Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate
New bis-chelate cobalt(II) complex [Co(DPG) 2 (DMF) 2 ] ( 1 ), where DPG is N -(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coor...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2023-09, Vol.68 (9), p.1257-1262 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Sakhapov, I. F. Kagilev, A. A. Kantyukov, A. O. Mikhailov, I. K. Sof’icheva, O. S. Islamov, D. R. Gafurov, Z. N. Yakhvarov, D. G. |
| description | New bis-chelate cobalt(II) complex [Co(DPG)
2
(DMF)
2
] (
1
), where DPG is
N
-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex
1
has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (
= –1.70 V vs Ag/AgNO
3
, 1 × 10
–2
М in CH
3
CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode. |
| doi_str_mv | 10.1134/S0036023623700316 |
| format | Article |
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2
(DMF)
2
] (
1
), where DPG is
N
-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex
1
has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (
= –1.70 V vs Ag/AgNO
3
, 1 × 10
–2
М in CH
3
CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023623700316</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Amino acids ; Chemical reduction ; Chemistry ; Chemistry and Materials Science ; Cobalt compounds ; Coordination Compounds ; Electrochemical analysis ; Inorganic Chemistry ; Silver nitrate</subject><ispartof>Russian journal of inorganic chemistry, 2023-09, Vol.68 (9), p.1257-1262</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 9, pp. 1257–1262. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 9, pp. 1287–1292.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-caaa1240bf996edfe780cb6439e69ad115e4a0e0f2e50a88f391fada0445188c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023623700316$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023623700316$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sakhapov, I. F.</creatorcontrib><creatorcontrib>Kagilev, A. A.</creatorcontrib><creatorcontrib>Kantyukov, A. O.</creatorcontrib><creatorcontrib>Mikhailov, I. K.</creatorcontrib><creatorcontrib>Sof’icheva, O. S.</creatorcontrib><creatorcontrib>Islamov, D. R.</creatorcontrib><creatorcontrib>Gafurov, Z. N.</creatorcontrib><creatorcontrib>Yakhvarov, D. G.</creatorcontrib><title>Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>New bis-chelate cobalt(II) complex [Co(DPG)
2
(DMF)
2
] (
1
), where DPG is
N
-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex
1
has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (
= –1.70 V vs Ag/AgNO
3
, 1 × 10
–2
М in CH
3
CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.</description><subject>Amino acids</subject><subject>Chemical reduction</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt compounds</subject><subject>Coordination Compounds</subject><subject>Electrochemical analysis</subject><subject>Inorganic Chemistry</subject><subject>Silver nitrate</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1UM1Kw0AQXkTBWn0AbwteKnR1f5Lt5mhL_QFRoXoO282kSUmzcXcDzWP4KL6Iz2RKBQ_iYfhm-H6GGYTOGb1iTETXC0qFpFxILiZ9y-QBGrBYMKIkE4dosKPJjj9GJ96vKY0iOlED9LHo6lCAL_0YL4JrTWgdjLGuMzyvwARnTQGb0ugKvzjbgAsleGxzPLNLXYUeNk0FWzzVHjJsa_xERnwck2npRxsIhd12RrulrbvqsilgB-Trk2TlfmgK6_tyXbWqOlPWOsApOsp15eHsB4fo7Xb-Orsnj893D7ObR2K4VIEYrTXjEV3mSSIhy2GiqFnKSCQgE50xFkOkKdCcQ0y1UrlIWK4z3R8eM6WMGKKLfW7j7HsLPqRr27q6X5nyhPKYKsnjXsX2KuOs9w7ytHHlRrsuZTTdfT798_new_ce32vrFbjf5P9N35DliDk</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>Sakhapov, I. F.</creator><creator>Kagilev, A. A.</creator><creator>Kantyukov, A. O.</creator><creator>Mikhailov, I. K.</creator><creator>Sof’icheva, O. S.</creator><creator>Islamov, D. R.</creator><creator>Gafurov, Z. N.</creator><creator>Yakhvarov, D. G.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230901</creationdate><title>Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate</title><author>Sakhapov, I. F. ; Kagilev, A. A. ; Kantyukov, A. O. ; Mikhailov, I. K. ; Sof’icheva, O. S. ; Islamov, D. R. ; Gafurov, Z. N. ; Yakhvarov, D. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-caaa1240bf996edfe780cb6439e69ad115e4a0e0f2e50a88f391fada0445188c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Amino acids</topic><topic>Chemical reduction</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt compounds</topic><topic>Coordination Compounds</topic><topic>Electrochemical analysis</topic><topic>Inorganic Chemistry</topic><topic>Silver nitrate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sakhapov, I. F.</creatorcontrib><creatorcontrib>Kagilev, A. A.</creatorcontrib><creatorcontrib>Kantyukov, A. O.</creatorcontrib><creatorcontrib>Mikhailov, I. K.</creatorcontrib><creatorcontrib>Sof’icheva, O. S.</creatorcontrib><creatorcontrib>Islamov, D. R.</creatorcontrib><creatorcontrib>Gafurov, Z. N.</creatorcontrib><creatorcontrib>Yakhvarov, D. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sakhapov, I. F.</au><au>Kagilev, A. A.</au><au>Kantyukov, A. O.</au><au>Mikhailov, I. K.</au><au>Sof’icheva, O. S.</au><au>Islamov, D. R.</au><au>Gafurov, Z. N.</au><au>Yakhvarov, D. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-09-01</date><risdate>2023</risdate><volume>68</volume><issue>9</issue><spage>1257</spage><epage>1262</epage><pages>1257-1262</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>New bis-chelate cobalt(II) complex [Co(DPG)
2
(DMF)
2
] (
1
), where DPG is
N
-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex
1
has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (
= –1.70 V vs Ag/AgNO
3
, 1 × 10
–2
М in CH
3
CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023623700316</doi><tpages>6</tpages></addata></record> |
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| subjects | Amino acids Chemical reduction Chemistry Chemistry and Materials Science Cobalt compounds Coordination Compounds Electrochemical analysis Inorganic Chemistry Silver nitrate |
| title | Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate |
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