Thermal, physical, structural, thermomechanical features and single gas permeation comparison of fluorine, phenyl phosphine oxide-based copolyimides with poly(dimethylsiloxane)
In this study, a series of copolyimide have been obtained, using a newly synthesized monomer named bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide ( m -BA6FPPO), 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4′-oxydianiline (ODA) and poly(dimethylsiloxane) (PDMS,...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2017-06, Vol.74 (6), p.2217-2244 |
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| creator | Biçen, Merve Karataş, Sevim Kayaman-Apohan, Nilhan Güngör, Atilla |
| description | In this study, a series of copolyimide have been obtained, using a newly synthesized monomer named bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide (
m
-BA6FPPO), 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4′-oxydianiline (ODA) and poly(dimethylsiloxane) (PDMS, amine terminated,
M
n
= 2500 g/mol). Homogeneous cavity distribution and homogeneous porosity appeared for the copolyimide containing 1.5 wt% of poly(dimethylsiloxane). The tensile strength and modulus of the materials containing 1.5 wt% of poly(dimethylsiloxane) had the highest values among others. The decomposition temperatures increased with increase of PDMS content. In general, hybrid materials were transparent. Storage moduli of 1.5 and 2 wt% of silicone containing materials were greater than those of others. The optimum results for the single gas permeability were achieved at 1 bar for the materials containing 1.5 and 2 wt% poly(dimethylsiloxane). The volume fraction of silicone was determined from thermomechanical analysis at a certain temperature for each sample. The best correlation between volume fraction of silicone and selectivities was obtained for CH
4
/CO
2
, CH
4
/N
2
, CO
2
/O
2
, CO
2
/N
2
and CH
4
/O
2
. Bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide ingredient in the same amounted silicone containing materials decreased the permeabilities of gases such as CO
2
, CH
4
, H
2
, while increased O
2
permeability at 1 bar. |
| doi_str_mv | 10.1007/s00289-016-1832-y |
| format | Article |
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m
-BA6FPPO), 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4′-oxydianiline (ODA) and poly(dimethylsiloxane) (PDMS, amine terminated,
M
n
= 2500 g/mol). Homogeneous cavity distribution and homogeneous porosity appeared for the copolyimide containing 1.5 wt% of poly(dimethylsiloxane). The tensile strength and modulus of the materials containing 1.5 wt% of poly(dimethylsiloxane) had the highest values among others. The decomposition temperatures increased with increase of PDMS content. In general, hybrid materials were transparent. Storage moduli of 1.5 and 2 wt% of silicone containing materials were greater than those of others. The optimum results for the single gas permeability were achieved at 1 bar for the materials containing 1.5 and 2 wt% poly(dimethylsiloxane). The volume fraction of silicone was determined from thermomechanical analysis at a certain temperature for each sample. The best correlation between volume fraction of silicone and selectivities was obtained for CH
4
/CO
2
, CH
4
/N
2
, CO
2
/O
2
, CO
2
/N
2
and CH
4
/O
2
. Bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide ingredient in the same amounted silicone containing materials decreased the permeabilities of gases such as CO
2
, CH
4
, H
2
, while increased O
2
permeability at 1 bar.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-016-1832-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Carbon dioxide ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Contact angle ; Fluorine ; Gas permeation ; Gases ; Membranes ; Nitrogen ; Organic Chemistry ; Original Paper ; Permeability ; Phosphine oxide ; Physical Chemistry ; Polydimethylsiloxane ; Polyethylene glycol ; Polymer Sciences ; Polymers ; Scanning electron microscopy ; Soft and Granular Matter ; Tensile strength ; Thermomechanical analysis</subject><ispartof>Polymer bulletin (Berlin, Germany), 2017-06, Vol.74 (6), p.2217-2244</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Springer-Verlag Berlin Heidelberg 2016.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-3fe60d0c7d03b0bf38314e523ae1bf2cae9ce19cf0e1689acdeb5aa2dfa63ac13</citedby><cites>FETCH-LOGICAL-c353t-3fe60d0c7d03b0bf38314e523ae1bf2cae9ce19cf0e1689acdeb5aa2dfa63ac13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-016-1832-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917872753?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,41488,42557,43805,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Biçen, Merve</creatorcontrib><creatorcontrib>Karataş, Sevim</creatorcontrib><creatorcontrib>Kayaman-Apohan, Nilhan</creatorcontrib><creatorcontrib>Güngör, Atilla</creatorcontrib><title>Thermal, physical, structural, thermomechanical features and single gas permeation comparison of fluorine, phenyl phosphine oxide-based copolyimides with poly(dimethylsiloxane)</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>In this study, a series of copolyimide have been obtained, using a newly synthesized monomer named bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide (
m
-BA6FPPO), 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4′-oxydianiline (ODA) and poly(dimethylsiloxane) (PDMS, amine terminated,
M
n
= 2500 g/mol). Homogeneous cavity distribution and homogeneous porosity appeared for the copolyimide containing 1.5 wt% of poly(dimethylsiloxane). The tensile strength and modulus of the materials containing 1.5 wt% of poly(dimethylsiloxane) had the highest values among others. The decomposition temperatures increased with increase of PDMS content. In general, hybrid materials were transparent. Storage moduli of 1.5 and 2 wt% of silicone containing materials were greater than those of others. The optimum results for the single gas permeability were achieved at 1 bar for the materials containing 1.5 and 2 wt% poly(dimethylsiloxane). The volume fraction of silicone was determined from thermomechanical analysis at a certain temperature for each sample. The best correlation between volume fraction of silicone and selectivities was obtained for CH
