Novel blends of alternating propene-carbon monoxide copolymers and styrenic copolymers
SummaryAlternating propene-carbon monoxide copolymers (P-CO) were melt-blended with polystyrene, poly(styrene-co-acrylonitrile) (SAN), and with poly(styrene-co-maleic anhydride) (SMA). P-CO forms homogeneously miscible blends with SAN containing 25 wt% AN at the investigated blend compositions. The...
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| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 1999-05, Vol.42 (5), p.611-618 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | DE VOS, S. C HUHN, W RIEGER, B MÖLLER, M |
| description | SummaryAlternating propene-carbon monoxide copolymers (P-CO) were melt-blended with polystyrene, poly(styrene-co-acrylonitrile) (SAN), and with poly(styrene-co-maleic anhydride) (SMA). P-CO forms homogeneously miscible blends with SAN containing 25 wt% AN at the investigated blend compositions. The transparent blends have single, intermediate glass transition temperatures that fit the Fox equation. The elastic properties of P-CO at room temperature disappear upon blending with SAN because the Tg is driven above RT. Polystyrene and SMA are not miscible with P-CO and form heterogeneous blends with two glass transitions. This demonstrates that both the polarity of the styrenic copolymer and the nature of the comonomer govern its phase behavior. |
| doi_str_mv | 10.1007/s002890050509 |
| format | Article |
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C ; HUHN, W ; RIEGER, B ; MÖLLER, M</creator><creatorcontrib>DE VOS, S. C ; HUHN, W ; RIEGER, B ; MÖLLER, M</creatorcontrib><description>SummaryAlternating propene-carbon monoxide copolymers (P-CO) were melt-blended with polystyrene, poly(styrene-co-acrylonitrile) (SAN), and with poly(styrene-co-maleic anhydride) (SMA). P-CO forms homogeneously miscible blends with SAN containing 25 wt% AN at the investigated blend compositions. The transparent blends have single, intermediate glass transition temperatures that fit the Fox equation. The elastic properties of P-CO at room temperature disappear upon blending with SAN because the Tg is driven above RT. Polystyrene and SMA are not miscible with P-CO and form heterogeneous blends with two glass transitions. This demonstrates that both the polarity of the styrenic copolymer and the nature of the comonomer govern its phase behavior.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s002890050509</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Applied sciences ; Carbon monoxide ; Copolymers ; Elastic properties ; Exact sciences and technology ; Glass transition temperature ; Maleic anhydride ; Mechanical properties ; Miscibility ; Organic polymers ; Physicochemistry of polymers ; Polymer blends ; Polystyrene resins ; Properties and characterization ; Room temperature ; Styrene acrylonitrile resins ; Styrenes</subject><ispartof>Polymer bulletin (Berlin, Germany), 1999-05, Vol.42 (5), p.611-618</ispartof><rights>1999 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 1999.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c294t-a8bfe64cf2d9163a5bb32269cc1cde3ed4d956b65ac4638c6062b71dedc74b2e3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2917858031?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21387,27923,27924,33743,43804,64384,64388,72240</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1863461$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>DE VOS, S. C</creatorcontrib><creatorcontrib>HUHN, W</creatorcontrib><creatorcontrib>RIEGER, B</creatorcontrib><creatorcontrib>MÖLLER, M</creatorcontrib><title>Novel blends of alternating propene-carbon monoxide copolymers and styrenic copolymers</title><title>Polymer bulletin (Berlin, Germany)</title><description>SummaryAlternating propene-carbon monoxide copolymers (P-CO) were melt-blended with polystyrene, poly(styrene-co-acrylonitrile) (SAN), and with poly(styrene-co-maleic anhydride) (SMA). P-CO forms homogeneously miscible blends with SAN containing 25 wt% AN at the investigated blend compositions. The transparent blends have single, intermediate glass transition temperatures that fit the Fox equation. The elastic properties of P-CO at room temperature disappear upon blending with SAN because the Tg is driven above RT. Polystyrene and SMA are not miscible with P-CO and form heterogeneous blends with two glass transitions. This demonstrates that both the polarity of the styrenic copolymer and the nature of the comonomer govern its phase behavior.