Synthesis of poly(N, N-dimethylcarbamoylmethylene) as a polymer homolog of N, N-dimethylacetamide

SummaryA novel polymer homolog of N,N-dimethylacetamide (DMAc) having amide groups on all main chain carbons, poly(N,N-dimethylcarbamoylmethylene) 1, was prepared by heating poly(di-t-butyl fumarate) 2 at 180 °C for 2 hours followed by treatment with hexamethylphosphoramide at 180 °C for 5 hours. Th...

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