Using waste to treat waste: facile synthesis of hollow carbon nanospheres from lignin for water decontamination
Lignin, the most abundant natural material, is considered as a low-value commercial biomass waste from paper mills and wineries. In an effort to turn biomass waste into a highly valuable material, herein, a new-type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biom...
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| Veröffentlicht in: | Chemical science (Cambridge) 2023-12, Vol.15 (1), p.24-212 |
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| creator | Liu, Xiang Hao, Zixuan Fang, Chen Pang, Kun Yan, Jiaying Huang, Yingping Huang, Di Astruc, Didier |
| description | Lignin, the most abundant natural material, is considered as a low-value commercial biomass waste from paper mills and wineries. In an effort to turn biomass waste into a highly valuable material, herein, a new-type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biomass dealkali lignin, as an efficient nanocatalyst for the elimination of antibiotics in complex water matrices. Detailed characterization shows that HCNs possess a hollow nanosphere structure, with abundant graphitic C/N and surface N and O-containing functional groups favorable for peroxydisulfate (PDS) activation. Among them, HCN-500 provides the maximum degradation rate (95.0%) and mineralization efficiency (74.4%) surpassing those of most metal-based advanced oxidation processes (AOPs) in the elimination of oxytetracycline (OTC). Density functional theory (DFT) calculations and high-resolution mass spectroscopy (HR-MS) were employed to reveal the possible degradation pathway of OTC elimination. In addition, the HCN-500/PDS system is also successfully applied to real antibiotics removal in complex water matrices (
e.g.
river water and tap water), with excellent catalytic performances.
Herein, a new type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biomass dealkali lignin, as an efficient nanocatalyst for the elimination of antibiotics in complex water matrices. |
| doi_str_mv | 10.1039/d3sc05275c |
| format | Article |
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e.g.
river water and tap water), with excellent catalytic performances.
Herein, a new type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biomass dealkali lignin, as an efficient nanocatalyst for the elimination of antibiotics in complex water matrices.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/d3sc05275c</identifier><identifier>PMID: 38131073</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Antibiotics ; Biomass ; Carbon ; Chemistry ; Decontamination ; Degradation ; Density functional theory ; Drinking water ; Functional groups ; Lignin ; Nanospheres ; Oxidation ; Oxytetracycline ; Pulp & paper mills ; Pyrolysis ; Water purification ; Wineries</subject><ispartof>Chemical science (Cambridge), 2023-12, Vol.15 (1), p.24-212</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2024</rights><rights>This journal is © The Royal Society of Chemistry 2024 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-ef9ecddc337616524fa5f95cca36b9043e8f91bffc9d2c628b4a841590d3a75b3</citedby><cites>FETCH-LOGICAL-c429t-ef9ecddc337616524fa5f95cca36b9043e8f91bffc9d2c628b4a841590d3a75b3</cites><orcidid>0000-0002-0213-637X ; 0000-0001-6446-8751</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10732141/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10732141/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38131073$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Xiang</creatorcontrib><creatorcontrib>Hao, Zixuan</creatorcontrib><creatorcontrib>Fang, Chen</creatorcontrib><creatorcontrib>Pang, Kun</creatorcontrib><creatorcontrib>Yan, Jiaying</creatorcontrib><creatorcontrib>Huang, Yingping</creatorcontrib><creatorcontrib>Huang, Di</creatorcontrib><creatorcontrib>Astruc, Didier</creatorcontrib><title>Using waste to treat waste: facile synthesis of hollow carbon nanospheres from lignin for water decontamination</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>Lignin, the most abundant natural material, is considered as a low-value commercial biomass waste from paper mills and wineries. In an effort to turn biomass waste into a highly valuable material, herein, a new-type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biomass dealkali lignin, as an efficient nanocatalyst for the elimination of antibiotics in complex water matrices. Detailed characterization shows that HCNs possess a hollow nanosphere structure, with abundant graphitic C/N and surface N and O-containing functional groups favorable for peroxydisulfate (PDS) activation. Among them, HCN-500 provides the maximum degradation rate (95.0%) and mineralization efficiency (74.4%) surpassing those of most metal-based advanced oxidation processes (AOPs) in the elimination of oxytetracycline (OTC). Density functional theory (DFT) calculations and high-resolution mass spectroscopy (HR-MS) were employed to reveal the possible degradation pathway of OTC elimination. In addition, the HCN-500/PDS system is also successfully applied to real antibiotics removal in complex water matrices (
e.g.
river water and tap water), with excellent catalytic performances.
