Wet-Type Packed-Bed Nonthermal Plasma for Simultaneous Removal of PM and VOCs
Several regulations on exhaust gases have been introduced to curb hazardous exhaust of volatile organic compounds (VOCs) and particulate matter (PM) from the paint and printing industries. VOCs produce photochemical oxidants and suspended PM such as PM 2.5 , which is now recognized as a global envir...
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Veröffentlicht in: | Plasma chemistry and plasma processing 2024, Vol.44 (1), p.239-255 |
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creator | Shimada, Takumi Yamasaki, Haruhiko Kuroki, Tomoyuki Kang, Jinkyu Kim, Dong-Wook Yagi, Tadao Okubo, Masaaki |
description | Several regulations on exhaust gases have been introduced to curb hazardous exhaust of volatile organic compounds (VOCs) and particulate matter (PM) from the paint and printing industries. VOCs produce photochemical oxidants and suspended PM such as PM
2.5
, which is now recognized as a global environmental problem. We assess a nonthermal plasma technique for controlling VOC emissions, especially, propose a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. This paper proposes a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. The proposed technique is evaluated through the simultaneous removal of nanoparticles and toluene at a relatively high flow rate. Simultaneous treatment of the VOCs and nanoparticles using the reactor indicates that the average particle collection efficiency is 94%, and the removal efficiency of 60 ppm toluene is 73% with a gas flow rate of 10 L/min. The resultant byproducts are benzaldehyde (C
6
H
5
CHO), benzyl alcohol (C
6
H
5
CH
2
OH), phenol (C
6
H
5
OH), ozone, formic acid, and acetic acid, and some are easily dissolved and removed by the sodium hydroxide solution film. A smaller pellet diameter leads to more efficient toluene removal at lower specific energy values, while the ozone concentration does not change. However, the ozone concentration can be greatly suppressed by dissolving the ozone in the alkali solution film. |
doi_str_mv | 10.1007/s11090-023-10403-1 |
format | Article |
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2.5
, which is now recognized as a global environmental problem. We assess a nonthermal plasma technique for controlling VOC emissions, especially, propose a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. This paper proposes a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. The proposed technique is evaluated through the simultaneous removal of nanoparticles and toluene at a relatively high flow rate. Simultaneous treatment of the VOCs and nanoparticles using the reactor indicates that the average particle collection efficiency is 94%, and the removal efficiency of 60 ppm toluene is 73% with a gas flow rate of 10 L/min. The resultant byproducts are benzaldehyde (C
6
H
5
CHO), benzyl alcohol (C
6
H
5
CH
2
OH), phenol (C
6
H
5
OH), ozone, formic acid, and acetic acid, and some are easily dissolved and removed by the sodium hydroxide solution film. A smaller pellet diameter leads to more efficient toluene removal at lower specific energy values, while the ozone concentration does not change. However, the ozone concentration can be greatly suppressed by dissolving the ozone in the alkali solution film.</description><identifier>ISSN: 0272-4324</identifier><identifier>EISSN: 1572-8986</identifier><identifier>DOI: 10.1007/s11090-023-10403-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acetic acid ; Benzaldehyde ; Benzyl alcohol ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Classical Mechanics ; Energy value ; Exhaust gases ; Flow velocity ; Formic acid ; Gas flow ; Inorganic Chemistry ; Mechanical Engineering ; Nanoparticles ; Original Paper ; Oxidizing agents ; Ozone ; Particulate emissions ; Photochemical oxidants ; Plasma ; Sodium hydroxide ; Specific energy ; Toluene ; VOCs ; Volatile organic compounds</subject><ispartof>Plasma chemistry and plasma processing, 2024, Vol.44 (1), p.239-255</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-d0fe934b7d591cd812f9ad132cd067f49142bcfa76d5e06157a5ed0e47b527673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11090-023-10403-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11090-023-10403-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Shimada, Takumi</creatorcontrib><creatorcontrib>Yamasaki, Haruhiko</creatorcontrib><creatorcontrib>Kuroki, Tomoyuki</creatorcontrib><creatorcontrib>Kang, Jinkyu</creatorcontrib><creatorcontrib>Kim, Dong-Wook</creatorcontrib><creatorcontrib>Yagi, Tadao</creatorcontrib><creatorcontrib>Okubo, Masaaki</creatorcontrib><title>Wet-Type Packed-Bed Nonthermal Plasma for Simultaneous Removal of PM and VOCs</title><title>Plasma chemistry and plasma processing</title><addtitle>Plasma Chem Plasma Process</addtitle><description>Several regulations on exhaust gases have been introduced to curb hazardous exhaust of volatile organic compounds (VOCs) and particulate matter (PM) from the paint and printing industries. VOCs produce photochemical oxidants and suspended PM such as PM
2.5
, which is now recognized as a global environmental problem. We assess a nonthermal plasma technique for controlling VOC emissions, especially, propose a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. This paper proposes a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. The proposed technique is evaluated through the simultaneous removal of nanoparticles and toluene at a relatively high flow rate. Simultaneous treatment of the VOCs and nanoparticles using the reactor indicates that the average particle collection efficiency is 94%, and the removal efficiency of 60 ppm toluene is 73% with a gas flow rate of 10 L/min. The resultant byproducts are benzaldehyde (C
6
H
5
CHO), benzyl alcohol (C
6
H
5
CH
2
OH), phenol (C
6
H
5
OH), ozone, formic acid, and acetic acid, and some are easily dissolved and removed by the sodium hydroxide solution film. A smaller pellet diameter leads to more efficient toluene removal at lower specific energy values, while the ozone concentration does not change. However, the ozone concentration can be greatly suppressed by dissolving the ozone in the alkali solution film.</description><subject>Acetic acid</subject><subject>Benzaldehyde</subject><subject>Benzyl alcohol</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Energy value</subject><subject>Exhaust gases</subject><subject>Flow velocity</subject><subject>Formic acid</subject><subject>Gas flow</subject><subject>Inorganic Chemistry</subject><subject>Mechanical Engineering</subject><subject>Nanoparticles</subject><subject>Original Paper</subject><subject>Oxidizing agents</subject><subject>Ozone</subject><subject>Particulate emissions</subject><subject>Photochemical oxidants</subject><subject>Plasma</subject><subject>Sodium hydroxide</subject><subject>Specific energy</subject><subject>Toluene</subject><subject>VOCs</subject><subject>Volatile organic compounds</subject><issn>0272-4324</issn><issn>1572-8986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLAzEQhYMoWKt_wFPAc3SS7G6aoxatQmuLVj2GdJNo6-6mJrtC_73RFbx5mRmY971hHkKnFM4pgLiIlIIEAowTChmkuocGNBeMjOSo2EcDYGnOOMsO0VGMG4CEcTFAsxfbkuVua_FCl-_WkCtr8L1v2jcbal3hRaVjrbHzAT-u665qdWN9F_GDrf1n2nuHFzOsG4Of5-N4jA6crqI9-e1D9HRzvRzfkul8cje-nJKSCWiJAWclz1bC5JKWZkSZk9pQzkoDhXCZpBlblU6LwuQWivSHzq0Bm4lVzkQh-BCd9b7b4D86G1u18V1o0knFJC2ASyZkUrFeVQYfY7BObcO61mGnKKjv2FQfm0qxqZ_YFE0Q76GYxM2rDX_W_1BfvYJuEg</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Shimada, Takumi</creator><creator>Yamasaki, Haruhiko</creator><creator>Kuroki, Tomoyuki</creator><creator>Kang, Jinkyu</creator><creator>Kim, Dong-Wook</creator><creator>Yagi, Tadao</creator><creator>Okubo, Masaaki</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2024</creationdate><title>Wet-Type Packed-Bed Nonthermal Plasma for Simultaneous Removal of PM and VOCs</title><author>Shimada, Takumi ; Yamasaki, Haruhiko ; Kuroki, Tomoyuki ; Kang, Jinkyu ; Kim, Dong-Wook ; Yagi, Tadao ; Okubo, Masaaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-d0fe934b7d591cd812f9ad132cd067f49142bcfa76d5e06157a5ed0e47b527673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Acetic acid</topic><topic>Benzaldehyde</topic><topic>Benzyl alcohol</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Energy value</topic><topic>Exhaust gases</topic><topic>Flow velocity</topic><topic>Formic acid</topic><topic>Gas flow</topic><topic>Inorganic Chemistry</topic><topic>Mechanical Engineering</topic><topic>Nanoparticles</topic><topic>Original Paper</topic><topic>Oxidizing agents</topic><topic>Ozone</topic><topic>Particulate emissions</topic><topic>Photochemical oxidants</topic><topic>Plasma</topic><topic>Sodium hydroxide</topic><topic>Specific energy</topic><topic>Toluene</topic><topic>VOCs</topic><topic>Volatile organic compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shimada, Takumi</creatorcontrib><creatorcontrib>Yamasaki, Haruhiko</creatorcontrib><creatorcontrib>Kuroki, Tomoyuki</creatorcontrib><creatorcontrib>Kang, Jinkyu</creatorcontrib><creatorcontrib>Kim, Dong-Wook</creatorcontrib><creatorcontrib>Yagi, Tadao</creatorcontrib><creatorcontrib>Okubo, Masaaki</creatorcontrib><collection>CrossRef</collection><jtitle>Plasma chemistry and plasma processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shimada, Takumi</au><au>Yamasaki, Haruhiko</au><au>Kuroki, Tomoyuki</au><au>Kang, Jinkyu</au><au>Kim, Dong-Wook</au><au>Yagi, Tadao</au><au>Okubo, Masaaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Wet-Type Packed-Bed Nonthermal Plasma for Simultaneous Removal of PM and VOCs</atitle><jtitle>Plasma chemistry and plasma processing</jtitle><stitle>Plasma Chem Plasma Process</stitle><date>2024</date><risdate>2024</risdate><volume>44</volume><issue>1</issue><spage>239</spage><epage>255</epage><pages>239-255</pages><issn>0272-4324</issn><eissn>1572-8986</eissn><abstract>Several regulations on exhaust gases have been introduced to curb hazardous exhaust of volatile organic compounds (VOCs) and particulate matter (PM) from the paint and printing industries. VOCs produce photochemical oxidants and suspended PM such as PM
2.5
, which is now recognized as a global environmental problem. We assess a nonthermal plasma technique for controlling VOC emissions, especially, propose a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. This paper proposes a wet-type packed-bed plasma reactor to extend the treatment of water-non-soluble VOCs. The proposed technique is evaluated through the simultaneous removal of nanoparticles and toluene at a relatively high flow rate. Simultaneous treatment of the VOCs and nanoparticles using the reactor indicates that the average particle collection efficiency is 94%, and the removal efficiency of 60 ppm toluene is 73% with a gas flow rate of 10 L/min. The resultant byproducts are benzaldehyde (C
6
H
5
CHO), benzyl alcohol (C
6
H
5
CH
2
OH), phenol (C
6
H
5
OH), ozone, formic acid, and acetic acid, and some are easily dissolved and removed by the sodium hydroxide solution film. A smaller pellet diameter leads to more efficient toluene removal at lower specific energy values, while the ozone concentration does not change. However, the ozone concentration can be greatly suppressed by dissolving the ozone in the alkali solution film.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11090-023-10403-1</doi><tpages>17</tpages></addata></record> |
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subjects | Acetic acid Benzaldehyde Benzyl alcohol Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Classical Mechanics Energy value Exhaust gases Flow velocity Formic acid Gas flow Inorganic Chemistry Mechanical Engineering Nanoparticles Original Paper Oxidizing agents Ozone Particulate emissions Photochemical oxidants Plasma Sodium hydroxide Specific energy Toluene VOCs Volatile organic compounds |
title | Wet-Type Packed-Bed Nonthermal Plasma for Simultaneous Removal of PM and VOCs |
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