</description><subject>Applied sciences</subject><subject>Carbon monoxide</subject><subject>Copolymers</subject><subject>Elastic properties</subject><subject>Exact sciences and technology</subject><subject>Glass transition temperature</subject><subject>Maleic anhydride</subject><subject>Mechanical properties</subject><subject>Miscibility</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer blends</subject><subject>Polystyrene resins</subject><subject>Properties and characterization</subject><subject>Room temperature</subject><subject>Styrene acrylonitrile resins</subject><subject>Styrenes</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpVkEtLAzEUhYMoWKtL9wHdRvOazGQpxRcU3ajbIY87MiVNxmQq9t870oLKXVzu4buHw0HonNErRml9XSjljaa0mkYfoBmTQhEupT5EM8pqSmgj9DE6KWVFp1spNkNvT-kTArYBoi84ddiEEXI0Yx_f8ZDTABGIM9mmiNcppq_eA3ZpSGG7hlywiR6XcZsh9u6PfoqOOhMKnO33HL3e3b4sHsjy-f5xcbMkjms5EtPYDpR0HfeaKWEqawXnSjvHnAcBXnpdKasq46QSjVNUcVszD97V0nIQc3Sx852ifmygjO0qbab4obRcs7qpGirYRJEd5XIqJUPXDrlfm7xtGW1_qmv_VTfxl3tXU5wJXTbR9eX3qVFCKia-Aa6Qb1A</recordid><startdate>19990501</startdate><enddate>19990501</enddate><creator>DE VOS, S. C</creator><creator>HUHN, W</creator><creator>RIEGER, B</creator><creator>MÖLLER, M</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>19990501</creationdate><title>Novel blends of alternating propene-carbon monoxide copolymers and styrenic copolymers</title><author>DE VOS, S. C ; HUHN, W ; RIEGER, B ; MÖLLER, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c294t-a8bfe64cf2d9163a5bb32269cc1cde3ed4d956b65ac4638c6062b71dedc74b2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Applied sciences</topic><topic>Carbon monoxide</topic><topic>Copolymers</topic><topic>Elastic properties</topic><topic>Exact sciences and technology</topic><topic>Glass transition temperature</topic><topic>Maleic anhydride</topic><topic>Mechanical properties</topic><topic>Miscibility</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymer blends</topic><topic>Polystyrene resins</topic><topic>Properties and characterization</topic><topic>Room temperature</topic><topic>Styrene acrylonitrile resins</topic><topic>Styrenes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>DE VOS, S. C</creatorcontrib><creatorcontrib>HUHN, W</creatorcontrib><creatorcontrib>RIEGER, B</creatorcontrib><creatorcontrib>MÖLLER, M</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>DE VOS, S. C</au><au>HUHN, W</au><au>RIEGER, B</au><au>MÖLLER, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel blends of alternating propene-carbon monoxide copolymers and styrenic copolymers</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>1999-05-01</date><risdate>1999</risdate><volume>42</volume><issue>5</issue><spage>611</spage><epage>618</epage><pages>611-618</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>SummaryAlternating propene-carbon monoxide copolymers (P-CO) were melt-blended with polystyrene, poly(styrene-co-acrylonitrile) (SAN), and with poly(styrene-co-maleic anhydride) (SMA). P-CO forms homogeneously miscible blends with SAN containing 25 wt% AN at the investigated blend compositions. The transparent blends have single, intermediate glass transition temperatures that fit the Fox equation. The elastic properties of P-CO at room temperature disappear upon blending with SAN because the Tg is driven above RT. Polystyrene and SMA are not miscible with P-CO and form heterogeneous blends with two glass transitions. This demonstrates that both the polarity of the styrenic copolymer and the nature of the comonomer govern its phase behavior.</abstract><cop>Heidelberg</cop><cop>Berlin</cop><cop>New York, NY</cop><pub>Springer</pub><doi>10.1007/s002890050509</doi><tpages>8</tpages></addata></record> |
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| ispartof | Polymer bulletin (Berlin, Germany), 1999-05, Vol.42 (5), p.611-618 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| source | ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Applied sciences Carbon monoxide Copolymers Elastic properties Exact sciences and technology Glass transition temperature Maleic anhydride Mechanical properties Miscibility Organic polymers Physicochemistry of polymers Polymer blends Polystyrene resins Properties and characterization Room temperature Styrene acrylonitrile resins Styrenes |
| title | Novel blends of alternating propene-carbon monoxide copolymers and styrenic copolymers |
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