Spatial Computer Model of the UCl3–NaCl–MgCl2–PuCl3 Isobaric Phase Diagram
A four-dimensional (4D, in concentration–temperature coordinates) computer model of the isobaric phase diagram of uranium, sodium, magnesium, and plutonium chlorides, as well as four three-dimensional (3D) computer models of the phase diagrams of the ternary systems forming it, has been constructed....
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2023-11, Vol.68 (11), p.1622-1631 |
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| container_issue | 11 |
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| container_title | Russian journal of inorganic chemistry |
| container_volume | 68 |
| creator | Vorob’eva, V. P. Zelenaya, A. E. Lutsyk, V. I. Lamueva, M. V. |
| description | A four-dimensional (4D, in concentration–temperature coordinates) computer model of the isobaric phase diagram of uranium, sodium, magnesium, and plutonium chlorides, as well as four three-dimensional (3D) computer models of the phase diagrams of the ternary systems forming it, has been constructed. The technology of assembling a 4D model of 46 hypersurfaces and 17 phase regions was used in the design. The obtained 4D model of the UCl
3
–NaCl–MgCl
2
–PuCl
3
phase diagram makes it possible to visualize a four-dimensional object as a whole (with all its hypersurfaces and phase regions) by any arbitrarily given 2D and 3D sections, as well as it is able to reproduce published (experimental or thermodynamically calculated) 2D sections. The scope of application of the results of the work is the development of materials for fuel components of fourth-generation molten salt reactors and pyrochemical recycling of spent fuel rods. For the first time, a comprehensive, complete description of phase diagrams composed of uranium, plutonium, sodium, and magnesium chlorides has been obtained. |
| doi_str_mv | 10.1134/S0036023623602039 |
| format | Article |
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3
–NaCl–MgCl
2
–PuCl
3
phase diagram makes it possible to visualize a four-dimensional object as a whole (with all its hypersurfaces and phase regions) by any arbitrarily given 2D and 3D sections, as well as it is able to reproduce published (experimental or thermodynamically calculated) 2D sections. The scope of application of the results of the work is the development of materials for fuel components of fourth-generation molten salt reactors and pyrochemical recycling of spent fuel rods. For the first time, a comprehensive, complete description of phase diagrams composed of uranium, plutonium, sodium, and magnesium chlorides has been obtained.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023623602039</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Hyperspaces ; Inorganic Chemistry ; Magnesium chloride ; Molten salt nuclear reactors ; Nuclear fuel elements ; Phase diagrams ; Physicochemical Analysis of Inorganic Systems ; Plutonium ; Sodium ; Ternary systems ; Three dimensional models ; Uranium</subject><ispartof>Russian journal of inorganic chemistry, 2023-11, Vol.68 (11), p.1622-1631</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 11, pp. 1622–1631. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 11, pp. 1626–1636.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-aeaa882eab3fc1f3864bd71b5f08f7a69ffa414079c609148d9e42dbc567b5e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023623602039$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023623602039$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Vorob’eva, V. P.</creatorcontrib><creatorcontrib>Zelenaya, A. E.</creatorcontrib><creatorcontrib>Lutsyk, V. I.</creatorcontrib><creatorcontrib>Lamueva, M. V.</creatorcontrib><title>Spatial Computer Model of the UCl3–NaCl–MgCl2–PuCl3 Isobaric Phase Diagram</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>A four-dimensional (4D, in concentration–temperature coordinates) computer model of the isobaric phase diagram of uranium, sodium, magnesium, and plutonium chlorides, as well as four three-dimensional (3D) computer models of the phase diagrams of the ternary systems forming it, has been constructed. The technology of assembling a 4D model of 46 hypersurfaces and 17 phase regions was used in the design. The obtained 4D model of the UCl
3
–NaCl–MgCl
2
–PuCl
3
