Thermo-mechanical properties of MWCNT-g-poly (l-lactide)/poly (l-lactide) nanocomposites

The thermo-mechanical properties of poly ( l -lactide) (PLLA) biodegradable polymer reinforced with PLLA grafted from multiwalled carbon nanotubes (MWCNT- g -PLLA)s are characterized. The crystallinity of PLLA polymer matrix affected by MWCNT- g -PLLAs is illuminated. For this purpose, the PLLA chai...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Polymer bulletin (Berlin, Germany) Germany), 2013-10, Vol.70 (10), p.2741-2754
Hauptverfasser:	Amirian, Maryam, Nabipour Chakoli, Ali, Sui, Jie He, Cai, Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Aluminum Applied sciences Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chloroform Complex Fluids and Microfluidics Composites Crystal structure Crystallinity Dispersion Dynamic mechanical analysis Exact sciences and technology Forms of application and semi-finished materials Glass transition temperature Grafting Mechanical properties Melting points Microscopy Modulus of elasticity Molecular weight Multi wall carbon nanotubes Nanocomposites Nucleation Organic Chemistry Original Paper Physical Chemistry Polylactic acid Polymer blends Polymer industry, paints, wood Polymer Sciences Polymers Reagents Soft and Granular Matter Technology of polymers Thermomechanical properties
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	2754
container_issue	10
container_start_page	2741
container_title	Polymer bulletin (Berlin, Germany)
container_volume	70
creator	Amirian, Maryam Nabipour Chakoli, Ali Sui, Jie He Cai, Wei
description	The thermo-mechanical properties of poly ( l -lactide) (PLLA) biodegradable polymer reinforced with PLLA grafted from multiwalled carbon nanotubes (MWCNT- g -PLLA)s are characterized. The crystallinity of PLLA polymer matrix affected by MWCNT- g -PLLAs is illuminated. For this purpose, the PLLA chains are covalently grafted from the sidewall of aminated MWCNTs. Then, the MWCNT- g -PLLAs/PLLA composite films are prepared by solution casting using chloroform as solvent. It is found that the MWCNT- g -PLLAs well dispersed in PLLA matrix. The mechanical properties of PLLA enhanced gradually with the increasing concentrations of MWCNT- g -PLLAs up to 2 wt%. The MWCNT- g -PLLAs increase the glass transition temperature ( T g ) and melting point of PLLA as revealed by the curves from differential scanning calorimeter (DSC). In addition, the dynamic mechanical analysis (DMA) results show that the T g and Young modulus of PLLA increase with the increment in the concentrations of MWCNT- g -PLLAs. Due to the homogenous dispersion of MWCNT- g -PLLAs and the van der Walls force between grafted PLLA chains on the sidewall of MWCNTs and the PLLA matrix chains, the chain stiffness in amorphous phase of PLLA increases. In addition, the MWCNT- g -PLLAs as heterogeneous nucleation agents increase the crystallinity of PLLA.
