Preparation of NASICON Silico Phosphates of Composition Na1 + xZr2SixP3 – xO12 by Pyrolysis of Solution in Melt
A new method for preparing Na 1 + x Zr 2 Si x P 3 – x O 12 (0 < x < 3) based on pyrolysis of solution containing a mixture of organic components in rosin melt has been proposed. Effect of superstoichiometric amounts of sodium and phosphorus on the phase composition of synthesis products has be...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2023-08, Vol.68 (8), p.972-978 |
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| container_title | Russian journal of inorganic chemistry |
| container_volume | 68 |
| creator | Grishchenko, D. N. Medkov, M. A. |
| description | A new method for preparing Na
1 +
x
Zr
2
Si
x
P
3 –
x
O
12
(0 <
x
< 3) based on pyrolysis of solution containing a mixture of organic components in rosin melt has been proposed. Effect of superstoichiometric amounts of sodium and phosphorus on the phase composition of synthesis products has been proved. It has been found that precursor for the sample of maximal purity of phase composition is prepared at molar ratio Na : Zr : Si : P = (1.15 +
x
) : 2 :
x
: (
y
–
x
), where
y
= 3 (1.20 +
x
)/(1 +
x
). Precursor calcination temperature is 1000°C. Different NASICON compositions without crystalline admixtures have been obtained in the range 1.5 ≤
x
≤ 2.12. The prepared samples have been studied by X-ray powder diffraction and scanning electron microscopy. The disclosed method of synthesis is promising for the preparation of NASICON as both bulk materials and thin layer coatings. |
| doi_str_mv | 10.1134/S003602362360123X |
| format | Article |
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1 +
x
Zr
2
Si
x
P
3 –
x
O
12
(0 <
x
< 3) based on pyrolysis of solution containing a mixture of organic components in rosin melt has been proposed. Effect of superstoichiometric amounts of sodium and phosphorus on the phase composition of synthesis products has been proved. It has been found that precursor for the sample of maximal purity of phase composition is prepared at molar ratio Na : Zr : Si : P = (1.15 +
x
) : 2 :
x
: (
y
–
x
), where
y
= 3 (1.20 +
x
)/(1 +
x
). Precursor calcination temperature is 1000°C. Different NASICON compositions without crystalline admixtures have been obtained in the range 1.5 ≤
x
≤ 2.12. The prepared samples have been studied by X-ray powder diffraction and scanning electron microscopy. The disclosed method of synthesis is promising for the preparation of NASICON as both bulk materials and thin layer coatings.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S003602362360123X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Admixtures ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Phase composition ; Phosphates ; Precursors ; Pyrolysis ; Rosin ; Silicon ; Sodium ; Synthesis ; Synthesis and Properties of Inorganic Compounds ; X ray powder diffraction ; Zirconium</subject><ispartof>Russian journal of inorganic chemistry, 2023-08, Vol.68 (8), p.972-978</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 8, pp. 972–978. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 8, pp. 1042–1049.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-aafe8a57cb718fb60a517076fd8ac8e9551e2ea9ae7851702da03ee5425fe00e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S003602362360123X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S003602362360123X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Grishchenko, D. N.</creatorcontrib><creatorcontrib>Medkov, M. A.</creatorcontrib><title>Preparation of NASICON Silico Phosphates of Composition Na1 + xZr2SixP3 – xO12 by Pyrolysis of Solution in Melt</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>A new method for preparing Na
1 +
x
Zr
2
Si
x
P
3 –
x
O
12
(0 <
x
< 3) based on pyrolysis of solution containing a mixture of organic components in rosin melt has been proposed. Effect of superstoichiometric amounts of sodium and phosphorus on the phase composition of synthesis products has been proved. It has been found that precursor for the sample of maximal purity of phase composition is prepared at molar ratio Na : Zr : Si : P = (1.15 +
x
) : 2 :
x
: (
y
–
x
), where
y
= 3 (1.20 +
x
)/(1 +
x
