Lead removal from battery wastewater using synthesized poly(ethyleneglycol dimethacrylate-methacrylic acid) gel bead and poly(methacrylic acid) hydrogel
This study presents the synthesis and characterization of two new polymers with the aim of Pb 2+ ion removal from the wastewater of a battery factory. Poly(ethyleneglycol dimethacrylate-methacrylic acid) (poly(EGDMA-MAA)) gel bead and polymetacrylic acid (polyMAA) hydrogel were prepared and characte...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2017-07, Vol.74 (7), p.2605-2624 |
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| creator | Vergili, Ilda Gönder, Z. Beril Kaya, Yasemin Gürdağ, Gülten Çavuş, Selva |
| description | This study presents the synthesis and characterization of two new polymers with the aim of Pb
2+
ion removal from the wastewater of a battery factory. Poly(ethyleneglycol dimethacrylate-methacrylic acid) (poly(EGDMA-MAA)) gel bead and polymetacrylic acid (polyMAA) hydrogel were prepared and characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), environmental scanning electron microscopy (ESEM), swelling capacity analysis and zeta potential measurements. Both polymers showed greater negative zeta potential values in the range of pH 3–8. Poly(EGDMA-MAA) had a relatively lower swelling capacity of 0.9
g
water
/
g
polymer
than polyMAA because of the crosslinking degree. The FTIR spectrum of the virgin poly(EGDMA-MAA) showed that the polymer has carboxylic groups to sorb the Pb
2+
ions. The FTIR spectrum of poly(EGDMA-MAA) after sorption showed that interactions between the Pb
2+
ions and carboxyl groups caused a decrease in the intensity of the C=O peak. The sorption experiments carried out under different conditions yielded optimal conditions of contact time and polymer amount. The Pb
2+
adsorption capacities were found to be 1.995 and 2.047 mg g
−1
for poly(EGDMA-MAA) and polyMAA, respectively. Moreover, the sorption mechanism was studied using kinetic and thermodynamic models. The higher
R
2
(0.9997 and 0.9999), lower
ε
% (1.3 and 0.8) and closer values of
q
exp
and
q
cal
show that the data fit well with the type (I) pseudo-second-order model. The higher positive Δ
S
° value indicated that greater structural changes occurred in polyMAA than in poly(EGDMA-MAA). |
| doi_str_mv | 10.1007/s00289-016-1855-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2917873299</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2917873299</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-c275da724ea13c82749130d6b3574ae3f3c50014d0e1ce549a54c030a63e45813</originalsourceid><addsrcrecordid>eNp1kctKAzEUhoMoWKsP4C7gRhfRXOeylOINCm50HdLMmemUdFKTqTI-iY9ryhRdiKtz4fv_w-FH6JzRa0ZpfhMp5UVJKMsIK5Qi8gBNmBQZ4VKWh2hCWU4JLUR5jE5iXNE0ZxmboK85mAoHWPt343Ad_BovTN9DGPCHiT18mNTjbWy7Bseh65cQ20-o8Ma74RL65eCgg8YN1jtcteu0MTYMLqnIz9BabGxbXeEGHF7s7plu7_CXWQ5V8Ak8RUe1cRHO9nWKXu_vXmaPZP788DS7nRMrlOiJ5bmqTM4lGCZswXNZMkGrbCFULg2IWliVnpUVBWZBydIoaamgJhMgVcHEFF2Mvpvg37YQe73y29Clk5qXLC9ywcsyUWykbPAxBqj1JrRrEwbNqN4FoMcAdApA7wLQMmn4qImJ7RoIv87_i74BxxCLrw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2917873299</pqid></control><display><type>article</type><title>Lead removal from battery wastewater using synthesized poly(ethyleneglycol dimethacrylate-methacrylic acid) gel bead and poly(methacrylic acid) hydrogel</title><source>ProQuest Central UK/Ireland</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Vergili, Ilda ; Gönder, Z. Beril ; Kaya, Yasemin ; Gürdağ, Gülten ; Çavuş, Selva</creator><creatorcontrib>Vergili, Ilda ; Gönder, Z. Beril ; Kaya, Yasemin ; Gürdağ, Gülten ; Çavuş, Selva</creatorcontrib><description>This study presents the synthesis and characterization of two new polymers with the aim of Pb
2+
ion removal from the wastewater of a battery factory. Poly(ethyleneglycol dimethacrylate-methacrylic acid) (poly(EGDMA-MAA)) gel bead and polymetacrylic acid (polyMAA) hydrogel were prepared and characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), environmental scanning electron microscopy (ESEM), swelling capacity analysis and zeta potential measurements. Both polymers showed greater negative zeta potential values in the range of pH 3–8. Poly(EGDMA-MAA) had a relatively lower swelling capacity of 0.9
g
water
/
g
polymer
than polyMAA because of the crosslinking degree. The FTIR spectrum of the virgin poly(EGDMA-MAA) showed that the polymer has carboxylic groups to sorb the Pb
2+
ions. The FTIR spectrum of poly(EGDMA-MAA) after sorption showed that interactions between the Pb
2+
ions and carboxyl groups caused a decrease in the intensity of the C=O peak. The sorption experiments carried out under different conditions yielded optimal conditions of contact time and polymer amount. The Pb
2+
adsorption capacities were found to be 1.995 and 2.047 mg g
−1
for poly(EGDMA-MAA) and polyMAA, respectively. Moreover, the sorption mechanism was studied using kinetic and thermodynamic models. The higher