Herein, a new type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biomass dealkali lignin, as an efficient nanocatalyst for the elimination of antibiotics in complex water matrices.</description><subject>Antibiotics</subject><subject>Biomass</subject><subject>Carbon</subject><subject>Chemistry</subject><subject>Decontamination</subject><subject>Degradation</subject><subject>Density functional theory</subject><subject>Drinking water</subject><subject>Functional groups</subject><subject>Lignin</subject><subject>Nanospheres</subject><subject>Oxidation</subject><subject>Oxytetracycline</subject><subject>Pulp & paper mills</subject><subject>Pyrolysis</subject><subject>Water purification</subject><subject>Wineries</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdks1rVDEUxYMottRu3CsBN0UYm-TmfcSNlNHWQsGFdh3y8m5mUt5LxiRj6X9vxqnjx93khvvjcG5OCHnJ2TvOQJ2PkC1rRNfYJ-RYMMkXbQPq6aEX7Iic5nzHagHwSj4nR9Bz4KyDYxJvsw8rem9yQVoiLQlN2V_fU2esn5Dmh1DWmH2m0dF1nKZ4T61JQww0mBDzZo0JM3UpznTyq-ADdTFVkYKJjmhjKGb2wRQfwwvyzJkp4-njeUJuLz99W35e3Hy5ul5e3CysFKos0Cm042gBupbXJaQzjVONtQbaQTEJ2DvFB-esGoVtRT9I00veKDaC6ZoBTsiHve5mO8w4WgwlmUlvkp9NetDReP3vJPi1XsUfevcsgkteFc4eFVL8vsVc9OyzxWkyAeM2a6FY0wjRSVXRN_-hd3GbQt1vR0EvJbSsUm_3lE0x54Tu4IYzvctSf4Svy19ZLiv8-m__B_R3chV4tQdStofpn88APwFyH6Xi</recordid><startdate>20231220</startdate><enddate>20231220</enddate><creator>Liu, Xiang</creator><creator>Hao, Zixuan</creator><creator>Fang, Chen</creator><creator>Pang, Kun</creator><creator>Yan, Jiaying</creator><creator>Huang, Yingping</creator><creator>Huang, Di</creator><creator>Astruc, Didier</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-0213-637X</orcidid><orcidid>https://orcid.org/0000-0001-6446-8751</orcidid></search><sort><creationdate>20231220</creationdate><title>Using waste to treat waste: facile synthesis of hollow carbon nanospheres from lignin for water decontamination</title><author>Liu, Xiang ; Hao, Zixuan ; Fang, Chen ; Pang, Kun ; Yan, Jiaying ; Huang, Yingping ; Huang, Di ; Astruc, Didier</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-ef9ecddc337616524fa5f95cca36b9043e8f91bffc9d2c628b4a841590d3a75b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Antibiotics</topic><topic>Biomass</topic><topic>Carbon</topic><topic>Chemistry</topic><topic>Decontamination</topic><topic>Degradation</topic><topic>Density functional theory</topic><topic>Drinking water</topic><topic>Functional groups</topic><topic>Lignin</topic><topic>Nanospheres</topic><topic>Oxidation</topic><topic>Oxytetracycline</topic><topic>Pulp & paper mills</topic><topic>Pyrolysis</topic><topic>Water purification</topic><topic>Wineries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Xiang</creatorcontrib><creatorcontrib>Hao, Zixuan</creatorcontrib><creatorcontrib>Fang, Chen</creatorcontrib><creatorcontrib>Pang, Kun</creatorcontrib><creatorcontrib>Yan, Jiaying</creatorcontrib><creatorcontrib>Huang, Yingping</creatorcontrib><creatorcontrib>Huang, Di</creatorcontrib><creatorcontrib>Astruc, Didier</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Xiang</au><au>Hao, Zixuan</au><au>Fang, Chen</au><au>Pang, Kun</au><au>Yan, Jiaying</au><au>Huang, Yingping</au><au>Huang, Di</au><au>Astruc, Didier</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Using waste to treat waste: facile synthesis of hollow carbon nanospheres from lignin for water decontamination</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2023-12-20</date><risdate>2023</risdate><volume>15</volume><issue>1</issue><spage>24</spage><epage>212</epage><pages>24-212</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Lignin, the most abundant natural material, is considered as a low-value commercial biomass waste from paper mills and wineries. In an effort to turn biomass waste into a highly valuable material, herein, a new-type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biomass dealkali lignin, as an efficient nanocatalyst for the elimination of antibiotics in complex water matrices. Detailed characterization shows that HCNs possess a hollow nanosphere structure, with abundant graphitic C/N and surface N and O-containing functional groups favorable for peroxydisulfate (PDS) activation. Among them, HCN-500 provides the maximum degradation rate (95.0%) and mineralization efficiency (74.4%) surpassing those of most metal-based advanced oxidation processes (AOPs) in the elimination of oxytetracycline (OTC). Density functional theory (DFT) calculations and high-resolution mass spectroscopy (HR-MS) were employed to reveal the possible degradation pathway of OTC elimination. In addition, the HCN-500/PDS system is also successfully applied to real antibiotics removal in complex water matrices (
e.g.
river water and tap water), with excellent catalytic performances.
Herein, a new type of hollow carbon nanospheres (HCNs) is designed and synthesized by pyrolysis of biomass dealkali lignin, as an efficient nanocatalyst for the elimination of antibiotics in complex water matrices.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38131073</pmid><doi>10.1039/d3sc05275c</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-0213-637X</orcidid><orcidid>https://orcid.org/0000-0001-6446-8751</orcidid><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| subjects | Antibiotics Biomass Carbon Chemistry Decontamination Degradation Density functional theory Drinking water Functional groups Lignin Nanospheres Oxidation Oxytetracycline Pulp & paper mills Pyrolysis Water purification Wineries |
| title | Using waste to treat waste: facile synthesis of hollow carbon nanospheres from lignin for water decontamination |
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