Swelling studies of super water retainer acrylamide/crotonic acid hydrogels crosslinked by trimethylolpropane triacrylate and 1,4-butanediol dimethacrylate
SummarySuperswelling acrylamide/crotonic acid (AAm/CA) hydrogels were prepared by free radical polymerization in aqueous solution of acrylamide (AAm) with crotonic acid (CA) as comonomer. For each copolymerization, four different composition of CA and a concentration of multifunctional crosslinkers...
Gespeichert in:
| Veröffentlicht in: | Polymer bulletin (Berlin, Germany) Germany), 2002-05, Vol.48 (3), p.299-307 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 307 |
|---|---|
| container_issue | 3 |
| container_start_page | 299 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 48 |
| creator | KARADAG, Erdener SARAYDM, Dursun |
| description | SummarySuperswelling acrylamide/crotonic acid (AAm/CA) hydrogels were prepared by free radical polymerization in aqueous solution of acrylamide (AAm) with crotonic acid (CA) as comonomer. For each copolymerization, four different composition of CA and a concentration of multifunctional crosslinkers such as trimethylolpropane triacrylate (TMPTA) and 1,4-butanediol dimethacrylate (BDMA) were used. As a result of dynamic swelling tests, the influence of the crosslinkers and the relative content of CA on the swelling properties were examined. AAm/CA hydrogels were swelled in the range of 1520–2980% in water, while AAm hydrogels swelled as 780 and 1360%. Equilibrium water content of AAm/CA hydrogels was calculated in the range of 88.73 and 96.75%. Water uptake of hydrogels was followed non-Fickian type diffusion. |
| doi_str_mv | 10.1007/s00289-002-0029-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2917857950</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2917857950</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-c68955482f71a2e28db3be44c46304cb157345a734160b09b21da2db019f6cb83</originalsourceid><addsrcrecordid>eNpFUctOwzAQtBBIlMIHcLOEuBFqx05iH1HFS6rEAThHfqV1cZNiO6ryLfwsTlvEYcfe8ex4VwvANUb3GKFqFhDKGc8SjsEzdgImmJIyyynlp2CCcIUyxAg_BxchrFHKyxJPwM_7zjhn2yUMsdfWBNg1MPRb4-FOxITeRGHbdBHKD05srDYz5bvYtVYlzmq4GrTvlsYFmPgQktmX0VAOMHq7MXE1uM5tfbcVrRmpg080ULQa4juayT6mJ207B_W-4E9xCc4a4YK5Op5T8Pn0-DF_yRZvz6_zh0WmSFnFTJWMFwVleVNhkZucaUmkoVTRkiCqJC4qQguRAJdIIi5zrEWuJcK8KZVkZApuDr6py-_ehFivu9636cs657hiRcULlFT4oNpP6U1Tb9N8wg81RvW4g_qwgzrhGLwenW-PziIo4RovWmXDfyFhBeOck18aE4qP</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2917857950</pqid></control><display><type>article</type><title>Swelling studies of super water retainer acrylamide/crotonic acid hydrogels crosslinked by trimethylolpropane triacrylate and 1,4-butanediol dimethacrylate</title><source>SpringerNature Journals</source><source>ProQuest Central UK/Ireland</source><source>ProQuest Central</source><creator>KARADAG, Erdener ; SARAYDM, Dursun</creator><creatorcontrib>KARADAG, Erdener ; SARAYDM, Dursun</creatorcontrib><description>SummarySuperswelling acrylamide/crotonic acid (AAm/CA) hydrogels were prepared by free radical polymerization in aqueous solution of acrylamide (AAm) with crotonic acid (CA) as comonomer. For each copolymerization, four different composition of CA and a concentration of multifunctional crosslinkers such as trimethylolpropane triacrylate (TMPTA) and 1,4-butanediol dimethacrylate (BDMA) were used. As a result of dynamic swelling tests, the influence of the crosslinkers and the relative content of CA on the swelling properties were examined. AAm/CA hydrogels were swelled in the range of 1520–2980% in water, while AAm hydrogels swelled as 780 and 1360%. Equilibrium water content of AAm/CA hydrogels was calculated in the range of 88.73 and 96.75%. Water uptake of hydrogels was followed non-Fickian type diffusion.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-002-0029-8</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Acrylamide ; Applied sciences ; Aqueous solutions ; Butanediol ; Copolymerization ; Crosslinking ; Exact sciences and technology ; Free radical polymerization ; Free radicals ; Hydrogels ; Moisture content ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Solution and gel properties ; Swelling</subject><ispartof>Polymer bulletin (Berlin, Germany), 2002-05, Vol.48 (3), p.299-307</ispartof><rights>2002 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2002.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-c68955482f71a2e28db3be44c46304cb157345a734160b09b21da2db019f6cb83</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2917857950?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,43805,64385,64389,72469</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=13858999$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>KARADAG, Erdener</creatorcontrib><creatorcontrib>SARAYDM, Dursun</creatorcontrib><title>Swelling studies of super water retainer acrylamide/crotonic acid hydrogels crosslinked by trimethylolpropane triacrylate and 1,4-butanediol dimethacrylate</title><title>Polymer bulletin (Berlin, Germany)</title><description>SummarySuperswelling acrylamide/crotonic acid (AAm/CA) hydrogels were prepared by free radical polymerization in aqueous solution of acrylamide (AAm) with crotonic acid (CA) as comonomer. For each copolymerization, four different composition of CA and a concentration of multifunctional crosslinkers such as trimethylolpropane triacrylate (TMPTA) and 1,4-butanediol dimethacrylate (BDMA) were used. As a result of dynamic swelling tests, the influence of the crosslinkers and the relative content of CA on the swelling properties were examined. AAm/CA hydrogels were swelled in the range of 1520–2980% in water, while AAm hydrogels swelled as 780 and 1360%. Equilibrium water content of AAm/CA hydrogels was calculated in the range of 88.73 and 96.75%. Water uptake of hydrogels was followed non-Fickian type diffusion.