Application of novel hydrophobically modified polybetaines based on alkylaminocrotonates and methacrylic acid as pour point depressants and ASP flooding agent
A series of hydrophobically modified polymeric betaines (HMPB) were synthesized from alkylaminocrotonates and methacrylic acid, analyzed by methods of GPC, potentiometric titration and DSC and applied as pour point depressants (PPD) to high paraffinic crude oils of Western Kazakhstan. The efficiency...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2019-10, Vol.76 (10), p.5129-5147 |
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| creator | Kudaibergenov, Sarkyt Shakhvorostov, Alexey Gussenov, Iskander Seilkhanov, Tulegen Nuraje, Nurxat |
| description | A series of hydrophobically modified polymeric betaines (HMPB) were synthesized from alkylaminocrotonates and methacrylic acid, analyzed by methods of GPC, potentiometric titration and DSC and applied as pour point depressants (PPD) to high paraffinic crude oils of Western Kazakhstan. The efficiency of paraffin inhibition with the help of HMPB was evaluated in static and dynamic conditions. The physicochemical properties of the Mangyshlak oil and the Buzachi–Mangyshlak oil mixture (67:33 vol%) were determined. Paraffins were found to form gelled networks in the Mangyshlak oil and Buzachi–Mangyshlak oil mixture within the fractions of hydrocarbons with lengths of C
12
–C
17
and C
13
–C
16
. The results of testing the HMPB as PPD in the model tank and oil pipeline showed that, at a concentration of polymeric additives of 500 ppm and at an injection temperature of 60 °C, the quantity of precipitated asphaltene–resin–paraffin depositions was significantly reduced. The efficiency of HMPB bearing C
16
H
33
groups was tested as a prototype alkaline–surfactant–polymer flooding agent on the heavy oil of the Karazhanbas oilfield. |
| doi_str_mv | 10.1007/s00289-018-2626-1 |
| format | Article |
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12
–C
17
and C
13
–C
16
. The results of testing the HMPB as PPD in the model tank and oil pipeline showed that, at a concentration of polymeric additives of 500 ppm and at an injection temperature of 60 °C, the quantity of precipitated asphaltene–resin–paraffin depositions was significantly reduced. The efficiency of HMPB bearing C
16
H
33
groups was tested as a prototype alkaline–surfactant–polymer flooding agent on the heavy oil of the Karazhanbas oilfield.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-018-2626-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Additives ; Asphaltenes ; Betaines ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Cold ; Complex Fluids and Microfluidics ; Cooling ; Crude oil ; Depressants ; Enhanced oil recovery ; Hydrogels ; Methacrylic acid ; Mixtures ; Oil fields ; Organic Chemistry ; Original Paper ; Paraffins ; Petroleum pipelines ; Physical Chemistry ; Polymer flooding ; Polymer Sciences ; Polymers ; Soft and Granular Matter ; Solvents ; Steel pipes ; Temperature ; Titration ; Viscosity</subject><ispartof>Polymer bulletin (Berlin, Germany), 2019-10, Vol.76 (10), p.5129-5147</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-450dff52401ae9620a17bca341ce7e9d1d762358c7c83943458dda95df047bfa3</citedby><cites>FETCH-LOGICAL-c353t-450dff52401ae9620a17bca341ce7e9d1d762358c7c83943458dda95df047bfa3</cites><orcidid>0000-0002-1166-7826</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00289-018-2626-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2917871683?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,41464,42533,43781,51294</link.rule.ids></links><search><creatorcontrib>Kudaibergenov, Sarkyt</creatorcontrib><creatorcontrib>Shakhvorostov, Alexey</creatorcontrib><creatorcontrib>Gussenov, Iskander</creatorcontrib><creatorcontrib>Seilkhanov, Tulegen</creatorcontrib><creatorcontrib>Nuraje, Nurxat</creatorcontrib><title>Application of novel hydrophobically modified polybetaines based on alkylaminocrotonates and methacrylic acid as pour point depressants and ASP flooding agent</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>A series of hydrophobically modified polymeric betaines (HMPB) were synthesized from alkylaminocrotonates and methacrylic acid, analyzed by methods of GPC, potentiometric titration and DSC and applied as pour point depressants (PPD) to high paraffinic crude oils of Western Kazakhstan. The efficiency of paraffin inhibition with the help of HMPB was evaluated in static and dynamic conditions. The physicochemical properties of the Mangyshlak oil and the Buzachi–Mangyshlak oil mixture (67:33 vol%) were determined. Paraffins were found to form gelled networks in the Mangyshlak oil and Buzachi–Mangyshlak oil mixture within the fractions of hydrocarbons with lengths of C
12
–C
17
and C
13
–C
16
. The results of testing the HMPB as PPD in the model tank and oil pipeline showed that, at a concentration of polymeric additives of 500 ppm and at an injection temperature of 60 °C, the quantity of precipitated asphaltene–resin–paraffin depositions was significantly reduced. The efficiency of HMPB bearing C
16
H
33
