Effect of emulsifier on poly(urea–formaldehyde) microencapsulation of tetrachloroethylene

Microcapsules containing tetrachloroethylene as an internal phase were prepared by in situ polymerization of urea–formaldehyde (UF) without prepolymerization. The effects of different emulsifiers on the process of microencapsulation and morphology of microcapsules were investigated. The results show...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2011-06, Vol.67 (1), p.15-27
Hauptverfasser: Fan, Chuanjie, Zhou, Xiaodong
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description Microcapsules containing tetrachloroethylene as an internal phase were prepared by in situ polymerization of urea–formaldehyde (UF) without prepolymerization. The effects of different emulsifiers on the process of microencapsulation and morphology of microcapsules were investigated. The results show that the emulsifier gum arabic (GA) can effectively slow down the deposition rate of resin onto the oil/water interface, which can lead to smooth and compact surface of microcapsules. The surface activity of GA was also enhanced by complex formation of gum arabic and sodium dodecyl benzene sulfonate. The microcapsules represent good thermal and barrier property as a result of the formation of capsule wall with compact microstructure.
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subjects Applied sciences
Aqueous solutions
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Complex formation
Emulsifiers
Exact sciences and technology
Formaldehyde
Microencapsulation
Morphology
Nanoparticles
Organic Chemistry
Organic polymers
Original Paper
Physical Chemistry
Physicochemistry of polymers
Polymer Sciences
Polymerization
Polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
Resins
Sodium dodecylbenzenesulfonate
Soft and Granular Matter
Surfactants
Tetrachloroethylene
Ureas
title Effect of emulsifier on poly(urea–formaldehyde) microencapsulation of tetrachloroethylene
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