</description><subject>Acrylamide</subject><subject>Applied sciences</subject><subject>Aqueous solutions</subject><subject>Butanediol</subject><subject>Copolymerization</subject><subject>Crosslinking</subject><subject>Exact sciences and technology</subject><subject>Free radical polymerization</subject><subject>Free radicals</subject><subject>Hydrogels</subject><subject>Moisture content</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Solution and gel properties</subject><subject>Swelling</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpFUctOwzAQtBBIlMIHcLOEuBFqx05iH1HFS6rEAThHfqV1cZNiO6ryLfwsTlvEYcfe8ex4VwvANUb3GKFqFhDKGc8SjsEzdgImmJIyyynlp2CCcIUyxAg_BxchrFHKyxJPwM_7zjhn2yUMsdfWBNg1MPRb4-FOxITeRGHbdBHKD05srDYz5bvYtVYlzmq4GrTvlsYFmPgQktmX0VAOMHq7MXE1uM5tfbcVrRmpg080ULQa4juayT6mJ207B_W-4E9xCc4a4YK5Op5T8Pn0-DF_yRZvz6_zh0WmSFnFTJWMFwVleVNhkZucaUmkoVTRkiCqJC4qQguRAJdIIi5zrEWuJcK8KZVkZApuDr6py-_ehFivu9636cs657hiRcULlFT4oNpP6U1Tb9N8wg81RvW4g_qwgzrhGLwenW-PziIo4RovWmXDfyFhBeOck18aE4qP</recordid><startdate>20020501</startdate><enddate>20020501</enddate><creator>KARADAG, Erdener</creator><creator>SARAYDM, Dursun</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20020501</creationdate><title>Swelling studies of super water retainer acrylamide/crotonic acid hydrogels crosslinked by trimethylolpropane triacrylate and 1,4-butanediol dimethacrylate</title><author>KARADAG, Erdener ; SARAYDM, Dursun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-c68955482f71a2e28db3be44c46304cb157345a734160b09b21da2db019f6cb83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Acrylamide</topic><topic>Applied sciences</topic><topic>Aqueous solutions</topic><topic>Butanediol</topic><topic>Copolymerization</topic><topic>Crosslinking</topic><topic>Exact sciences and technology</topic><topic>Free radical polymerization</topic><topic>Free radicals</topic><topic>Hydrogels</topic><topic>Moisture content</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Solution and gel properties</topic><topic>Swelling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KARADAG, Erdener</creatorcontrib><creatorcontrib>SARAYDM, Dursun</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KARADAG, Erdener</au><au>SARAYDM, Dursun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Swelling studies of super water retainer acrylamide/crotonic acid hydrogels crosslinked by trimethylolpropane triacrylate and 1,4-butanediol dimethacrylate</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>2002-05-01</date><risdate>2002</risdate><volume>48</volume><issue>3</issue><spage>299</spage><epage>307</epage><pages>299-307</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>SummarySuperswelling acrylamide/crotonic acid (AAm/CA) hydrogels were prepared by free radical polymerization in aqueous solution of acrylamide (AAm) with crotonic acid (CA) as comonomer. For each copolymerization, four different composition of CA and a concentration of multifunctional crosslinkers such as trimethylolpropane triacrylate (TMPTA) and 1,4-butanediol dimethacrylate (BDMA) were used. As a result of dynamic swelling tests, the influence of the crosslinkers and the relative content of CA on the swelling properties were examined. AAm/CA hydrogels were swelled in the range of 1520–2980% in water, while AAm hydrogels swelled as 780 and 1360%. Equilibrium water content of AAm/CA hydrogels was calculated in the range of 88.73 and 96.75%. Water uptake of hydrogels was followed non-Fickian type diffusion.</abstract><cop>Heidelberg</cop><cop>Berlin</cop><cop>New York, NY</cop><pub>Springer</pub><doi>10.1007/s00289-002-0029-8</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2002-05, Vol.48 (3), p.299-307 |
| issn | 0170-0839 1436-2449 |
| language | eng |
| recordid | cdi_proquest_journals_2917857950 |
| source | SpringerNature Journals; ProQuest Central UK/Ireland; ProQuest Central |
| subjects | Acrylamide Applied sciences Aqueous solutions Butanediol Copolymerization Crosslinking Exact sciences and technology Free radical polymerization Free radicals Hydrogels Moisture content Organic polymers Physicochemistry of polymers Properties and characterization Solution and gel properties Swelling |
| title | Swelling studies of super water retainer acrylamide/crotonic acid hydrogels crosslinked by trimethylolpropane triacrylate and 1,4-butanediol dimethacrylate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T07%3A26%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Swelling%20studies%20of%20super%20water%20retainer%20acrylamide/crotonic%20acid%20hydrogels%20crosslinked%20by%20trimethylolpropane%20triacrylate%20and%201,4-butanediol%20dimethacrylate&rft.jtitle=Polymer%20bulletin%20(Berlin,%20Germany)&rft.au=KARADAG,%20Erdener&rft.date=2002-05-01&rft.volume=48&rft.issue=3&rft.spage=299&rft.epage=307&rft.pages=299-307&rft.issn=0170-0839&rft.eissn=1436-2449&rft.coden=POBUDR&rft_id=info:doi/10.1007/s00289-002-0029-8&rft_dat=%3Cproquest_cross%3E2917857950%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2917857950&rft_id=info:pmid/&rfr_iscdi=true |