Transition metal complex induced morphology change in an ABC-triblock copolymer
SummaryThe short 1,2-polybutadiene center block of the ternary polystyrene-block-polybuta-diene-block-poly(methyl methacrylate) S45B6M49225 -triblock copolymer (subscripts indicating the weight fractions and the superscript indicating the total molecular weight in kg/mol) has been selectively modifi...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 1997-09, Vol.39 (3), p.361-368 |
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| container_end_page | 368 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | Bronstein, L. Seregina, M. Valetsky, P. Breiner, U. Abetz, V. Stadler, R. |
| description | SummaryThe short 1,2-polybutadiene center block of the ternary polystyrene-block-polybuta-diene-block-poly(methyl methacrylate) S45B6M49225 -triblock copolymer (subscripts indicating the weight fractions and the superscript indicating the total molecular weight in kg/mol) has been selectively modified by complexation with metal complexes of two different transition metals, namely Pd and Fe. These modifications cause significant variations in the microphase morphology. The original ls-morphology (spheres at lamellar interphase) belonging to the lamellar class changes via a cocontinuous morphology in the case of the Pd-complex to a morphology belonging to the cylindrical class for the Fe-complex. |
| doi_str_mv | 10.1007/s002890050160 |
| format | Article |
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These modifications cause significant variations in the microphase morphology. The original ls-morphology (spheres at lamellar interphase) belonging to the lamellar class changes via a cocontinuous morphology in the case of the Pd-complex to a morphology belonging to the cylindrical class for the Fe-complex.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s002890050160</identifier><language>eng</language><publisher>Heidelberg: Springer Nature B.V</publisher><subject>Block copolymers ; Coordination compounds ; Iron ; Morphology ; Palladium ; Polybutadiene ; Polymethyl methacrylate ; Polystyrene resins ; Transition metal compounds</subject><ispartof>Polymer bulletin (Berlin, Germany), 1997-09, Vol.39 (3), p.361-368</ispartof><rights>Springer-Verlag 1997.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c263t-4373f89c39c7063af1cf1ce81bdc47fdf593abc60d99a150fd3e275f6f21207f3</citedby><cites>FETCH-LOGICAL-c263t-4373f89c39c7063af1cf1ce81bdc47fdf593abc60d99a150fd3e275f6f21207f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2917867723?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,43805,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Bronstein, L.</creatorcontrib><creatorcontrib>Seregina, M.</creatorcontrib><creatorcontrib>Valetsky, P.</creatorcontrib><creatorcontrib>Breiner, U.</creatorcontrib><creatorcontrib>Abetz, V.</creatorcontrib><creatorcontrib>Stadler, R.</creatorcontrib><title>Transition metal complex induced morphology change in an ABC-triblock copolymer</title><title>Polymer bulletin (Berlin, Germany)</title><description>SummaryThe short 1,2-polybutadiene center block of the ternary polystyrene-block-polybuta-diene-block-poly(methyl methacrylate) S45B6M49225 -triblock copolymer (subscripts indicating the weight fractions and the superscript indicating the total molecular weight in kg/mol) has been selectively modified by complexation with metal complexes of two different transition metals, namely Pd and Fe. These modifications cause significant variations in the microphase morphology. The original ls-morphology (spheres at lamellar interphase) belonging to the lamellar class changes via a cocontinuous morphology in the case of the Pd-complex to a morphology belonging to the cylindrical class for the Fe-complex.</description><subject>Block copolymers</subject><subject>Coordination compounds</subject><subject>Iron</subject><subject>Morphology</subject><subject>Palladium</subject><subject>Polybutadiene</subject><subject>Polymethyl methacrylate</subject><subject>Polystyrene resins</subject><subject>Transition metal compounds</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpVkEFLxDAQhYMoWFeP3gOeo5OkTZrjWnQVFvaynkuaJrtd26YmLdh_b2W9CA-Gx_tmBh5C9xQeKYB8igAsVwAZUAEXKKEpF4SlqbpECVAJBHKurtFNjCdYvBA0Qbt90H1sxsb3uLOjbrHx3dDab9z09WRsjTsfhqNv_WHG5qj7g10SrHu8fi7IGJqq9eZzWRp8O3c23KIrp9to7_7mCn28vuyLN7Ldbd6L9ZYYJvhIUi65y5XhykgQXDtqFtmcVrVJpatdpriujIBaKU0zcDW3TGZOOEYZSMdX6OF8dwj-a7JxLE9-Cv3ysmSKylxIyfhCkTNlgo8xWFcOoel0mEsK5W9n5b_O-A-B-F6p</recordid><startdate>19970901</startdate><enddate>19970901</enddate><creator>Bronstein, L.</creator><creator>Seregina, M.</creator><creator>Valetsky, P.</creator><creator>Breiner, U.</creator><creator>Abetz, V.</creator><creator>Stadler, R.</creator><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>19970901</creationdate><title>Transition metal complex induced morphology change in an ABC-triblock copolymer</title><author>Bronstein, L. ; Seregina, M. ; Valetsky, P. ; Breiner, U. ; Abetz, V. ; Stadler, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c263t-4373f89c39c7063af1cf1ce81bdc47fdf593abc60d99a150fd3e275f6f21207f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Block copolymers</topic><topic>Coordination compounds</topic><topic>Iron</topic><topic>Morphology</topic><topic>Palladium</topic><topic>Polybutadiene</topic><topic>Polymethyl methacrylate</topic><topic>Polystyrene resins</topic><topic>Transition metal compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bronstein, L.</creatorcontrib><creatorcontrib>Seregina, M.</creatorcontrib><creatorcontrib>Valetsky, P.</creatorcontrib><creatorcontrib>Breiner, U.</creatorcontrib><creatorcontrib>Abetz, V.</creatorcontrib><creatorcontrib>Stadler, R.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bronstein, L.</au><au>Seregina, M.</au><au>Valetsky, P.</au><au>Breiner, U.</au><au>Abetz, V.</au><au>Stadler, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transition metal complex induced morphology change in an ABC-triblock copolymer</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>1997-09-01</date><risdate>1997</risdate><volume>39</volume><issue>3</issue><spage>361</spage><epage>368</epage><pages>361-368</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>SummaryThe short 1,2-polybutadiene center block of the ternary polystyrene-block-polybuta-diene-block-poly(methyl methacrylate) S45B6M49225 -triblock copolymer (subscripts indicating the weight fractions and the superscript indicating the total molecular weight in kg/mol) has been selectively modified by complexation with metal complexes of two different transition metals, namely Pd and Fe. These modifications cause significant variations in the microphase morphology. The original ls-morphology (spheres at lamellar interphase) belonging to the lamellar class changes via a cocontinuous morphology in the case of the Pd-complex to a morphology belonging to the cylindrical class for the Fe-complex.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/s002890050160</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 1997-09, Vol.39 (3), p.361-368 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| source | SpringerNature Journals; ProQuest Central UK/Ireland; ProQuest Central |
| subjects | Block copolymers Coordination compounds Iron Morphology Palladium Polybutadiene Polymethyl methacrylate Polystyrene resins Transition metal compounds |
| title | Transition metal complex induced morphology change in an ABC-triblock copolymer |
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