Directed C−H Allylation of Aromatic Carboxamides with Allyl Aryl Ethers under CpCo(III)‐Catalysis

The Cp*Co(III) C−H allylation of (hetero)arenes with allyl aryl ethers has been developed using an amide as directing group (24 examples). DFT calculations have shed light on the mechanistic course and reactivity pattern, showing that strong electron releasing groups favour the reaction by reducing...

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Veröffentlicht in:	European journal of organic chemistry 2024-01, Vol.27 (1), p.n/a
Hauptverfasser:	Carral‐Menoyo, Asier, Barbolla, Iratxe, Santiago, Carlos, Espinel, Martín, Sotomayor, Nuria, Gómez‐Bengoa, Enrique, Lete, Esther
Format:	Artikel
Sprache:	eng
Schlagworte:	Allyl compounds allylation Aromatic compounds aromatic substitution Chemical reactions cobalt C−H activation density functional calculations Ethers
Online-Zugang:	Volltext
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