Polymer Sciences Polymers Process variables Soft and Granular Matter Synthesis Water absorption |
| title | Rapid and efficient uptake of aqueous lead pollutant using starch-based superabsorbent hydrogel |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T12%3A08%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rapid%20and%20efficient%20uptake%20of%20aqueous%20lead%20pollutant%20using%20starch-based%20superabsorbent%20hydrogel&rft.jtitle=Polymer%20bulletin%20(Berlin,%20Germany)&rft.au=Aniagor,%20Chukwunonso%20O.&rft.date=2022-08-01&rft.volume=79&rft.issue=8&rft.spage=6373&rft.epage=6388&rft.pages=6373-6388&rft.issn=0170-0839&rft.eissn=1436-2449&rft_id=info:doi/10.1007/s00289-021-03817-4&rft_dat=%3Cproquest_cross%3E2917875211%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2917875211&rft_id=info:pmid/&rfr_iscdi=true |