Random copolymerization of ε-caprolactone and l-lactide with molybdenum complexes

Dioxomolybdenum complexes were examined as catalysts for the copolymerization of ε-caprolactone (ε-CL) and l -lactide ( l -LA). The bis-[(5-OMe)salicylaldehydato]dioxomolybdenum complex completed the copolymerization after 20 h at 110 °C with 0.05 mol% of the catalyst to produce a copolymer in high...

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Veröffentlicht in:	Polymer bulletin (Berlin, Germany) Germany), 2014-04, Vol.71 (4), p.989-999
Hauptverfasser:	Maruta, Yasumi, Abiko, Atsushi
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Applied sciences Block copolymers Catalysts Characterization and Evaluation of Materials Chemical industry Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Copolymerization Copolymers Esterification Exact sciences and technology Mathematical analysis Molybdenum Molybdenum oxides NMR spectroscopy Organic Chemistry Organic polymers Original Paper Physical Chemistry Physicochemistry of polymers Polymer Sciences Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Soft and Granular Matter Spectrum analysis
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