Dinitrogen activation by a titanium hydride complex supported by 2-butene ligand

The activation of dinitrogen by a titanium hydride complex with two bridging hydrides located between metal Ti and Li was investigated. Exposing cyclic bis-alkylidene titanium complex 1 to H 2 in THF solution yielded titanium hydride 2 , {[(2-butene)(C 5 H 5 )Ti](μ-H) 2 Li(THF) 3 }. 2 aggregated int...

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Veröffentlicht in:	Inorganic chemistry frontiers 2023-12, Vol.11 (1), p.27-214
Hauptverfasser:	Shi, Xianghui, Zhang, Yongliang, Zhong, Mingdong, Feng, Rui, Chen, Yuanjin, Yu, Lei, Wu, Yue, Wei, Junnian, Xi, Zhenfeng
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylidene Ammonia Crystallography Hexanes Hydrazines Lithium hydrides Nitrogen compounds Reducing agents Titanium compounds
Online-Zugang:	Volltext
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