R
2
(0.9997 and 0.9999), lower
ε
% (1.3 and 0.8) and closer values of
q
exp
and
q
cal
show that the data fit well with the type (I) pseudo-second-order model. The higher positive Δ
S
° value indicated that greater structural changes occurred in polyMAA than in poly(EGDMA-MAA).</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-016-1855-4</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acids ; Characterization and Evaluation of Materials ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Crosslinking ; Equilibrium ; Experiments ; Fourier transforms ; Free radicals ; Heavy metals ; Hydrogels ; Infrared analysis ; Infrared spectroscopy ; Lead ; Manufacturing ; Nitrogen ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer Sciences ; Polymerization ; Polymers ; Polymethacrylic acid ; Soft and Granular Matter ; Sorption ; Swelling ; Thermodynamic models ; Thermogravimetric analysis ; Wastewater treatment ; Zeta potential</subject><ispartof>Polymer bulletin (Berlin, Germany), 2017-07, Vol.74 (7), p.2605-2624</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Springer-Verlag Berlin Heidelberg 2016.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-c275da724ea13c82749130d6b3574ae3f3c50014d0e1ce549a54c030a63e45813</citedby><cites>FETCH-LOGICAL-c353t-c275da724ea13c82749130d6b3574ae3f3c50014d0e1ce549a54c030a63e45813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-016-1855-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917873299?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21387,27923,27924,33743,41487,42556,43804,51318,64384,64388,72340</link.rule.ids></links><search><creatorcontrib>Vergili, Ilda</creatorcontrib><creatorcontrib>Gönder, Z. Beril</creatorcontrib><creatorcontrib>Kaya, Yasemin</creatorcontrib><creatorcontrib>Gürdağ, Gülten</creatorcontrib><creatorcontrib>Çavuş, Selva</creatorcontrib><title>Lead removal from battery wastewater using synthesized poly(ethyleneglycol dimethacrylate-methacrylic acid) gel bead and poly(methacrylic acid) hydrogel</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>This study presents the synthesis and characterization of two new polymers with the aim of Pb
2+
ion removal from the wastewater of a battery factory. Poly(ethyleneglycol dimethacrylate-methacrylic acid) (poly(EGDMA-MAA)) gel bead and polymetacrylic acid (polyMAA) hydrogel were prepared and characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), environmental scanning electron microscopy (ESEM), swelling capacity analysis and zeta potential measurements. Both polymers showed greater negative zeta potential values in the range of pH 3–8. Poly(EGDMA-MAA) had a relatively lower swelling capacity of 0.9
g
water
/
g
polymer
than polyMAA because of the crosslinking degree. The FTIR spectrum of the virgin poly(EGDMA-MAA) showed that the polymer has carboxylic groups to sorb the Pb
2+
ions. The FTIR spectrum of poly(EGDMA-MAA) after sorption showed that interactions between the Pb
2+
ions and carboxyl groups caused a decrease in the intensity of the C=O peak. The sorption experiments carried out under different conditions yielded optimal conditions of contact time and polymer amount. The Pb
2+
adsorption capacities were found to be 1.995 and 2.047 mg g
−1
for poly(EGDMA-MAA) and polyMAA, respectively. Moreover, the sorption mechanism was studied using kinetic and thermodynamic models. The higher
R
2
(0.9997 and 0.9999), lower
ε
% (1.3 and 0.8) and closer values of
q
exp
and
q
cal
show that the data fit well with the type (I) pseudo-second-order model. The higher positive Δ
S
° value indicated that greater structural changes occurred in polyMAA than in poly(EGDMA-MAA).</description><subject>Acids</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Crosslinking</subject><subject>Equilibrium</subject><subject>Experiments</subject><subject>Fourier transforms</subject><subject>Free radicals</subject><subject>Heavy metals</subject><subject>Hydrogels</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Lead</subject><subject>Manufacturing</subject><subject>Nitrogen</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polymethacrylic acid</subject><subject>Soft and Granular Matter</subject><subject>Sorption</subject><subject>Swelling</subject><subject>Thermodynamic models</subject><subject>Thermogravimetric analysis</subject><subject>Wastewater treatment</subject><subject>Zeta potential</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kctKAzEUhoMoWKsP4C7gRhfRXOeylOINCm50HdLMmemUdFKTqTI-iY9ryhRdiKtz4fv_w-FH6JzRa0ZpfhMp5UVJKMsIK5Qi8gBNmBQZ4VKWh2hCWU4JLUR5jE5iXNE0ZxmboK85mAoHWPt343Ad_BovTN9DGPCHiT18mNTjbWy7Bseh65cQ20-o8Ma74RL65eCgg8YN1jtcteu0MTYMLqnIz9BabGxbXeEGHF7s7plu7_CXWQ5V8Ak8RUe1cRHO9nWKXu_vXmaPZP788DS7nRMrlOiJ5bmqTM4lGCZswXNZMkGrbCFULg2IWliVnpUVBWZBydIoaamgJhMgVcHEFF2Mvpvg37YQe73y29Clk5qXLC9ywcsyUWykbPAxBqj1JrRrEwbNqN4FoMcAdApA7wLQMmn4qImJ7RoIv87_i74BxxCLrw</recordid><startdate>20170701</startdate><enddate>20170701</enddate><creator>Vergili, Ilda</creator><creator>Gönder, Z. Beril</creator><creator>Kaya, Yasemin</creator><creator>Gürdağ, Gülten</creator><creator>Çavuş, Selva</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20170701</creationdate><title>Lead