doi_str_mv	10.1007/s00289-013-0984-2
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2917872273</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2917872273</sourcerecordid><originalsourceid>FETCH-LOGICAL-c346t-46b963eb0f7ab478f16f39831ed902c824a30f10781a230b46bb0844617ec17e3</originalsourceid><addsrcrecordid>eNp1kMtKAzEUhoMoWKsP4G5ABF3EnlzIZSnFG1TdVHQXMmmmnTKdjMl00bc3ZURBcBEOyfnOn8OH0DmBGwIgJwmAKo2BMAxacUwP0IhwJjDlXB-iERAJGBTTx-gkpTXkuxBkhD7mKx83AW-8W9m2drYpuhg6H_vapyJUxfP79GWOl7gLza64anBjXV8v_PXk70PR2ja4sOlCqnufTtFRZZvkz77rGL3d382nj3j2-vA0vZ1hx7joMRelFsyXUElbcqkqIiqmFSN-oYE6RbllUBGQiljKoMx8CYpzQaR3-bAxuhhy89qfW596sw7b2OYvDdVEKkmpZJkiA-ViSCn6ynSx3ti4MwTMXqAZBJos0OwFGppnLr-TbcpeqmhbV6efQSqFlESQzNGBS7nVLn383eD_8C96hH5V</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2917872273</pqid></control><display><type>article</type><title>Thermo-mechanical properties of MWCNT-g-poly (l-lactide)/poly (l-lactide) nanocomposites</title><source>ProQuest Central UK/Ireland</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Amirian, Maryam ; Nabipour Chakoli, Ali ; Sui, Jie He ; Cai, Wei</creator><creatorcontrib>Amirian, Maryam ; Nabipour Chakoli, Ali ; Sui, Jie He ; Cai, Wei</creatorcontrib><description>The thermo-mechanical properties of poly ( l -lactide) (PLLA) biodegradable polymer reinforced with PLLA grafted from multiwalled carbon nanotubes (MWCNT- g -PLLA)s are characterized. The crystallinity of PLLA polymer matrix affected by MWCNT- g -PLLAs is illuminated. For this purpose, the PLLA chains are covalently grafted from the sidewall of aminated MWCNTs. Then, the MWCNT- g -PLLAs/PLLA composite films are prepared by solution casting using chloroform as solvent. It is found that the MWCNT- g -PLLAs well dispersed in PLLA matrix. The mechanical properties of PLLA enhanced gradually with the increasing concentrations of MWCNT- g -PLLAs up to 2 wt%. The MWCNT- g -PLLAs increase the glass transition temperature ( T g ) and melting point of PLLA as revealed by the curves from differential scanning calorimeter (DSC). In addition, the dynamic mechanical analysis (DMA) results show that the T g and Young modulus of PLLA increase with the increment in the concentrations of MWCNT- g -PLLAs. Due to the homogenous dispersion of MWCNT- g -PLLAs and the van der Walls force between grafted PLLA chains on the sidewall of MWCNTs and the PLLA matrix chains, the chain stiffness in amorphous phase of PLLA increases. In addition, the MWCNT- g -PLLAs as heterogeneous nucleation agents increase the crystallinity of PLLA.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-013-0984-2</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acids ; Aluminum ; Applied sciences ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Chloroform ; Complex Fluids and Microfluidics ; Composites ; Crystal structure ; Crystallinity ; Dispersion ; Dynamic mechanical analysis ; Exact sciences and technology ; Forms of application and semi-finished materials ; Glass transition temperature ; Grafting ; Mechanical properties ; Melting points ; Microscopy ; Modulus of elasticity ; Molecular weight ; Multi wall carbon nanotubes ; Nanocomposites ; Nucleation ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polylactic acid ; Polymer blends ; Polymer industry, paints, wood ; Polymer Sciences ; Polymers ; Reagents ; Soft and Granular Matter ; Technology of polymers ; Thermomechanical properties</subject><ispartof>Polymer bulletin (Berlin, Germany), 2013-10, Vol.70 (10), p.2741-2754</ispartof><rights>Springer-Verlag Berlin Heidelberg 2013</rights><rights>2015 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2013.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-46b963eb0f7ab478f16f39831ed902c824a30f10781a230b46bb0844617ec17e3</citedby><cites>FETCH-LOGICAL-c346t-46b963eb0f7ab478f16f39831ed902c824a30f10781a230b46bb0844617ec17e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-013-0984-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917872273?