A high valence binary metal-organic framework as an electrode material for aqueous asymmetric supercapacitors

A high valence binary metal-organic framework as an electrode material for aqueous asymmetric supercapacitors

This study presents the chemical transformation of nickel-based metal-organic frameworks into binary metal-organic frameworks by introducing cobalt metal ions. The resulting NiCo-BDC hierarchical nanostructure exhibited higher oxidation states, resulting in an impressive capacitance of 1431 F g −1 ....

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-12, Vol.6 (2), p.28-211
Hauptverfasser: Naveen, T. B, Durgalakshmi, D, Balakumar, S, Rakkesh, R. Ajay
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Sprache:eng
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Electrode materials
Metal-organic frameworks
Oxidation
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container_title Chemical communications (Cambridge, England)
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creator Naveen, T. B
Durgalakshmi, D
Balakumar, S
Rakkesh, R. Ajay
description This study presents the chemical transformation of nickel-based metal-organic frameworks into binary metal-organic frameworks by introducing cobalt metal ions. The resulting NiCo-BDC hierarchical nanostructure exhibited higher oxidation states, resulting in an impressive capacitance of 1431 F g −1 . Additionally, the device based on this material exhibited exceptional capacity retention over 3000 cycles. The fabricated hierarchical nanostructure based on NiCo-metal-organic frameworks provides numerous pathways for electron transport, resulting in increased capacitance and superior rate performance.
doi_str_mv 10.1039/d3cc05195a
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subjects Electrode materials
Metal-organic frameworks
Oxidation
title A high valence binary metal-organic framework as an electrode material for aqueous asymmetric supercapacitors
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