Prospects for Application of Guanidine-Containing Organomineral Complexes as Biocidal Functional Additives for Waterborne Polymer Materials
The possibility of using organomineral complexes of polyhexamethylene guanidine hydrochloride as a functional additive for a waterborne paint based on polyvinyl acetate has been investigated. Organomineral complexes containing 20 and 30 wt % guanidine polymer have been obtained, with intercalation o...
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| Veröffentlicht in: | Polymer science. Series B 2023, Vol.65 (5), p.681-691 |
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| container_title | Polymer science. Series B |
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| creator | Gerasin, V. A. Zhurina, M. V. Kurenkov, V. V. Mendeleev, D. I. Ochenkov, D. E. Myat, K. K. Htoo |
| description | The possibility of using organomineral complexes of polyhexamethylene guanidine hydrochloride as a functional additive for a waterborne paint based on polyvinyl acetate has been investigated. Organomineral complexes containing 20 and 30 wt % guanidine polymer have been obtained, with intercalation of polyguanidine chains into the interlayer space of montmorillonite being observed. It has been revealed that the stability of the polymer film to water is retained when organomineral complexes are introduced into a polyvinyl acetate dispersion, whereas the water resistance of the film sharply decreases when free polyguanidine is added. There was no significant influence of organomineral complexes on the rheological characteristics of the dispersion and its sedimentation stability. Testing of waterborne paints with various additives has shown that introduction of organomineral complexes into the material prevents the coating from fouling by biofilms of gram-positive bacteria
Staphylococcus aureus
and
Rhodococcus erythropolis
, with the hardness, water resistance, and water-vapor transmission of the coatings being retained at a satisfactory level. |
| doi_str_mv | 10.1134/S1560090423701269 |
| format | Article |
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Staphylococcus aureus
and
Rhodococcus erythropolis
, with the hardness, water resistance, and water-vapor transmission of the coatings being retained at a satisfactory level.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090423701269</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Additives ; Biocides ; Chemistry ; Chemistry and Materials Science ; Composites ; Dispersion ; Gram-positive bacteria ; Guanidine hydrochloride ; Interlayers ; Montmorillonite ; Polymer films ; Polymer Sciences ; Polymers ; Rheological properties ; Rhodococcus ; Stability ; Vapor resistance ; Water hardness ; Water resistance ; Water vapor</subject><ispartof>Polymer science. Series B, 2023, Vol.65 (5), p.681-691</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 1560-0904, Polymer Science, Series B, 2023, Vol. 65, No. 5, pp. 681–691. © Pleiades Publishing, Ltd., 2023. ISSN 1560-0904, Polymer Science, Series B, 2023. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2023, Vol. 65, No. 5, pp. 372–383.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-470d9b8d268a451a22a9e84bc61f3098464eaa2fde2c9c9444e5b7d8b01464423</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1560090423701269$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1560090423701269$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27926,27927,41490,42559,51321</link.rule.ids></links><search><creatorcontrib>Gerasin, V. A.</creatorcontrib><creatorcontrib>Zhurina, M. V.</creatorcontrib><creatorcontrib>Kurenkov, V. V.</creatorcontrib><creatorcontrib>Mendeleev, D. I.</creatorcontrib><creatorcontrib>Ochenkov, D. E.</creatorcontrib><creatorcontrib>Myat, K. K. Htoo</creatorcontrib><title>Prospects for Application of Guanidine-Containing Organomineral Complexes as Biocidal Functional Additives for Waterborne Polymer Materials</title><title>Polymer science. Series B</title><addtitle>Polym. Sci. Ser. B</addtitle><description>The possibility of using organomineral complexes of polyhexamethylene guanidine hydrochloride as a functional additive for a waterborne paint based on polyvinyl acetate has been investigated. Organomineral complexes containing 20 and 30 wt % guanidine polymer have been obtained, with intercalation of polyguanidine chains into the interlayer space of montmorillonite being observed. It has been revealed that the stability of the polymer film to water is retained when organomineral complexes are introduced into a polyvinyl acetate dispersion, whereas the water resistance of the film sharply decreases when free polyguanidine is added. There was no significant influence of organomineral complexes on the rheological characteristics of the dispersion and its sedimentation stability. Testing of waterborne paints with various additives has shown that introduction of organomineral complexes into the material prevents the coating from fouling by biofilms of gram-positive bacteria