groups was tested as a prototype alkaline–surfactant–polymer flooding agent on the heavy oil of the Karazhanbas oilfield.</description><subject>Additives</subject><subject>Asphaltenes</subject><subject>Betaines</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cold</subject><subject>Complex Fluids and Microfluidics</subject><subject>Cooling</subject><subject>Crude oil</subject><subject>Depressants</subject><subject>Enhanced oil recovery</subject><subject>Hydrogels</subject><subject>Methacrylic acid</subject><subject>Mixtures</subject><subject>Oil fields</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Paraffins</subject><subject>Petroleum pipelines</subject><subject>Physical Chemistry</subject><subject>Polymer flooding</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Soft and Granular Matter</subject><subject>Solvents</subject><subject>Steel pipes</subject><subject>Temperature</subject><subject>Titration</subject><subject>Viscosity</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1Uctq3DAUFSWFTtJ-QHeCrt3qZcteDiFpCoEUmqzFtR4zSjWSIykB_0y_tQoudJWNLrr3PKR7EPpMyVdKiPxWCGHj1BE6dmxgQ0ffoR0VfOiYENMZ2hEqSUdGPn1A56U8knYfBrpDf_bLEryG6lPEyeGYXmzAx9XktBzT3CYhrPiUjHfeGryksM62go-24BlKazUehN9rgJOPSedUU4TaphANPtl6BJ3X5oBBe4OhNInn3A4fKzZ2ybYUiHWD73_9xC6kZhYPGA421o_ovYNQ7Kd_9QI9XF_dX950t3fff1zubzvNe1470RPjXM8EoWCngRGgctbABdVW2slQIwfG-1FL3VYguOhHY2DqjSNCzg74Bfqy6S45PT3bUtVje2ZslopNVI6SDiNvKLqh2jdLydapJfsT5FVRol5jUFsMqsWgXmNQtHHYxikNGw82_1d-m_QXEZGOrQ</recordid><startdate>20191001</startdate><enddate>20191001</enddate><creator>Kudaibergenov, Sarkyt</creator><creator>Shakhvorostov, Alexey</creator><creator>Gussenov, Iskander</creator><creator>Seilkhanov, Tulegen</creator><creator>Nuraje, Nurxat</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-1166-7826</orcidid></search><sort><creationdate>20191001</creationdate><title>Application of novel hydrophobically modified polybetaines based on alkylaminocrotonates and methacrylic acid as pour point depressants and ASP flooding agent</title><author>Kudaibergenov, Sarkyt ; Shakhvorostov, Alexey ; Gussenov, Iskander ; Seilkhanov, Tulegen ; Nuraje, Nurxat</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-450dff52401ae9620a17bca341ce7e9d1d762358c7c83943458dda95df047bfa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Additives</topic><topic>Asphaltenes</topic><topic>Betaines</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cold</topic><topic>Complex Fluids and Microfluidics</topic><topic>Cooling</topic><topic>Crude oil</topic><topic>Depressants</topic><topic>Enhanced oil recovery</topic><topic>Hydrogels</topic><topic>Methacrylic acid</topic><topic>Mixtures</topic><topic>Oil fields</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Paraffins</topic><topic>Petroleum pipelines</topic><topic>Physical Chemistry</topic><topic>Polymer flooding</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Soft and Granular Matter</topic><topic>Solvents</topic><topic>Steel pipes</topic><topic>Temperature</topic><topic>Titration</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kudaibergenov, Sarkyt</creatorcontrib><creatorcontrib>Shakhvorostov, Alexey</creatorcontrib><creatorcontrib>Gussenov, Iskander</creatorcontrib><creatorcontrib>Seilkhanov, Tulegen</creatorcontrib><creatorcontrib>Nuraje, Nurxat</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kudaibergenov, Sarkyt</au><au>Shakhvorostov, Alexey</au><au>Gussenov, Iskander</au><au>Seilkhanov, Tulegen</au><au>Nuraje, Nurxat</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of novel hydrophobically modified polybetaines based on alkylaminocrotonates and methacrylic acid as pour point depressants and ASP flooding agent</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2019-10-01</date><risdate>2019</risdate><volume>76</volume><issue>10</issue><spage>5129</spage><epage>5147</epage><pages>5129-5147</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>A series of hydrophobically modified polymeric betaines (HMPB) were synthesized from alkylaminocrotonates and methacrylic acid, analyzed by methods of GPC, potentiometric titration and DSC and applied as pour point depressants (PPD) to high paraffinic crude oils of Western Kazakhstan. The efficiency of paraffin inhibition with the help of HMPB was evaluated in static and dynamic conditions. The physicochemical properties of the Mangyshlak oil and the Buzachi–Mangyshlak oil mixture (67:33 vol%) were determined. Paraffins were found to form gelled networks in the Mangyshlak oil and Buzachi–Mangyshlak oil mixture within the fractions of hydrocarbons with lengths of C
12
–C
17
and C
13
–C
16
. The results of testing the HMPB as PPD in the model tank and oil pipeline showed that, at a concentration of polymeric additives of 500 ppm and at an injection temperature of 60 °C, the quantity of precipitated asphaltene–resin–paraffin depositions was significantly reduced. The efficiency of HMPB bearing C
16
H
33
groups was tested as a prototype alkaline–surfactant–polymer flooding agent on the heavy oil of the Karazhanbas oilfield.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-018-2626-1</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0002-1166-7826</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals; ProQuest Central |
| subjects | Additives Asphaltenes Betaines Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Cold Complex Fluids and Microfluidics Cooling Crude oil Depressants Enhanced oil recovery Hydrogels Methacrylic acid Mixtures Oil fields Organic Chemistry Original Paper Paraffins Petroleum pipelines Physical Chemistry Polymer flooding Polymer Sciences Polymers Soft and Granular Matter Solvents Steel pipes Temperature Titration Viscosity |
| title | Application of novel hydrophobically modified polybetaines based on alkylaminocrotonates and methacrylic acid as pour point depressants and ASP flooding agent |
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