). Precursor calcination temperature is 1000°C. Different NASICON compositions without crystalline admixtures have been obtained in the range 1.5 ≤
x
≤ 2.12. The prepared samples have been studied by X-ray powder diffraction and scanning electron microscopy. The disclosed method of synthesis is promising for the preparation of NASICON as both bulk materials and thin layer coatings.</description><subject>Admixtures</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Phase composition</subject><subject>Phosphates</subject><subject>Precursors</subject><subject>Pyrolysis</subject><subject>Rosin</subject><subject>Silicon</subject><subject>Sodium</subject><subject>Synthesis</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><subject>X ray powder diffraction</subject><subject>Zirconium</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kN9KwzAUh4MoOKcP4F3AS6meJE2bXo7in8HcClUQb0rWpS6ja7qkg_XOd_ANfRLbTfBChAPn4vt958APoUsCN4Qw_zYFYAFQFnQDhLLXIzQgnBFPBIQdo0GPvZ6fojPnVgC-D6EYoE1iVS2tbLSpsCnwdJSO49kUp7rUucHJ0rh6KRvlehibdW2c3menkuBrvHuzNNW7hOGvj0-8mxGK5y1OWmvK1um9lJpyuzd0hZ9U2Zyjk0KWTl387CF6ub97jh-9yexhHI8mXk4i0XhSFkpIHubzkIhiHoDkJIQwKBZC5kJFnBNFlYykCkVP6EICU4r7lBcKQLEhujrcra3ZbJVrspXZ2qp7mdEIKAfBu7KGiBxSuTXOWVVktdVraduMQNY3m_1ptnPowXFdtnpX9vfy_9I31FF6Dw</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Grishchenko, D. N.</creator><creator>Medkov, M. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230801</creationdate><title>Preparation of NASICON Silico Phosphates of Composition Na1 + xZr2SixP3 – xO12 by Pyrolysis of Solution in Melt</title><author>Grishchenko, D. N. ; Medkov, M. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-aafe8a57cb718fb60a517076fd8ac8e9551e2ea9ae7851702da03ee5425fe00e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Admixtures</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Phase composition</topic><topic>Phosphates</topic><topic>Precursors</topic><topic>Pyrolysis</topic><topic>Rosin</topic><topic>Silicon</topic><topic>Sodium</topic><topic>Synthesis</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><topic>X ray powder diffraction</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Grishchenko, D. N.</creatorcontrib><creatorcontrib>Medkov, M. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Grishchenko, D. N.</au><au>Medkov, M. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of NASICON Silico Phosphates of Composition Na1 + xZr2SixP3 – xO12 by Pyrolysis of Solution in Melt</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-08-01</date><risdate>2023</risdate><volume>68</volume><issue>8</issue><spage>972</spage><epage>978</epage><pages>972-978</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>A new method for preparing Na
1 +
x
Zr
2
Si
x
P
3 –
x
O
12
(0 <
x
< 3) based on pyrolysis of solution containing a mixture of organic components in rosin melt has been proposed. Effect of superstoichiometric amounts of sodium and phosphorus on the phase composition of synthesis products has been proved. It has been found that precursor for the sample of maximal purity of phase composition is prepared at molar ratio Na : Zr : Si : P = (1.15 +
x
) : 2 :
x
: (
y
–
x
), where
y
= 3 (1.20 +
x
)/(1 +
x
). Precursor calcination temperature is 1000°C. Different NASICON compositions without crystalline admixtures have been obtained in the range 1.5 ≤
x
≤ 2.12. The prepared samples have been studied by X-ray powder diffraction and scanning electron microscopy. The disclosed method of synthesis is promising for the preparation of NASICON as both bulk materials and thin layer coatings.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S003602362360123X</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2023-08, Vol.68 (8), p.972-978 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2902508562 |
| source | SpringerLink Journals |
| subjects | Admixtures Chemistry Chemistry and Materials Science Inorganic Chemistry Phase composition Phosphates Precursors Pyrolysis Rosin Silicon Sodium Synthesis Synthesis and Properties of Inorganic Compounds X ray powder diffraction Zirconium |
| title | Preparation of NASICON Silico Phosphates of Composition Na1 + xZr2SixP3 – xO12 by Pyrolysis of Solution in Melt |
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