Radical polymerisation of methylacrylate initiation by the azidoadamantane / copper bromide system

SummaryA new initiating system, azidoadamantane/CuBr, for the radical polymerisation of methylacrylate was found. Polymerisations occur as well at 50°C in toluene solution as in bulk at 70°C. A kinetic study seems to show a monomer consumption of first order in monomer concentration. However, despit...

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Veröffentlicht in:	Polymer bulletin (Berlin, Germany) Germany), 2003-06, Vol.50 (4), p.265-269
Hauptverfasser:	HUNG ANH NGUYEN, CHERADAME, Hervé, GUERIN, Philippe
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Copper bromide Exact sciences and technology Initiation (polymerization) Monomers Organic polymers Physicochemistry of polymers Polydispersity Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Toluene
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