Selective Catalysts for the Homogeneous Semi‐Hydrogenation

An efficient and highly selective semi‐hydrogenation of terminal alkynes to alkenes using neutral dimeric rhodium(I) complexes of the type [Rh(μ‐Cl)(PP)]2 is presented. Dehydroisophytol (DIP) was chosen as the alkyne for this study because of its high importance in the industrial production of synth...

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Veröffentlicht in:	Advanced synthesis & catalysis 2023-12, Vol.365 (24), p.4538-4543
Hauptverfasser:	Jannsen, Nora, Pribbenow, Cornelia, Selle, Carmen, Drexler, Hans‐Joachim, Müller, Marc‐André, Medlock, Jonathan A., Bonrath, Werner, Heller, Detlef
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Alkynes Catalysts Hydrogenation Industrial applications Rhodium Selectivity vitamins
Online-Zugang:	Volltext
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