Graphene-strengthened ternary Sn-based sulfide as advanced lithium storage material
Ternary Sn-based sulfide materials are generally considered as potential candidate anode for next-generation lithium-ion batteries (LIBs) owing to their high capacity and superior ion/electrical conductivity. In the work, we successfully prepared the multiphase Cu 4 SnS 4 /CuS/SnS (CTS) nanoparticle...
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| Veröffentlicht in: | Journal of materials science 2024, Vol.59 (1), p.206-214 |
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| creator | Deng, Chao Xu, Jie Cen, Changqun Yang, Meijun Deng, Yiheng Yang, Chunliang Zhi, Qing Fu, Lin |
| description | Ternary Sn-based sulfide materials are generally considered as potential candidate anode for next-generation lithium-ion batteries (LIBs) owing to their high capacity and superior ion/electrical conductivity. In the work, we successfully prepared the multiphase Cu
4
SnS
4
/CuS/SnS (CTS) nanoparticles uniformly anchored in the reduced graphene oxide (RGO) sheets (CTS/RGO). The CTS/RGO composite exhibits superior cycling stability with negligible capacity decay under a current density of 200 mA g
−1
as well as favorable rate capability compared with that of bare CTS particles. The improved electrochemical performance can be attributed to the existence of RGO as a buffer to restrain the huge volume variation during the charge/discharge processes, enhancing the conductivity and diffusion kinetics of Li
+
in the composite. This work highlights the strengthening effect of RGO for the Li storage properties of Sn-based sulfides, which is beneficial to guide these composites with good electrochemical performances. |
| doi_str_mv | 10.1007/s10853-023-09189-6 |
| format | Article |
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4
SnS
4
/CuS/SnS (CTS) nanoparticles uniformly anchored in the reduced graphene oxide (RGO) sheets (CTS/RGO). The CTS/RGO composite exhibits superior cycling stability with negligible capacity decay under a current density of 200 mA g
−1
as well as favorable rate capability compared with that of bare CTS particles. The improved electrochemical performance can be attributed to the existence of RGO as a buffer to restrain the huge volume variation during the charge/discharge processes, enhancing the conductivity and diffusion kinetics of Li
+
in the composite. This work highlights the strengthening effect of RGO for the Li storage properties of Sn-based sulfides, which is beneficial to guide these composites with good electrochemical performances.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-023-09189-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Batteries ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Copper sulfides ; Crystallography and Scattering Methods ; Electric properties ; Electrical resistivity ; Electrochemical analysis ; Energy Materials ; Graphene ; Graphite ; Lithium-ion batteries ; Materials Science ; Polymer Sciences ; Rechargeable batteries ; Solid Mechanics ; Sulfides ; Tetracycline ; Tetracyclines</subject><ispartof>Journal of materials science, 2024, Vol.59 (1), p.206-214</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2024 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c332t-5d503d0eaa7dc4986747cc7beaaa30a0a7ef63b4cb0ad50f826acc0af5a69a153</cites><orcidid>0000-0001-6834-2881</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-023-09189-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-023-09189-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Deng, Chao</creatorcontrib><creatorcontrib>Xu, Jie</creatorcontrib><creatorcontrib>Cen, Changqun</creatorcontrib><creatorcontrib>Yang, Meijun</creatorcontrib><creatorcontrib>Deng, Yiheng</creatorcontrib><creatorcontrib>Yang, Chunliang</creatorcontrib><creatorcontrib>Zhi, Qing</creatorcontrib><creatorcontrib>Fu, Lin</creatorcontrib><title>Graphene-strengthened ternary Sn-based sulfide as advanced lithium storage material</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Ternary Sn-based sulfide materials are generally considered as potential candidate anode for next-generation lithium-ion batteries (LIBs) owing to their high capacity and superior ion/electrical conductivity. In the work, we successfully prepared the multiphase Cu
4
SnS
4
/CuS/SnS (CTS) nanoparticles uniformly anchored in the reduced graphene oxide (RGO) sheets (CTS/RGO). The CTS/RGO composite exhibits superior cycling stability with negligible capacity decay under a current density of 200 mA g
−1
as well as favorable rate capability compared with that of bare CTS particles. The improved electrochemical performance can be attributed to the existence of RGO as a buffer to restrain the huge volume variation during the charge/discharge processes, enhancing the conductivity and diffusion kinetics of Li
+