4
/CO
2
, CH
4
/N
2
, CO
2
/O
2
, CO
2
/N
2
and CH
4
/O
2
. Bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide ingredient in the same amounted silicone containing materials decreased the permeabilities of gases such as CO
2
, CH
4
, H
2
, while increased O
2
permeability at 1 bar.</description><subject>Carbon dioxide</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Contact angle</subject><subject>Fluorine</subject><subject>Gas permeation</subject><subject>Gases</subject><subject>Membranes</subject><subject>Nitrogen</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Permeability</subject><subject>Phosphine oxide</subject><subject>Physical Chemistry</subject><subject>Polydimethylsiloxane</subject><subject>Polyethylene glycol</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Scanning electron microscopy</subject><subject>Soft and Granular Matter</subject><subject>Tensile strength</subject><subject>Thermomechanical analysis</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1Uctu1TAQtRBIXAofwM4SG5Aw-HFvHktUFYpUiU1ZWxNnfOMqsYMnEc1f8Yk4ukhdsZozcx6zOIy9VfKTkrL-TFLqphVSVUI1RovtGTuoo6mEPh7b5-wgVS2FbEz7kr0iepBlryp1YH_uB8wTjB_5PGwU3I5oyatb1rzjZafThG6AuLPcIxQKiUPsOYV4HpGfgfhcdIUKKXKXphlyoAKT535cUw4R9w8Yt7GMRPNQLjw9hh5FB4R9Mc1p3MJULsR_h2Xg-_6-DxMuwzZSGNMjRPzwmr3wMBK--Tev2M-vN_fXt-Lux7fv11_uhDMnswjjsZK9dHUvTSc7bxqjjnjSBlB1XjvA1qFqnZeoqqYF12N3AtC9h8qAU-aKvbvkzjn9WpEW-5DWHMtLq1tVN7WuT6ao1EXlciLK6O2cwwR5s0ravRh7KcaWYuxejN2KR188VLTxjPkp-f-mv8TsmEE</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>Biçen, Merve</creator><creator>Karataş, Sevim</creator><creator>Kayaman-Apohan, Nilhan</creator><creator>Güngör, Atilla</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20170601</creationdate><title>Thermal, physical, structural, thermomechanical features and single gas permeation comparison of fluorine, phenyl phosphine oxide-based copolyimides with poly(dimethylsiloxane)</title><author>Biçen, Merve ; Karataş, Sevim ; Kayaman-Apohan, Nilhan ; Güngör, Atilla</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-3fe60d0c7d03b0bf38314e523ae1bf2cae9ce19cf0e1689acdeb5aa2dfa63ac13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Carbon dioxide</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Contact angle</topic><topic>Fluorine</topic><topic>Gas permeation</topic><topic>Gases</topic><topic>Membranes</topic><topic>Nitrogen</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Permeability</topic><topic>Phosphine oxide</topic><topic>Physical Chemistry</topic><topic>Polydimethylsiloxane</topic><topic>Polyethylene glycol</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Scanning electron microscopy</topic><topic>Soft and Granular Matter</topic><topic>Tensile strength</topic><topic>Thermomechanical analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biçen, Merve</creatorcontrib><creatorcontrib>Karataş, Sevim</creatorcontrib><creatorcontrib>Kayaman-Apohan, Nilhan</creatorcontrib><creatorcontrib>Güngör, Atilla</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biçen, Merve</au><au>Karataş, Sevim</au><au>Kayaman-Apohan, Nilhan</au><au>Güngör, Atilla</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal, physical, structural, thermomechanical features and single gas permeation comparison of fluorine, phenyl phosphine oxide-based copolyimides with poly(dimethylsiloxane)</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2017-06-01</date><risdate>2017</risdate><volume>74</volume><issue>6</issue><spage>2217</spage><epage>2244</epage><pages>2217-2244</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>In this study, a series of copolyimide have been obtained, using a newly synthesized monomer named bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide (
m
-BA6FPPO), 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4′-oxydianiline (ODA) and poly(dimethylsiloxane) (PDMS, amine terminated,
M
n
= 2500 g/mol). Homogeneous cavity distribution and homogeneous porosity appeared for the copolyimide containing 1.5 wt% of poly(dimethylsiloxane). The tensile strength and modulus of the materials containing 1.5 wt% of poly(dimethylsiloxane) had the highest values among others. The decomposition temperatures increased with increase of PDMS content. In general, hybrid materials were transparent. Storage moduli of 1.5 and 2 wt% of silicone containing materials were greater than those of others. The optimum results for the single gas permeability were achieved at 1 bar for the materials containing 1.5 and 2 wt% poly(dimethylsiloxane). The volume fraction of silicone was determined from thermomechanical analysis at a certain temperature for each sample. The best correlation between volume fraction of silicone and selectivities was obtained for CH
4
/CO
2
, CH
4
/N
2
, CO
2
/O
2
, CO
2
/N
2
and CH
4
/O
2
. Bis-(3-aminophenoxy-3-trifluoromethyl-4-phenyl)phenylphosphine oxide ingredient in the same amounted silicone containing materials decreased the permeabilities of gases such as CO
2
, CH
4
, H
2
, while increased O
2
permeability at 1 bar.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-016-1832-y</doi><tpages>28</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2017-06, Vol.74 (6), p.2217-2244 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_2917872753 |
| source | SpringerNature Journals; ProQuest Central UK/Ireland; ProQuest Central |
| subjects | Carbon dioxide Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Contact angle Fluorine Gas permeation Gases Membranes Nitrogen Organic Chemistry Original Paper Permeability Phosphine oxide Physical Chemistry Polydimethylsiloxane Polyethylene glycol Polymer Sciences Polymers Scanning electron microscopy Soft and Granular Matter Tensile strength Thermomechanical analysis |
| title | Thermal, physical, structural, thermomechanical features and single gas permeation comparison of fluorine, phenyl phosphine oxide-based copolyimides with poly(dimethylsiloxane) |
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