Preparation and characterization of novel polyimides from 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine for the selective extraction of some metals

Preparation and characterization of novel polyimides from 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine for the selective extraction of some metals

SummaryA group of new polyimides has been prepared by solution condensation of 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine containing pendant NMe2 units and various dianhyrides in N-methylpyrrolidone (NMP). The tridentate (N-N′-N) pydim ligands were prepared by Schiff-base condensation of...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 2005-08, Vol.55 (1-2), p.41-49
Hauptverfasser: SECKIN, Turgay, KÖYTEPE, Suleyman
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Copper
Exact sciences and technology
Formic acid
Imines
Manganese
Nickel
Organic polymers
Physicochemistry of polymers
Polyimide resins
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
Pyridines
Zinc
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KÖYTEPE, Suleyman
description SummaryA group of new polyimides has been prepared by solution condensation of 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine containing pendant NMe2 units and various dianhyrides in N-methylpyrrolidone (NMP). The tridentate (N-N′-N) pydim ligands were prepared by Schiff-base condensation of 2,6-diacetylpyridine and 4-dimethylaminoaniline in the presence of formic acid as catalyst. These polymers were investigated for their extraction capabilities for Zn(II), Mn(II), Cu(II), Cd (II) and Ni(II) and at different pH. Under different conditions enhanced selectivity was observed. Up to 98% quantitative recoveries were observed for all metals.
doi_str_mv 10.1007/s00289-005-0415-0
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The tridentate (N-N′-N) pydim ligands were prepared by Schiff-base condensation of 2,6-diacetylpyridine and 4-dimethylaminoaniline in the presence of formic acid as catalyst. These polymers were investigated for their extraction capabilities for Zn(II), Mn(II), Cu(II), Cd (II) and Ni(II) and at different pH. Under different conditions enhanced selectivity was observed. 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subjects Applied sciences
Copper
Exact sciences and technology
Formic acid
Imines
Manganese
Nickel
Organic polymers
Physicochemistry of polymers
Polyimide resins
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
Pyridines
Zinc
title Preparation and characterization of novel polyimides from 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine for the selective extraction of some metals
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