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,41488,42557,43805,51319,64385,64389,72469</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27677161$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Amirian, Maryam</creatorcontrib><creatorcontrib>Nabipour Chakoli, Ali</creatorcontrib><creatorcontrib>Sui, Jie He</creatorcontrib><creatorcontrib>Cai, Wei</creatorcontrib><title>Thermo-mechanical properties of MWCNT-g-poly (l-lactide)/poly (l-lactide) nanocomposites</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>The thermo-mechanical properties of poly ( l -lactide) (PLLA) biodegradable polymer reinforced with PLLA grafted from multiwalled carbon nanotubes (MWCNT- g -PLLA)s are characterized. The crystallinity of PLLA polymer matrix affected by MWCNT- g -PLLAs is illuminated. For this purpose, the PLLA chains are covalently grafted from the sidewall of aminated MWCNTs. Then, the MWCNT- g -PLLAs/PLLA composite films are prepared by solution casting using chloroform as solvent. It is found that the MWCNT- g -PLLAs well dispersed in PLLA matrix. The mechanical properties of PLLA enhanced gradually with the increasing concentrations of MWCNT- g -PLLAs up to 2 wt%. The MWCNT- g -PLLAs increase the glass transition temperature ( T g ) and melting point of PLLA as revealed by the curves from differential scanning calorimeter (DSC). In addition, the dynamic mechanical analysis (DMA) results show that the T g and Young modulus of PLLA increase with the increment in the concentrations of MWCNT- g -PLLAs. Due to the homogenous dispersion of MWCNT- g -PLLAs and the van der Walls force between grafted PLLA chains on the sidewall of MWCNTs and the PLLA matrix chains, the chain stiffness in amorphous phase of PLLA increases. In addition, the MWCNT- g -PLLAs as heterogeneous nucleation agents increase the crystallinity of PLLA.</description><subject>Acids</subject><subject>Aluminum</subject><subject>Applied sciences</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chloroform</subject><subject>Complex Fluids and Microfluidics</subject><subject>Composites</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Dispersion</subject><subject>Dynamic mechanical analysis</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Glass transition temperature</subject><subject>Grafting</subject><subject>Mechanical properties</subject><subject>Melting points</subject><subject>Microscopy</subject><subject>Modulus of elasticity</subject><subject>Molecular weight</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanocomposites</subject><subject>Nucleation</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polylactic acid</subject><subject>Polymer blends</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Reagents</subject><subject>Soft and Granular Matter</subject><subject>Technology of polymers</subject><subject>Thermomechanical properties</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kMtKAzEUhoMoWKsP4G5ABF3EnlzIZSnFG1TdVHQXMmmmnTKdjMl00bc3ZURBcBEOyfnOn8OH0DmBGwIgJwmAKo2BMAxacUwP0IhwJjDlXB-iERAJGBTTx-gkpTXkuxBkhD7mKx83AW-8W9m2drYpuhg6H_vapyJUxfP79GWOl7gLza64anBjXV8v_PXk70PR2ja4sOlCqnufTtFRZZvkz77rGL3d382nj3j2-vA0vZ1hx7joMRelFsyXUElbcqkqIiqmFSN-oYE6RbllUBGQiljKoMx8CYpzQaR3-bAxuhhy89qfW596sw7b2OYvDdVEKkmpZJkiA-ViSCn6ynSx3ti4MwTMXqAZBJos0OwFGppnLr-TbcpeqmhbV6efQSqFlESQzNGBS7nVLn383eD_8C96hH5V</recordid><startdate>20131001</startdate><enddate>20131001</enddate><creator>Amirian, Maryam</creator><creator>Nabipour Chakoli, Ali</creator><creator>Sui, Jie He</creator><creator>Cai, Wei</creator><general>Springer Berlin Heidelberg</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20131001</creationdate><title>Thermo-mechanical properties of MWCNT-g-poly (l-lactide)/poly (l-lactide) nanocomposites</title><author>Amirian, Maryam ; Nabipour Chakoli, Ali ; Sui, Jie He ; Cai, Wei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-46b963eb0f7ab478f16f39831ed902c824a30f10781a230b46bb0844617ec17e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Acids</topic><topic>Aluminum</topic><topic>Applied sciences</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chloroform</topic><topic>Complex Fluids and Microfluidics</topic><topic>Composites</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Dispersion</topic><topic>Dynamic mechanical analysis</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Glass transition temperature</topic><topic>Grafting</topic><topic>Mechanical properties</topic><topic>Melting points</topic><topic>Microscopy</topic><topic>Modulus