Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates
A structure–property correlation has been developed, which makes it possible to choose the optimal values of the enthalpy of formation of alkali metal borates, for which, according to the data of various experimental works and reference publications, wide variations are observed. Using this correlat...
Gespeichert in:
| Veröffentlicht in: | Russian journal of inorganic chemistry 2023-03, Vol.68 (3), p.270-277 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 277 |
|---|---|
| container_issue | 3 |
| container_start_page | 270 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 68 |
| creator | Tupitsin, A. A. Bychinskii, V. A. Shtenberg, M. V. Fomichev, S. V. Koroleva, O. N. |
| description | A structure–property correlation has been developed, which makes it possible to choose the optimal values of the enthalpy of formation of alkali metal borates, for which, according to the data of various experimental works and reference publications, wide variations are observed. Using this correlation, the enthalpy of formation of unstudied alkali metal borates can be reasonably estimated. It has been found that the contribution of B
2
O
3
to the enthalpy of formation is the same not only for alkali metal borates but also for Ba, Ca, and Pb borates, for whose enthalpy of formation a structure–property correlation has also been established. This suggests the suitability of the obtained correlations for estimating the enthalpy of formation in the borate series, where the value is known only for one member of the series, as well as the possibility of estimating the enthalpy of formation of mixed borates of different metals. |
| doi_str_mv | 10.1134/S0036023622700243 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2901473383</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2901473383</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-1343cefd30a704608af876971166d0a5865da69a637e3b781ff6ad5ffc6b855e3</originalsourceid><addsrcrecordid>eNp1kD9PwzAQxS0EEqXwAdgsMQfOucR2xlK1gFTE0DJH18SmKSEutjv025OoSB0Q00n3fu_-PMZuBdwLgdnDEgAlpCjTVAGkGZ6xkchRJFoKPGejQU4G_ZJdhbAFyDJQesRWsxCbL4qN67izPG4MX0bqavI1n3VxQ-3uMAhz50_U1B9CpLZtOsMn7Se1DX81fYM_Ok_RhGt2YakN5ua3jtn7fLaaPieLt6eX6WSRVChkTPq7sTK2RiAFmQRNVitZKCGkrIFyLfOaZEESlcG10sJaSXVubSXXOs8Njtndce7Ou--9CbHcur3v-pVlWoDIFKLGnhJHqvIuBG9sufP9y_5QCiiH8Mo_4fWe9OgJPdt9GH-a_L_pB-tMb7U</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2901473383</pqid></control><display><type>article</type><title>Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates</title><source>Springer Journals</source><creator>Tupitsin, A. A. ; Bychinskii, V. A. ; Shtenberg, M. V. ; Fomichev, S. V. ; Koroleva, O. N.</creator><creatorcontrib>Tupitsin, A. A. ; Bychinskii, V. A. ; Shtenberg, M. V. ; Fomichev, S. V. ; Koroleva, O. N.</creatorcontrib><description>A structure–property correlation has been developed, which makes it possible to choose the optimal values of the enthalpy of formation of alkali metal borates, for which, according to the data of various experimental works and reference publications, wide variations are observed. Using this correlation, the enthalpy of formation of unstudied alkali metal borates can be reasonably estimated. It has been found that the contribution of B
2
O
3
to the enthalpy of formation is the same not only for alkali metal borates but also for Ba, Ca, and Pb borates, for whose enthalpy of formation a structure–property correlation has also been established. This suggests the suitability of the obtained correlations for estimating the enthalpy of formation in the borate series, where the value is known only for one member of the series, as well as the possibility of estimating the enthalpy of formation of mixed borates of different metals.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023622700243</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Borates ; Boron oxides ; Calcium ; Chemistry ; Chemistry and Materials Science ; Correlation ; Enthalpy ; Estimation ; Inorganic Chemistry ; Physical Methods of Investigation</subject><ispartof>Russian journal of inorganic chemistry, 2023-03, Vol.68 (3), p.270-277</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 3, pp. 270–277. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 3, pp. 325–332.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-1343cefd30a704608af876971166d0a5865da69a637e3b781ff6ad5ffc6b855e3</citedby><cites>FETCH-LOGICAL-c316t-1343cefd30a704608af876971166d0a5865da69a637e3b781ff6ad5ffc6b855e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023622700243$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023622700243$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Tupitsin, A. A.</creatorcontrib><creatorcontrib>Bychinskii, V. A.</creatorcontrib><creatorcontrib>Shtenberg, M. V.</creatorcontrib><creatorcontrib>Fomichev, S. V.</creatorcontrib><creatorcontrib>Koroleva, O. N.</creatorcontrib><title>Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>A structure–property correlation has been developed, which makes it possible to choose the optimal values of the enthalpy of formation of alkali metal borates, for which, according to the data of various experimental works and reference publications, wide variations are observed. Using this correlation, the enthalpy of formation of unstudied alkali metal borates can be reasonably estimated. It has been found that the contribution of B
