Preparation and properties of organic-inorganic hybrid materials from sodium silicate
SummaryIn this study, organic-inorganic hybrid monomer, poly silicic acid urethane methacrylate (PSUMA), was prepared by reaction of poly silicic acid extracted from sodium silicate aqueous solution with THF and 2-(methacryloyloxy)ethyl isocyanate. The PSUMA was copolymerized with methyl methacrylat...
Gespeichert in:
| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2004-10, Vol.52 (3-4), p.209-218 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 218 |
|---|---|
| container_issue | 3-4 |
| container_start_page | 209 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 52 |
| creator | SUGIMOTO, Hideki NAKANISHI, Eiji YANTAUCHI, Katsunori DAIMATSU, Kazuki YASUMURA, Takashi INOMATA, Katsuhiro |
| description | SummaryIn this study, organic-inorganic hybrid monomer, poly silicic acid urethane methacrylate (PSUMA), was prepared by reaction of poly silicic acid extracted from sodium silicate aqueous solution with THF and 2-(methacryloyloxy)ethyl isocyanate. The PSUMA was copolymerized with methyl methacrylate to obtain hybrid copolymers. The material properties such as mechanical properties, thermal properties, Vickers hardness, transparency and so on were evaluated. The PMMA-PSUMA hybrid copolymers kept high transparency and showed higher elastic modulus and Vickers hardness than those of raw PMMA. Moreover, in comparison with PMMA, the hybrid copolymers had greater heat-resistance and lower volume contraction. |
| doi_str_mv | 10.1007/s00289-004-0283-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2917871973</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2917871973</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-69f1798a236d429970b4432d4a6b39b1749e682fef917ac87794d6c2fbe695973</originalsourceid><addsrcrecordid>eNpFUMtKAzEUDaJgrX6Au4C4jObVZLKU4gsKurDrkMkkmtJOxpvpov16U1pwdc_lPO7lIHTL6AOjVD8WSnljCKWSVCDI_gxNmBSKcCnNOZpQpimhjTCX6KqUFa27UmyClp8QBgduTLnHru_wAHkIMKZQcI44w7frkyepPyH8s2shdXjjxgDJrQuOkDe45C5t60jr5CtzjS5i5cLNaU7R8uX5a_5GFh-v7_OnBfFC6ZEoE5k2jeNCdZIbo2krpeCddKoVpmVamqAaHkM0TDvfaG1kpzyPbVBmZrSYortjbv36dxvKaFd5C309aXm1NJpVUVWxo8pDLgVCtAOkjYOdZdQe2rPH9mxtzx7as_vquT8lu-LdOoLrfSr_RsVmmnEm_gCTk2_T</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2917871973</pqid></control><display><type>article</type><title>Preparation and properties of organic-inorganic hybrid materials from sodium silicate</title><source>SpringerLink Journals</source><source>ProQuest Central</source><creator>SUGIMOTO, Hideki ; NAKANISHI, Eiji ; YANTAUCHI, Katsunori ; DAIMATSU, Kazuki ; YASUMURA, Takashi ; INOMATA, Katsuhiro</creator><creatorcontrib>SUGIMOTO, Hideki ; NAKANISHI, Eiji ; YANTAUCHI, Katsunori ; DAIMATSU, Kazuki ; YASUMURA, Takashi ; INOMATA, Katsuhiro</creatorcontrib><description>SummaryIn this study, organic-inorganic hybrid monomer, poly silicic acid urethane methacrylate (PSUMA), was prepared by reaction of poly silicic acid extracted from sodium silicate aqueous solution with THF and 2-(methacryloyloxy)ethyl isocyanate. The PSUMA was copolymerized with methyl methacrylate to obtain hybrid copolymers. The material properties such as mechanical properties, thermal properties, Vickers hardness, transparency and so on were evaluated. The PMMA-PSUMA hybrid copolymers kept high transparency and showed higher elastic modulus and Vickers hardness than those of raw PMMA. Moreover, in comparison with PMMA, the hybrid copolymers had greater heat-resistance and lower volume contraction.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-004-0283-z</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Applied sciences ; Aqueous solutions ; Copolymerization ; Copolymers ; Diamond pyramid hardness ; Exact sciences and technology ; Isocyanates ; Material properties ; Mechanical properties ; Modulus of elasticity ; Physicochemistry of polymers ; Polymethyl methacrylate ; Sodium silicates ; Thermodynamic properties</subject><ispartof>Polymer bulletin (Berlin, Germany), 2004-10, Vol.52 (3-4), p.209-218</ispartof><rights>2005 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2004.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-69f1798a236d429970b4432d4a6b39b1749e682fef917ac87794d6c2fbe695973</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2917871973?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,43805,64385,64389,72469</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16157121$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>SUGIMOTO, Hideki</creatorcontrib><creatorcontrib>NAKANISHI, Eiji</creatorcontrib><creatorcontrib>YANTAUCHI, Katsunori</creatorcontrib><creatorcontrib>DAIMATSU, Kazuki</creatorcontrib><creatorcontrib>YASUMURA, Takashi</creatorcontrib><creatorcontrib>INOMATA, Katsuhiro</creatorcontrib><title>Preparation and properties of organic-inorganic hybrid materials from sodium silicate</title><title>Polymer bulletin (Berlin, Germany)</title><description>SummaryIn this study, organic-inorganic hybrid monomer, poly silicic acid urethane methacrylate (PSUMA), was prepared by reaction of poly silicic acid extracted from sodium silicate aqueous solution with THF and 2-(methacryloyloxy)ethyl isocyanate. The PSUMA was copolymerized with methyl methacrylate to obtain hybrid copolymers. The material properties such as mechanical properties, thermal properties, Vickers hardness, transparency and so on were evaluated. The PMMA-PSUMA hybrid copolymers kept high transparency and showed higher elastic modulus and Vickers hardness than those of raw PMMA. Moreover, in comparison with PMMA, the hybrid copolymers had greater heat-resistance and lower volume contraction.