Densities, Ultrasonic Velocities, Viscosities, and FT-IR Spectra of Binary Mixtures of Morpholine in Isobutyl Acetate, Formamide, and 2-Butanol
The densities, ultrasonic velocities and viscosities of binary mixtures of morpholine along isobutyl acetate, formamide, and 2-butanol have gone determined at various temperatures over the entire composition range. From the observation data the values of deviation viscosity, excess isentropic compre...
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Veröffentlicht in: | Russian Journal of Physical Chemistry A 2023-12, Vol.97 (13), p.3028-3036 |
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creator | Rajani, Ch Gowrisankar, M. Kalyani, K. Raju, R. Ramesh |
description | The densities, ultrasonic velocities and viscosities of binary mixtures of morpholine along isobutyl acetate, formamide, and 2-butanol have gone determined at various temperatures over the entire composition range. From the observation data the values of deviation viscosity, excess isentropic compressibility’s (
), and excess thermodynamic properties of the mixture were measured at an absolute dilution. Finally, the theory of Prigogine–Flory–Patterson (PFP) is correlated to recognize most prevalent interactions among the molecules. The Jouyban Acree version was used-up to coordinate the laboratory values of density (ρ), speed of sound, and viscosity (η). Further binary mixing and FT-IR spectra were studied at equimolar concentration have been estimated. The observations were analyzed and explained in terms of molecular package and type of interactions through the formation of hydrogen bonding. |
doi_str_mv | 10.1134/S0036024423130174 |
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), and excess thermodynamic properties of the mixture were measured at an absolute dilution. Finally, the theory of Prigogine–Flory–Patterson (PFP) is correlated to recognize most prevalent interactions among the molecules. The Jouyban Acree version was used-up to coordinate the laboratory values of density (ρ), speed of sound, and viscosity (η). Further binary mixing and FT-IR spectra were studied at equimolar concentration have been estimated. The observations were analyzed and explained in terms of molecular package and type of interactions through the formation of hydrogen bonding.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024423130174</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Binary mixtures ; Butanol ; Chemistry ; Chemistry and Materials Science ; Compressibility ; Dilution ; Hydrogen bonding ; Infrared spectroscopy ; Morpholine ; Physical Chemistry ; Physical Chemistry of Solutions ; Spectra ; Thermodynamic properties ; Viscosity</subject><ispartof>Russian Journal of Physical Chemistry A, 2023-12, Vol.97 (13), p.3028-3036</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2023, Vol. 97, No. 13, pp. 3028–3036. © Pleiades Publishing, Ltd., 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-3cf2297fafe03ddf772b8b33a796c419f9da24561fe12ac4c4b4f399d0f78a713</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024423130174$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024423130174$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Rajani, Ch</creatorcontrib><creatorcontrib>Gowrisankar, M.</creatorcontrib><creatorcontrib>Kalyani, K.</creatorcontrib><creatorcontrib>Raju, R. Ramesh</creatorcontrib><title>Densities, Ultrasonic Velocities, Viscosities, and FT-IR Spectra of Binary Mixtures of Morpholine in Isobutyl Acetate, Formamide, and 2-Butanol</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The densities, ultrasonic velocities and viscosities of binary mixtures of morpholine along isobutyl acetate, formamide, and 2-butanol have gone determined at various temperatures over the entire composition range. From the observation data the values of deviation viscosity, excess isentropic compressibility’s (
