Y-Shaped Fluorophores Based on N(2)-Aryl-1,2,3-triazoles: Synthesis and Study of Photophysical and Chemosensor Properties for the Detection of Nitroaromatic Compounds

A five-stage method for the synthesis of Y-shaped push–pull fluorophores based on 2-(4'-methoxyphenyl)-1,2,3-triazole was proposed. The resulting molecules exhibited emission in the range from 350 to 450 nm with high quantum yields (QY) of 90–99% in solvents of various polarity. The products pr...

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Veröffentlicht in:Doklady. Chemistry 2023-09, Vol.512 (1), p.232-241
Hauptverfasser: Lavrinchenko, I. A., Moseev, T. D., Varaksin, M. V., Seleznev, Yu. A., Sadieva, L. K., Zyryanov, G. V., Tsmokaluk, A. N., Charushin, V. N., Chupakhin, O. N.
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container_end_page 241
container_issue 1
container_start_page 232
container_title Doklady. Chemistry
container_volume 512
creator Lavrinchenko, I. A.
Moseev, T. D.
Varaksin, M. V.
Seleznev, Yu. A.
Sadieva, L. K.
Zyryanov, G. V.
Tsmokaluk, A. N.
Charushin, V. N.
Chupakhin, O. N.
description A five-stage method for the synthesis of Y-shaped push–pull fluorophores based on 2-(4'-methoxyphenyl)-1,2,3-triazole was proposed. The resulting molecules exhibited emission in the range from 350 to 450 nm with high quantum yields (QY) of 90–99% in solvents of various polarity. The products proved to be applicable as chemosensors for both aromatic and aliphatic nitro analytes in concentrations down to 300 ppb.
doi_str_mv 10.1134/S0012500823600682
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subjects Chemical compounds
Chemical sensors
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chemoreceptors
Fluorescence
Industrial Chemistry/Chemical Engineering
Synthesis
Triazoles
title Y-Shaped Fluorophores Based on N(2)-Aryl-1,2,3-triazoles: Synthesis and Study of Photophysical and Chemosensor Properties for the Detection of Nitroaromatic Compounds
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