Voltammetric Studies on the Reduction Potentials of Perfluoroalkyl Halides and Their Analogous Compounds
Photocatalytic single-electron transfer (SET) reactions involving perfluoroalkyl halides play a crucial role in synthetic organic chemistry. However, the electrochemical data for these compounds, which are essential in the discussion of the SET process, are missing. In this study, the electrochemica...
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| Veröffentlicht in: | Denki kagaku oyobi kōgyō butsuri kagaku 2023/11/30, Vol.91(11), pp.112016-112016 |
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| container_title | Denki kagaku oyobi kōgyō butsuri kagaku |
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| creator | YAMAGUCHI, Airi SHIDA, Naoki ATOBE, Mahito YAJIMA, Tomoko |
| description | Photocatalytic single-electron transfer (SET) reactions involving perfluoroalkyl halides play a crucial role in synthetic organic chemistry. However, the electrochemical data for these compounds, which are essential in the discussion of the SET process, are missing. In this study, the electrochemical reduction potentials of perfluoroalkyl halides, alkyl halides, and other analogous compounds were investigated in 0.1 M Bu4NPF6/CH3CN using Ag, Pt, and glassy carbon electrodes. The Ag electrode showed remarkable catalytic properties and a positive reduction peak shift during the reduction reaction; this indicates that the Ag electrode is suitable for estimating the electrochemical potential of the SET process. This study provides a comprehensive dataset for the electrochemical measurements of perfluoroalkyl and alkyl halides, which will help synthetic organic chemists select appropriate reaction systems for these compounds. |
| doi_str_mv | 10.5796/electrochemistry.23-67111 |
| format | Article |
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However, the electrochemical data for these compounds, which are essential in the discussion of the SET process, are missing. In this study, the electrochemical reduction potentials of perfluoroalkyl halides, alkyl halides, and other analogous compounds were investigated in 0.1 M Bu4NPF6/CH3CN using Ag, Pt, and glassy carbon electrodes. The Ag electrode showed remarkable catalytic properties and a positive reduction peak shift during the reduction reaction; this indicates that the Ag electrode is suitable for estimating the electrochemical potential of the SET process. This study provides a comprehensive dataset for the electrochemical measurements of perfluoroalkyl and alkyl halides, which will help synthetic organic chemists select appropriate reaction systems for these compounds.</description><identifier>ISSN: 1344-3542</identifier><identifier>EISSN: 2186-2451</identifier><identifier>DOI: 10.5796/electrochemistry.23-67111</identifier><language>eng</language><publisher>Tokyo: The Electrochemical Society of Japan</publisher><subject>Alkyl Halide ; Chemical reduction ; Electrochemical potential ; Electrochemistry ; Electrodes ; Electron transfer ; Fluorine Chemistry ; Glassy carbon ; Halides ; Linear Sweep Voltammetry ; Organic chemistry ; Perfluoro compounds ; Perfluoroalkyl & polyfluoroalkyl substances ; Perfluoroalkyl Halide ; Single electrons</subject><ispartof>Electrochemistry, 2023/11/30, Vol.91(11), pp.112016-112016</ispartof><rights>The Author(s) 2023. Published by ECSJ.</rights><rights>2023. 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| subjects | Alkyl Halide Chemical reduction Electrochemical potential Electrochemistry Electrodes Electron transfer Fluorine Chemistry Glassy carbon Halides Linear Sweep Voltammetry Organic chemistry Perfluoro compounds Perfluoroalkyl & polyfluoroalkyl substances Perfluoroalkyl Halide Single electrons |
| title | Voltammetric Studies on the Reduction Potentials of Perfluoroalkyl Halides and Their Analogous Compounds |
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