), and excess thermodynamic properties of the mixture were measured at an absolute dilution. Finally, the theory of Prigogine–Flory–Patterson (PFP) is correlated to recognize most prevalent interactions among the molecules. The Jouyban Acree version was used-up to coordinate the laboratory values of density (ρ), speed of sound, and viscosity (η). Further binary mixing and FT-IR spectra were studied at equimolar concentration have been estimated. The observations were analyzed and explained in terms of molecular package and type of interactions through the formation of hydrogen bonding.</description><subject>Binary mixtures</subject><subject>Butanol</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Compressibility</subject><subject>Dilution</subject><subject>Hydrogen bonding</subject><subject>Infrared spectroscopy</subject><subject>Morpholine</subject><subject>Physical Chemistry</subject><subject>Physical Chemistry of Solutions</subject><subject>Spectra</subject><subject>Thermodynamic properties</subject><subject>Viscosity</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KAzEUhYMoWKsP4C7gtqP568xk2VarhRbB_uBuyGQSTZkmNcmAfQpf2SmtuBBXF875zrncC8A1RrcYU3Y3R4imiDBGKKYIZ-wEdHCf4iRP6esp6OztZO-fg4sQ1ggxxjDrgK97ZYOJRoUeXNbRi-CskXClaieP8soE6X4YYSs4XiSTFzjfKtny0Gk4NFb4HZyZz9h4FfbSzPntu6uNVdBYOAmubOKuhgOpooiqB8fOb8TGVOpQSZJhE4V19SU406IO6uo4u2A5fliMnpLp8-NkNJgmkqR5TKjUhPBMC60QrSqdZaTMS0pFxlPJMNe8EoT1U6wVJkIyyUqmKecV0lkuMky74ObQu_Xuo1EhFmvXeNuuLAhHhPN-SrKWwgdKeheCV7rYerNpby0wKvZ_L_78vc2QQya0rH1T_rf5_9A3wvSE-Q</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Rajani, Ch</creator><creator>Gowrisankar, M.</creator><creator>Kalyani, K.</creator><creator>Raju, R. Ramesh</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231201</creationdate><title>Densities, Ultrasonic Velocities, Viscosities, and FT-IR Spectra of Binary Mixtures of Morpholine in Isobutyl Acetate, Formamide, and 2-Butanol</title><author>Rajani, Ch ; Gowrisankar, M. ; Kalyani, K. ; Raju, R. Ramesh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-3cf2297fafe03ddf772b8b33a796c419f9da24561fe12ac4c4b4f399d0f78a713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Binary mixtures</topic><topic>Butanol</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Compressibility</topic><topic>Dilution</topic><topic>Hydrogen bonding</topic><topic>Infrared spectroscopy</topic><topic>Morpholine</topic><topic>Physical Chemistry</topic><topic>Physical Chemistry of Solutions</topic><topic>Spectra</topic><topic>Thermodynamic properties</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rajani, Ch</creatorcontrib><creatorcontrib>Gowrisankar, M.</creatorcontrib><creatorcontrib>Kalyani, K.</creatorcontrib><creatorcontrib>Raju, R. Ramesh</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rajani, Ch</au><au>Gowrisankar, M.</au><au>Kalyani, K.</au><au>Raju, R. Ramesh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Densities, Ultrasonic Velocities, Viscosities, and FT-IR Spectra of Binary Mixtures of Morpholine in Isobutyl Acetate, Formamide, and 2-Butanol</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>97</volume><issue>13</issue><spage>3028</spage><epage>3036</epage><pages>3028-3036</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The densities, ultrasonic velocities and viscosities of binary mixtures of morpholine along isobutyl acetate, formamide, and 2-butanol have gone determined at various temperatures over the entire composition range. From the observation data the values of deviation viscosity, excess isentropic compressibility’s (
), and excess thermodynamic properties of the mixture were measured at an absolute dilution. Finally, the theory of Prigogine–Flory–Patterson (PFP) is correlated to recognize most prevalent interactions among the molecules. The Jouyban Acree version was used-up to coordinate the laboratory values of density (ρ), speed of sound, and viscosity (η). Further binary mixing and FT-IR spectra were studied at equimolar concentration have been estimated. The observations were analyzed and explained in terms of molecular package and type of interactions through the formation of hydrogen bonding.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024423130174</doi><tpages>9</tpages></addata></record> |
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subjects | Binary mixtures Butanol Chemistry Chemistry and Materials Science Compressibility Dilution Hydrogen bonding Infrared spectroscopy Morpholine Physical Chemistry Physical Chemistry of Solutions Spectra Thermodynamic properties Viscosity |
title | Densities, Ultrasonic Velocities, Viscosities, and FT-IR Spectra of Binary Mixtures of Morpholine in Isobutyl Acetate, Formamide, and 2-Butanol |
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