2
O
3
to the enthalpy of formation is the same not only for alkali metal borates but also for Ba, Ca, and Pb borates, for whose enthalpy of formation a structure–property correlation has also been established. This suggests the suitability of the obtained correlations for estimating the enthalpy of formation in the borate series, where the value is known only for one member of the series, as well as the possibility of estimating the enthalpy of formation of mixed borates of different metals.</description><subject>Borates</subject><subject>Boron oxides</subject><subject>Calcium</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Correlation</subject><subject>Enthalpy</subject><subject>Estimation</subject><subject>Inorganic Chemistry</subject><subject>Physical Methods of Investigation</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kD9PwzAQxS0EEqXwAdgsMQfOucR2xlK1gFTE0DJH18SmKSEutjv025OoSB0Q00n3fu_-PMZuBdwLgdnDEgAlpCjTVAGkGZ6xkchRJFoKPGejQU4G_ZJdhbAFyDJQesRWsxCbL4qN67izPG4MX0bqavI1n3VxQ-3uMAhz50_U1B9CpLZtOsMn7Se1DX81fYM_Ok_RhGt2YakN5ua3jtn7fLaaPieLt6eX6WSRVChkTPq7sTK2RiAFmQRNVitZKCGkrIFyLfOaZEESlcG10sJaSXVubSXXOs8Njtndce7Ou--9CbHcur3v-pVlWoDIFKLGnhJHqvIuBG9sufP9y_5QCiiH8Mo_4fWe9OgJPdt9GH-a_L_pB-tMb7U</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Tupitsin, A. A.</creator><creator>Bychinskii, V. A.</creator><creator>Shtenberg, M. V.</creator><creator>Fomichev, S. V.</creator><creator>Koroleva, O. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230301</creationdate><title>Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates</title><author>Tupitsin, A. A. ; Bychinskii, V. A. ; Shtenberg, M. V. ; Fomichev, S. V. ; Koroleva, O. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-1343cefd30a704608af876971166d0a5865da69a637e3b781ff6ad5ffc6b855e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Borates</topic><topic>Boron oxides</topic><topic>Calcium</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Correlation</topic><topic>Enthalpy</topic><topic>Estimation</topic><topic>Inorganic Chemistry</topic><topic>Physical Methods of Investigation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tupitsin, A. A.</creatorcontrib><creatorcontrib>Bychinskii, V. A.</creatorcontrib><creatorcontrib>Shtenberg, M. V.</creatorcontrib><creatorcontrib>Fomichev, S. V.</creatorcontrib><creatorcontrib>Koroleva, O. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tupitsin, A. A.</au><au>Bychinskii, V. A.</au><au>Shtenberg, M. V.</au><au>Fomichev, S. V.</au><au>Koroleva, O. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>68</volume><issue>3</issue><spage>270</spage><epage>277</epage><pages>270-277</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>A structure–property correlation has been developed, which makes it possible to choose the optimal values of the enthalpy of formation of alkali metal borates, for which, according to the data of various experimental works and reference publications, wide variations are observed. Using this correlation, the enthalpy of formation of unstudied alkali metal borates can be reasonably estimated. It has been found that the contribution of B
2
O
3
to the enthalpy of formation is the same not only for alkali metal borates but also for Ba, Ca, and Pb borates, for whose enthalpy of formation a structure–property correlation has also been established. This suggests the suitability of the obtained correlations for estimating the enthalpy of formation in the borate series, where the value is known only for one member of the series, as well as the possibility of estimating the enthalpy of formation of mixed borates of different metals.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023622700243</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2023-03, Vol.68 (3), p.270-277 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2901473383 |
| source | Springer Journals |
| subjects | Borates Boron oxides Calcium Chemistry Chemistry and Materials Science Correlation Enthalpy Estimation Inorganic Chemistry Physical Methods of Investigation |
| title | Estimation of the Standard Enthalpy of Formation of Crystalline Alkali Metal Borates |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T19%3A17%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Estimation%20of%20the%20Standard%20Enthalpy%20of%20Formation%20of%20Crystalline%20Alkali%20Metal%20Borates&rft.jtitle=Russian%20journal%20of%20inorganic%20chemistry&rft.au=Tupitsin,%20A.%20A.&rft.date=2023-03-01&rft.volume=68&rft.issue=3&rft.spage=270&rft.epage=277&rft.pages=270-277&rft.issn=0036-0236&rft.eissn=1531-8613&rft_id=info:doi/10.1134/S0036023622700243&rft_dat=%3Cproquest_cross%3E2901473383%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2901473383&rft_id=info:pmid/&rfr_iscdi=true |