in the composite. This work highlights the strengthening effect of RGO for the Li storage properties of Sn-based sulfides, which is beneficial to guide these composites with good electrochemical performances.</description><subject>Batteries</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Copper sulfides</subject><subject>Crystallography and Scattering Methods</subject><subject>Electric properties</subject><subject>Electrical resistivity</subject><subject>Electrochemical analysis</subject><subject>Energy Materials</subject><subject>Graphene</subject><subject>Graphite</subject><subject>Lithium-ion batteries</subject><subject>Materials Science</subject><subject>Polymer Sciences</subject><subject>Rechargeable batteries</subject><subject>Solid Mechanics</subject><subject>Sulfides</subject><subject>Tetracycline</subject><subject>Tetracyclines</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kU9LxDAQxYMouK5-AU8FTx6ik6Rt2uOy-A8EwdVzmE3TWum2ayYV_fZmXWHZi4dhhsfvDcM8xs4FXAkAfU0CikxxkLFKUZQ8P2ATkWnF0wLUIZsASMllmotjdkL0DgCZlmLCFnce12-ud5yCd30TNnOVBOd79N_JoudLpCjQ2NVt5RKkBKtP7G3Uuja8teMqoTB4bFyywmhrsTtlRzV25M7--pS93t68zO_549Pdw3z2yK1SMvCsykBV4BB1ZdOyyHWqrdXLKKACBNSuztUytUvAiNaFzNFawDrDvESRqSm72O5d--FjdBTM-zDGuzsyshQq06XQekc12DnT9vUQPNpVS9bMtC6lFmm-oS73KDv0wX2FBkci87B43mfllrV-IPKuNmvfruK7jACzicNs4zAxDvMbh8mjSW1NFOG-cX537D-uH5J8jPE</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Deng, Chao</creator><creator>Xu, Jie</creator><creator>Cen, Changqun</creator><creator>Yang, Meijun</creator><creator>Deng, Yiheng</creator><creator>Yang, Chunliang</creator><creator>Zhi, Qing</creator><creator>Fu, Lin</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0001-6834-2881</orcidid></search><sort><creationdate>2024</creationdate><title>Graphene-strengthened ternary Sn-based sulfide as advanced lithium storage material</title><author>Deng, Chao ; Xu, Jie ; Cen, Changqun ; Yang, Meijun ; Deng, Yiheng ; Yang, Chunliang ; Zhi, Qing ; Fu, Lin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c332t-5d503d0eaa7dc4986747cc7beaaa30a0a7ef63b4cb0ad50f826acc0af5a69a153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Batteries</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Copper sulfides</topic><topic>Crystallography and Scattering Methods</topic><topic>Electric properties</topic><topic>Electrical resistivity</topic><topic>Electrochemical analysis</topic><topic>Energy Materials</topic><topic>Graphene</topic><topic>Graphite</topic><topic>Lithium-ion batteries</topic><topic>Materials Science</topic><topic>Polymer Sciences</topic><topic>Rechargeable batteries</topic><topic>Solid Mechanics</topic><topic>Sulfides</topic><topic>Tetracycline</topic><topic>Tetracyclines</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deng, Chao</creatorcontrib><creatorcontrib>Xu, Jie</creatorcontrib><creatorcontrib>Cen, Changqun</creatorcontrib><creatorcontrib>Yang, Meijun</creatorcontrib><creatorcontrib>Deng, Yiheng</creatorcontrib><creatorcontrib>Yang, Chunliang</creatorcontrib><creatorcontrib>Zhi, Qing</creatorcontrib><creatorcontrib>Fu, Lin</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deng, Chao</au><au>Xu, Jie</au><au>Cen, Changqun</au><au>Yang, Meijun</au><au>Deng, Yiheng</au><au>Yang, Chunliang</au><au>Zhi, Qing</au><au>Fu, Lin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graphene-strengthened ternary Sn-based sulfide as advanced lithium storage material</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2024</date><risdate>2024</risdate><volume>59</volume><issue>1</issue><spage>206</spage><epage>214</epage><pages>206-214</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Ternary Sn-based sulfide materials are generally considered as potential candidate anode for next-generation lithium-ion batteries (LIBs) owing to their high capacity and superior ion/electrical conductivity. In the work, we successfully prepared the multiphase Cu
4
SnS
4
/CuS/SnS (CTS) nanoparticles uniformly anchored in the reduced graphene oxide (RGO) sheets (CTS/RGO). The CTS/RGO composite exhibits superior cycling stability with negligible capacity decay under a current density of 200 mA g
−1
as well as favorable rate capability compared with that of bare CTS particles. The improved electrochemical performance can be attributed to the existence of RGO as a buffer to restrain the huge volume variation during the charge/discharge processes, enhancing the conductivity and diffusion kinetics of Li
+
in the composite. This work highlights the strengthening effect of RGO for the Li storage properties of Sn-based sulfides, which is beneficial to guide these composites with good electrochemical performances.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-023-09189-6</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-6834-2881</orcidid></addata></record> |
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| subjects | Batteries Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Copper sulfides Crystallography and Scattering Methods Electric properties Electrical resistivity Electrochemical analysis Energy Materials Graphene Graphite Lithium-ion batteries Materials Science Polymer Sciences Rechargeable batteries Solid Mechanics Sulfides Tetracycline Tetracyclines |
| title | Graphene-strengthened ternary Sn-based sulfide as advanced lithium storage material |
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