Staphylococcus aureus
and
Rhodococcus erythropolis
, with the hardness, water resistance, and water-vapor transmission of the coatings being retained at a satisfactory level.</description><subject>Additives</subject><subject>Biocides</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Dispersion</subject><subject>Gram-positive bacteria</subject><subject>Guanidine hydrochloride</subject><subject>Interlayers</subject><subject>Montmorillonite</subject><subject>Polymer films</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Rheological properties</subject><subject>Rhodococcus</subject><subject>Stability</subject><subject>Vapor resistance</subject><subject>Water hardness</subject><subject>Water resistance</subject><subject>Water vapor</subject><issn>1560-0904</issn><issn>1555-6123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1UF1LwzAUDaLgmPsBvgV8ruarXfM4i5vCxIGKjyVN0pHRJjVpxf0G_7QpFXwQ78u9Ofeck8sB4BKja4wpu3nGaYYQR4zQJcIk4ydghtM0TTJM6Ok4ZygZ9-dgEcIBxaKcYsxn4GvnXei07AOsnYerrmuMFL1xFroabgZhjTJWJ4WzvTDW2D188nthXRtRLxpYuLZr9KcOUAR4a5w0KqLrwcrRJI4rpUxvPvT0wZvota-ctxruXHNstYePI2REEy7AWR2bXvz0OXhd370U98n2afNQrLaJJFneJ2yJFK9yFR-CpVgQIrjOWSUzXFPEc5YxLQSplSaSS84Y02m1VHmFcFzFjObgavLtvHsfdOjLgxt8vDWUhMf4ckRzGll4YsmYUPC6LjtvWuGPJUblGHv5J_aoIZMmRK7da__r_L_oG7Tmhd8</recordid><startdate>2023</startdate><enddate>2023</enddate><creator>Gerasin, V. A.</creator><creator>Zhurina, M. V.</creator><creator>Kurenkov, V. V.</creator><creator>Mendeleev, D. I.</creator><creator>Ochenkov, D. E.</creator><creator>Myat, K. K. Htoo</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2023</creationdate><title>Prospects for Application of Guanidine-Containing Organomineral Complexes as Biocidal Functional Additives for Waterborne Polymer Materials</title><author>Gerasin, V. A. ; Zhurina, M. V. ; Kurenkov, V. V. ; Mendeleev, D. I. ; Ochenkov, D. E. ; Myat, K. K. 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A.</creatorcontrib><creatorcontrib>Zhurina, M. V.</creatorcontrib><creatorcontrib>Kurenkov, V. V.</creatorcontrib><creatorcontrib>Mendeleev, D. I.</creatorcontrib><creatorcontrib>Ochenkov, D. E.</creatorcontrib><creatorcontrib>Myat, K. K. Htoo</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer science. Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gerasin, V. A.</au><au>Zhurina, M. V.</au><au>Kurenkov, V. V.</au><au>Mendeleev, D. I.</au><au>Ochenkov, D. E.</au><au>Myat, K. K. Htoo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Prospects for Application of Guanidine-Containing Organomineral Complexes as Biocidal Functional Additives for Waterborne Polymer Materials</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2023</date><risdate>2023</risdate><volume>65</volume><issue>5</issue><spage>681</spage><epage>691</epage><pages>681-691</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>The possibility of using organomineral complexes of polyhexamethylene guanidine hydrochloride as a functional additive for a waterborne paint based on polyvinyl acetate has been investigated. Organomineral complexes containing 20 and 30 wt % guanidine polymer have been obtained, with intercalation of polyguanidine chains into the interlayer space of montmorillonite being observed. It has been revealed that the stability of the polymer film to water is retained when organomineral complexes are introduced into a polyvinyl acetate dispersion, whereas the water resistance of the film sharply decreases when free polyguanidine is added. There was no significant influence of organomineral complexes on the rheological characteristics of the dispersion and its sedimentation stability. Testing of waterborne paints with various additives has shown that introduction of organomineral complexes into the material prevents the coating from fouling by biofilms of gram-positive bacteria
Staphylococcus aureus
and
Rhodococcus erythropolis
, with the hardness, water resistance, and water-vapor transmission of the coatings being retained at a satisfactory level.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1560090423701269</doi><tpages>11</tpages></addata></record> |
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| subjects | Additives Biocides Chemistry Chemistry and Materials Science Composites Dispersion Gram-positive bacteria Guanidine hydrochloride Interlayers Montmorillonite Polymer films Polymer Sciences Polymers Rheological properties Rhodococcus Stability Vapor resistance Water hardness Water resistance Water vapor |
| title | Prospects for Application of Guanidine-Containing Organomineral Complexes as Biocidal Functional Additives for Waterborne Polymer Materials |
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