of elasticity</topic><topic>Molecular weight</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanocomposites</topic><topic>Nucleation</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polylactic acid</topic><topic>Polymer blends</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Reagents</topic><topic>Soft and Granular Matter</topic><topic>Technology of polymers</topic><topic>Thermomechanical properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Amirian, Maryam</creatorcontrib><creatorcontrib>Nabipour Chakoli, Ali</creatorcontrib><creatorcontrib>Sui, Jie He</creatorcontrib><creatorcontrib>Cai, Wei</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Amirian, Maryam</au><au>Nabipour Chakoli, Ali</au><au>Sui, Jie He</au><au>Cai, Wei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermo-mechanical properties of MWCNT-g-poly (l-lactide)/poly (l-lactide) nanocomposites</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2013-10-01</date><risdate>2013</risdate><volume>70</volume><issue>10</issue><spage>2741</spage><epage>2754</epage><pages>2741-2754</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>The thermo-mechanical properties of poly ( l -lactide) (PLLA) biodegradable polymer reinforced with PLLA grafted from multiwalled carbon nanotubes (MWCNT- g -PLLA)s are characterized. The crystallinity of PLLA polymer matrix affected by MWCNT- g -PLLAs is illuminated. For this purpose, the PLLA chains are covalently grafted from the sidewall of aminated MWCNTs. Then, the MWCNT- g -PLLAs/PLLA composite films are prepared by solution casting using chloroform as solvent. It is found that the MWCNT- g -PLLAs well dispersed in PLLA matrix. The mechanical properties of PLLA enhanced gradually with the increasing concentrations of MWCNT- g -PLLAs up to 2 wt%. The MWCNT- g -PLLAs increase the glass transition temperature ( T g ) and melting point of PLLA as revealed by the curves from differential scanning calorimeter (DSC). In addition, the dynamic mechanical analysis (DMA) results show that the T g and Young modulus of PLLA increase with the increment in the concentrations of MWCNT- g -PLLAs. Due to the homogenous dispersion of MWCNT- g -PLLAs and the van der Walls force between grafted PLLA chains on the sidewall of MWCNTs and the PLLA matrix chains, the chain stiffness in amorphous phase of PLLA increases. In addition, the MWCNT- g -PLLAs as heterogeneous nucleation agents increase the crystallinity of PLLA.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-013-0984-2</doi><tpages>14</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 0170-0839
ispartof	Polymer bulletin (Berlin, Germany), 2013-10, Vol.70 (10), p.2741-2754
issn	0170-0839 1436-2449
language	eng
recordid	cdi_proquest_journals_2917872273
source	ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central
subjects	Acids Aluminum Applied sciences Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chloroform Complex Fluids and Microfluidics Composites Crystal structure Crystallinity Dispersion Dynamic mechanical analysis Exact sciences and technology Forms of application and semi-finished materials Glass transition temperature Grafting Mechanical properties Melting points Microscopy Modulus of elasticity Molecular weight Multi wall carbon nanotubes Nanocomposites Nucleation Organic Chemistry Original Paper Physical Chemistry Polylactic acid Polymer blends Polymer industry, paints, wood Polymer Sciences Polymers Reagents Soft and Granular Matter Technology of polymers Thermomechanical properties
title	Thermo-mechanical properties of MWCNT-g-poly (l-lactide)/poly (l-lactide) nanocomposites
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T04%3A11%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermo-mechanical%20properties%20of%20MWCNT-g-poly%20(l-lactide)/poly%20(l-lactide)%20nanocomposites&rft.jtitle=Polymer%20bulletin%20(Berlin,%20Germany)&rft.au=Amirian,%20Maryam&rft.date=2013-10-01&rft.volume=70&rft.issue=10&rft.spage=2741&rft.epage=2754&rft.pages=2741-2754&rft.issn=0170-0839&rft.eissn=1436-2449&rft.coden=POBUDR&rft_id=info:doi/10.1007/s00289-013-0984-2&rft_dat=%3Cproquest_cross%3E2917872273%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2917872273&rft_id=info:pmid/&rfr_iscdi=true