phase diagram makes it possible to visualize a four-dimensional object as a whole (with all its hypersurfaces and phase regions) by any arbitrarily given 2D and 3D sections, as well as it is able to reproduce published (experimental or thermodynamically calculated) 2D sections. The scope of application of the results of the work is the development of materials for fuel components of fourth-generation molten salt reactors and pyrochemical recycling of spent fuel rods. For the first time, a comprehensive, complete description of phase diagrams composed of uranium, plutonium, sodium, and magnesium chlorides has been obtained.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Hyperspaces</subject><subject>Inorganic Chemistry</subject><subject>Magnesium chloride</subject><subject>Molten salt nuclear reactors</subject><subject>Nuclear fuel elements</subject><subject>Phase diagrams</subject><subject>Physicochemical Analysis of Inorganic Systems</subject><subject>Plutonium</subject><subject>Sodium</subject><subject>Ternary systems</subject><subject>Three dimensional models</subject><subject>Uranium</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE1OwzAQhS0EEqVwAHaWWAf8F8dZovBXqYVILetokthtqrQOdrJgxx24ISfBUZFYIFafNPPem9FD6JKSa0q5uFkSwiVhXLIRhKdHaEJjTiMlKT9Gk3EdjftTdOb9lhAhSKImKF920DfQ4szuuqHXDi9srVtsDe43Gr9mLf_6-HyGrA1YrLOWBeZDGOOZtyW4psL5BrzGdw2sHezO0YmB1uuLH07R6uF-lT1F85fHWXY7jyomVR-BBlCKaSi5qajhSoqyTmgZG6JMAjI1BgQNP6aVJCkVqk61YHVZxTIpY82n6OoQ2zn7NmjfF1s7uH24WLCUsJgoGcugogdV5az3Tpuic80O3HtBSTH2VvzpLXjYweODdr_W7jf5f9M3Y-Vv9Q</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Vorob’eva, V. P.</creator><creator>Zelenaya, A. E.</creator><creator>Lutsyk, V. I.</creator><creator>Lamueva, M. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231101</creationdate><title>Spatial Computer Model of the UCl3–NaCl–MgCl2–PuCl3 Isobaric Phase Diagram</title><author>Vorob’eva, V. P. ; Zelenaya, A. E. ; Lutsyk, V. I. ; Lamueva, M. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-aeaa882eab3fc1f3864bd71b5f08f7a69ffa414079c609148d9e42dbc567b5e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Hyperspaces</topic><topic>Inorganic Chemistry</topic><topic>Magnesium chloride</topic><topic>Molten salt nuclear reactors</topic><topic>Nuclear fuel elements</topic><topic>Phase diagrams</topic><topic>Physicochemical Analysis of Inorganic Systems</topic><topic>Plutonium</topic><topic>Sodium</topic><topic>Ternary systems</topic><topic>Three dimensional models</topic><topic>Uranium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vorob’eva, V. P.</creatorcontrib><creatorcontrib>Zelenaya, A. E.</creatorcontrib><creatorcontrib>Lutsyk, V. I.</creatorcontrib><creatorcontrib>Lamueva, M. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vorob’eva, V. P.</au><au>Zelenaya, A. E.</au><au>Lutsyk, V. I.</au><au>Lamueva, M. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spatial Computer Model of the UCl3–NaCl–MgCl2–PuCl3 Isobaric Phase Diagram</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>68</volume><issue>11</issue><spage>1622</spage><epage>1631</epage><pages>1622-1631</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>A four-dimensional (4D, in concentration–temperature coordinates) computer model of the isobaric phase diagram of uranium, sodium, magnesium, and plutonium chlorides, as well as four three-dimensional (3D) computer models of the phase diagrams of the ternary systems forming it, has been constructed. The technology of assembling a 4D model of 46 hypersurfaces and 17 phase regions was used in the design. The obtained 4D model of the UCl
3
–NaCl–MgCl
2
–PuCl
3
phase diagram makes it possible to visualize a four-dimensional object as a whole (with all its hypersurfaces and phase regions) by any arbitrarily given 2D and 3D sections, as well as it is able to reproduce published (experimental or thermodynamically calculated) 2D sections. The scope of application of the results of the work is the development of materials for fuel components of fourth-generation molten salt reactors and pyrochemical recycling of spent fuel rods. For the first time, a comprehensive, complete description of phase diagrams composed of uranium, plutonium, sodium, and magnesium chlorides has been obtained.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023623602039</doi><tpages>10</tpages></addata></record> |
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| language | eng |
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| subjects | Chemistry Chemistry and Materials Science Hyperspaces Inorganic Chemistry Magnesium chloride Molten salt nuclear reactors Nuclear fuel elements Phase diagrams Physicochemical Analysis of Inorganic Systems Plutonium Sodium Ternary systems Three dimensional models Uranium |
| title | Spatial Computer Model of the UCl3–NaCl–MgCl2–PuCl3 Isobaric Phase Diagram |
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