</description><subject>Applied sciences</subject><subject>Aqueous solutions</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Diamond pyramid hardness</subject><subject>Exact sciences and technology</subject><subject>Isocyanates</subject><subject>Material properties</subject><subject>Mechanical properties</subject><subject>Modulus of elasticity</subject><subject>Physicochemistry of polymers</subject><subject>Polymethyl methacrylate</subject><subject>Sodium silicates</subject><subject>Thermodynamic properties</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpFUMtKAzEUDaJgrX6Au4C4jObVZLKU4gsKurDrkMkkmtJOxpvpov16U1pwdc_lPO7lIHTL6AOjVD8WSnljCKWSVCDI_gxNmBSKcCnNOZpQpimhjTCX6KqUFa27UmyClp8QBgduTLnHru_wAHkIMKZQcI44w7frkyepPyH8s2shdXjjxgDJrQuOkDe45C5t60jr5CtzjS5i5cLNaU7R8uX5a_5GFh-v7_OnBfFC6ZEoE5k2jeNCdZIbo2krpeCddKoVpmVamqAaHkM0TDvfaG1kpzyPbVBmZrSYortjbv36dxvKaFd5C309aXm1NJpVUVWxo8pDLgVCtAOkjYOdZdQe2rPH9mxtzx7as_vquT8lu-LdOoLrfSr_RsVmmnEm_gCTk2_T</recordid><startdate>20041001</startdate><enddate>20041001</enddate><creator>SUGIMOTO, Hideki</creator><creator>NAKANISHI, Eiji</creator><creator>YANTAUCHI, Katsunori</creator><creator>DAIMATSU, Kazuki</creator><creator>YASUMURA, Takashi</creator><creator>INOMATA, Katsuhiro</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20041001</creationdate><title>Preparation and properties of organic-inorganic hybrid materials from sodium silicate</title><author>SUGIMOTO, Hideki ; NAKANISHI, Eiji ; YANTAUCHI, Katsunori ; DAIMATSU, Kazuki ; YASUMURA, Takashi ; INOMATA, Katsuhiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-69f1798a236d429970b4432d4a6b39b1749e682fef917ac87794d6c2fbe695973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Aqueous solutions</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Diamond pyramid hardness</topic><topic>Exact sciences and technology</topic><topic>Isocyanates</topic><topic>Material properties</topic><topic>Mechanical properties</topic><topic>Modulus of elasticity</topic><topic>Physicochemistry of polymers</topic><topic>Polymethyl methacrylate</topic><topic>Sodium silicates</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>SUGIMOTO, Hideki</creatorcontrib><creatorcontrib>NAKANISHI, Eiji</creatorcontrib><creatorcontrib>YANTAUCHI, Katsunori</creatorcontrib><creatorcontrib>DAIMATSU, Kazuki</creatorcontrib><creatorcontrib>YASUMURA, Takashi</creatorcontrib><creatorcontrib>INOMATA, Katsuhiro</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>Materials Science Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SUGIMOTO, Hideki</au><au>NAKANISHI, Eiji</au><au>YANTAUCHI, Katsunori</au><au>DAIMATSU, Kazuki</au><au>YASUMURA, Takashi</au><au>INOMATA, Katsuhiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and properties of organic-inorganic hybrid materials from sodium silicate</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>2004-10-01</date><risdate>2004</risdate><volume>52</volume><issue>3-4</issue><spage>209</spage><epage>218</epage><pages>209-218</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>SummaryIn this study, organic-inorganic hybrid monomer, poly silicic acid urethane methacrylate (PSUMA), was prepared by reaction of poly silicic acid extracted from sodium silicate aqueous solution with THF and 2-(methacryloyloxy)ethyl isocyanate. The PSUMA was copolymerized with methyl methacrylate to obtain hybrid copolymers. The material properties such as mechanical properties, thermal properties, Vickers hardness, transparency and so on were evaluated. The PMMA-PSUMA hybrid copolymers kept high transparency and showed higher elastic modulus and Vickers hardness than those of raw PMMA. Moreover, in comparison with PMMA, the hybrid copolymers had greater heat-resistance and lower volume contraction.</abstract><cop>Heidelberg</cop><cop>Berlin</cop><cop>New York, NY</cop><pub>Springer</pub><doi>10.1007/s00289-004-0283-z</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2004-10, Vol.52 (3-4), p.209-218 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_2917871973 |
| source | SpringerLink Journals; ProQuest Central |
| subjects | Applied sciences Aqueous solutions Copolymerization Copolymers Diamond pyramid hardness Exact sciences and technology Isocyanates Material properties Mechanical properties Modulus of elasticity Physicochemistry of polymers Polymethyl methacrylate Sodium silicates Thermodynamic properties |
| title | Preparation and properties of organic-inorganic hybrid materials from sodium silicate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-20T15%3A53%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Preparation%20and%20properties%20of%20organic-inorganic%20hybrid%20materials%20from%20sodium%20silicate&rft.jtitle=Polymer%20bulletin%20(Berlin,%20Germany)&rft.au=SUGIMOTO,%20Hideki&rft.date=2004-10-01&rft.volume=52&rft.issue=3-4&rft.spage=209&rft.epage=218&rft.pages=209-218&rft.issn=0170-0839&rft.eissn=1436-2449&rft.coden=POBUDR&rft_id=info:doi/10.1007/s00289-004-0283-z&rft_dat=%3Cproquest_cross%3E2917871973%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2917871973&rft_id=info:pmid/&rfr_iscdi=true |