removal from battery wastewater using synthesized poly(ethyleneglycol dimethacrylate-methacrylic acid) gel bead and poly(methacrylic acid) hydrogel</title><author>Vergili, Ilda ; Gönder, Z. Beril ; Kaya, Yasemin ; Gürdağ, Gülten ; Çavuş, Selva</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-c275da724ea13c82749130d6b3574ae3f3c50014d0e1ce549a54c030a63e45813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Acids</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Crosslinking</topic><topic>Equilibrium</topic><topic>Experiments</topic><topic>Fourier transforms</topic><topic>Free radicals</topic><topic>Heavy metals</topic><topic>Hydrogels</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Lead</topic><topic>Manufacturing</topic><topic>Nitrogen</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polymethacrylic acid</topic><topic>Soft and Granular Matter</topic><topic>Sorption</topic><topic>Swelling</topic><topic>Thermodynamic models</topic><topic>Thermogravimetric analysis</topic><topic>Wastewater treatment</topic><topic>Zeta potential</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vergili, Ilda</creatorcontrib><creatorcontrib>Gönder, Z. Beril</creatorcontrib><creatorcontrib>Kaya, Yasemin</creatorcontrib><creatorcontrib>Gürdağ, Gülten</creatorcontrib><creatorcontrib>Çavuş, Selva</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vergili, Ilda</au><au>Gönder, Z. Beril</au><au>Kaya, Yasemin</au><au>Gürdağ, Gülten</au><au>Çavuş, Selva</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lead removal from battery wastewater using synthesized poly(ethyleneglycol dimethacrylate-methacrylic acid) gel bead and poly(methacrylic acid) hydrogel</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2017-07-01</date><risdate>2017</risdate><volume>74</volume><issue>7</issue><spage>2605</spage><epage>2624</epage><pages>2605-2624</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>This study presents the synthesis and characterization of two new polymers with the aim of Pb
2+
ion removal from the wastewater of a battery factory. Poly(ethyleneglycol dimethacrylate-methacrylic acid) (poly(EGDMA-MAA)) gel bead and polymetacrylic acid (polyMAA) hydrogel were prepared and characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), environmental scanning electron microscopy (ESEM), swelling capacity analysis and zeta potential measurements. Both polymers showed greater negative zeta potential values in the range of pH 3–8. Poly(EGDMA-MAA) had a relatively lower swelling capacity of 0.9
g
water
/
g
polymer
than polyMAA because of the crosslinking degree. The FTIR spectrum of the virgin poly(EGDMA-MAA) showed that the polymer has carboxylic groups to sorb the Pb
2+
ions. The FTIR spectrum of poly(EGDMA-MAA) after sorption showed that interactions between the Pb
2+
ions and carboxyl groups caused a decrease in the intensity of the C=O peak. The sorption experiments carried out under different conditions yielded optimal conditions of contact time and polymer amount. The Pb
2+
adsorption capacities were found to be 1.995 and 2.047 mg g
−1
for poly(EGDMA-MAA) and polyMAA, respectively. Moreover, the sorption mechanism was studied using kinetic and thermodynamic models. The higher
R
2
(0.9997 and 0.9999), lower
ε
% (1.3 and 0.8) and closer values of
q
exp
and
q
cal
show that the data fit well with the type (I) pseudo-second-order model. The higher positive Δ
S
° value indicated that greater structural changes occurred in polyMAA than in poly(EGDMA-MAA).</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-016-1855-4</doi><tpages>20</tpages></addata></record> |
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| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2017-07, Vol.74 (7), p.2605-2624 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| source | ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Acids Characterization and Evaluation of Materials Chemical synthesis Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Crosslinking Equilibrium Experiments Fourier transforms Free radicals Heavy metals Hydrogels Infrared analysis Infrared spectroscopy Lead Manufacturing Nitrogen Organic Chemistry Original Paper Physical Chemistry Polymer Sciences Polymerization Polymers Polymethacrylic acid Soft and Granular Matter Sorption Swelling Thermodynamic models Thermogravimetric analysis Wastewater treatment Zeta potential |
| title | Lead removal from battery wastewater using synthesized poly(ethyleneglycol dimethacrylate-methacrylic acid) gel bead and poly(methacrylic acid) hydrogel |
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